Two Dimensional Polyamides Prepared From Unsaturated Carboxylic Acids And Amines.
Abstract
A polyamide and a process for preparing the polyamide are disclosed. The process comprises reacting in a reaction mixture a monomer selected from unsaturated carboxylic acids, esters of unsaturated carboxylic acids, anhydrides of unsaturated carboxylic acids, and mixtures thereof, and a first amine to form an intermediate reaction product in the reaction mixture, wherein the first amine is selected from RR.sub.1 NH, RNH.sub.2, RR.sub.1 NH.sub.2.sup.+, RNH.sub.3.sup.+ and mixtures thereof, wherein R and R.sub.1 can be the same or different and each contain between about 1 and 50 carbon atoms and are optionally substituted with heteroatoms oxygen, nitrogen, sulfur, and phosphorus and combinations thereof, and reacting the intermediate reaction product and a second amine to form a polyamide, wherein the second amine is selected from R.sub.2 R.sub.3 NH, R.sub.2 NH.sub.2, R.sub.2 R.sub.3 NH.sub.2.sup.+, R.sub.2 NH.sub.3.sup.+ and mixtures thereof wherein R.sub.2 and R.sub.3 can be the same or different and each contain between about 1 and 50 carbon atoms and are optionally substituted with heteroatoms oxygen, nitrogen, sulfur, and phosphorus and combinations thereof, wherein multiple of the R, R.sub.1, R.sub.2, and R.sub.3 are in vertically aligned spaced relationship along a backbone formed by the polyamide. In one version of the invention, themore »
- Inventors:
-
- Utica, OH
- East Lansing, MI
- Lansing, MI
- Northbrook, IL
- Ann Arbor, MI
- Issue Date:
- OSTI Identifier:
- 879672
- Patent Number(s):
- 6495657
- Application Number:
- 09/698619
- Assignee:
- Michigan Biotechnology Institute (Lansing, MI)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10S - TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- DOE Contract Number:
- XXE-9-29058-01
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
Citation Formats
McDonald, William F, Huang, Zhi Heng, Wright, Stacy C, Danzig, Morris, and Taylor, Andrew C. Two Dimensional Polyamides Prepared From Unsaturated Carboxylic Acids And Amines.. United States: N. p., 2002.
Web.
McDonald, William F, Huang, Zhi Heng, Wright, Stacy C, Danzig, Morris, & Taylor, Andrew C. Two Dimensional Polyamides Prepared From Unsaturated Carboxylic Acids And Amines.. United States.
McDonald, William F, Huang, Zhi Heng, Wright, Stacy C, Danzig, Morris, and Taylor, Andrew C. Wed .
"Two Dimensional Polyamides Prepared From Unsaturated Carboxylic Acids And Amines.". United States. https://www.osti.gov/servlets/purl/879672.
@article{osti_879672,
title = {Two Dimensional Polyamides Prepared From Unsaturated Carboxylic Acids And Amines.},
author = {McDonald, William F and Huang, Zhi Heng and Wright, Stacy C and Danzig, Morris and Taylor, Andrew C},
abstractNote = {A polyamide and a process for preparing the polyamide are disclosed. The process comprises reacting in a reaction mixture a monomer selected from unsaturated carboxylic acids, esters of unsaturated carboxylic acids, anhydrides of unsaturated carboxylic acids, and mixtures thereof, and a first amine to form an intermediate reaction product in the reaction mixture, wherein the first amine is selected from RR.sub.1 NH, RNH.sub.2, RR.sub.1 NH.sub.2.sup.+, RNH.sub.3.sup.+ and mixtures thereof, wherein R and R.sub.1 can be the same or different and each contain between about 1 and 50 carbon atoms and are optionally substituted with heteroatoms oxygen, nitrogen, sulfur, and phosphorus and combinations thereof, and reacting the intermediate reaction product and a second amine to form a polyamide, wherein the second amine is selected from R.sub.2 R.sub.3 NH, R.sub.2 NH.sub.2, R.sub.2 R.sub.3 NH.sub.2.sup.+, R.sub.2 NH.sub.3.sup.+ and mixtures thereof wherein R.sub.2 and R.sub.3 can be the same or different and each contain between about 1 and 50 carbon atoms and are optionally substituted with heteroatoms oxygen, nitrogen, sulfur, and phosphorus and combinations thereof, wherein multiple of the R, R.sub.1, R.sub.2, and R.sub.3 are in vertically aligned spaced relationship along a backbone formed by the polyamide. In one version of the invention, the monomer is selected from maleic anhydride, maleic acid esters, and mixtures thereof. In another version of the invention, the first amine is an alkylamine, such as tetradecylamine, and the second amine is a polyalkylene polyamine, such as pentaethylenehexamine. In yet another version of the invention, the first amine and the second amine are olefinic or acetylenic amines, such as the reaction products of an alkyldiamine and an acetylenic carboxylic acid. The first amine and the second amine may be the same or different depending on the desired polyamide polymer structure.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Jul 17 00:00:00 EDT 2002},
month = {Wed Jul 17 00:00:00 EDT 2002}
}