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Title: Interplay of local structure, charge, and spin in bilayered manganese perovskites

Abstract

Chemical doping is a reliable method of modification of the electronic properties of transition metal compounds. In manganese perovskites, it leads to charge transfer and peculiar ordering phenomena. However, depending on the interplay of the local crystal structure and electronic properties, synthesis of stable compounds in the entire doping range is often impossible. In this paper, we show results of high-energy resolution x-ray absorption and emission spectroscopies on a $${\mathrm{La}}_{2{-}2x}{\mathrm{Sr}}_{1+2x}{\mathrm{Mn}}_{2}{\mathrm{O}}_{7}$$ family of bilayered manganites in a broad doping range $$(0.5{\le}x{\le}1)$$. We established a relation between local Mn charge and Mn-O distances as a function of doping. Finally, based on a comparison of such relation with other manganites, we suggest why stable structures cannot be realized for certain doping levels of bilayered compounds.

Authors:
 [1];  [2];  [1];  [1];  [3]
  1. AGH Univ. of Science and Technology, Krakow (Poland). Faculty of Physics and Applied Computer Science. Dept. of Solid State Physics
  2. AGH Univ. of Science and Technology, Krakow (Poland). Academic Centre for Materials and Nanotechnology
  3. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States); AGH Univ. of Science and Technology, Krakow (Poland)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); Ministry of Science and Higher Education (Poland); National Science Centre of Poland
OSTI Identifier:
1433887
Alternate Identifier(s):
OSTI ID: 1429939
Grant/Contract Number:  
AC02-06CH11357; 11.11.220.01/6; DIR/WK/2016/19; 2014/14/E/ST3/00026
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 97; Journal Issue: 11; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; dopants; manganites; x-ray absorption near-edge spectroscopy; x-ray absorption spectroscopy; x-ray emission spectroscopy

Citation Formats

Rybicki, Damian, Sikora, Marcin, Przewoznik, Janusz, Kapusta, Czeslaw, and Mitchell, John F. Interplay of local structure, charge, and spin in bilayered manganese perovskites. United States: N. p., 2018. Web. doi:10.1103/PhysRevB.97.115158.
Rybicki, Damian, Sikora, Marcin, Przewoznik, Janusz, Kapusta, Czeslaw, & Mitchell, John F. Interplay of local structure, charge, and spin in bilayered manganese perovskites. United States. doi:10.1103/PhysRevB.97.115158.
Rybicki, Damian, Sikora, Marcin, Przewoznik, Janusz, Kapusta, Czeslaw, and Mitchell, John F. Tue . "Interplay of local structure, charge, and spin in bilayered manganese perovskites". United States. doi:10.1103/PhysRevB.97.115158. https://www.osti.gov/servlets/purl/1433887.
@article{osti_1433887,
title = {Interplay of local structure, charge, and spin in bilayered manganese perovskites},
author = {Rybicki, Damian and Sikora, Marcin and Przewoznik, Janusz and Kapusta, Czeslaw and Mitchell, John F.},
abstractNote = {Chemical doping is a reliable method of modification of the electronic properties of transition metal compounds. In manganese perovskites, it leads to charge transfer and peculiar ordering phenomena. However, depending on the interplay of the local crystal structure and electronic properties, synthesis of stable compounds in the entire doping range is often impossible. In this paper, we show results of high-energy resolution x-ray absorption and emission spectroscopies on a ${\mathrm{La}}_{2{-}2x}{\mathrm{Sr}}_{1+2x}{\mathrm{Mn}}_{2}{\mathrm{O}}_{7}$ family of bilayered manganites in a broad doping range $(0.5{\le}x{\le}1)$. We established a relation between local Mn charge and Mn-O distances as a function of doping. Finally, based on a comparison of such relation with other manganites, we suggest why stable structures cannot be realized for certain doping levels of bilayered compounds.},
doi = {10.1103/PhysRevB.97.115158},
journal = {Physical Review B},
number = 11,
volume = 97,
place = {United States},
year = {2018},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Figures / Tables:

FIG. 1. FIG. 1.: (Color online) Crystal structure of a) \pseudocubic" LaMnO3, b) single-layer La1−xSr1+xMnO4 and c) bilayered La2−2xSr1+2xMn2O7 with corresponding arrangements of MnO6 octahedra. Different colors of Mn-O bonds indicate different lengths.

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    Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.