Selective catalytic production of linear alpha olefins from lactones and unsaturated carboxylic acids
Abstract
Described is a method to make linear alpha olefins. The method includes the steps of contacting a feedstock having a lactone and/or an unsaturated carboxylic acid with a solid acid catalyst having acidic catalytic sites including Lewis acid catalytic sites, for a time and a temperature wherein at least a fraction of the lactone and/or unsaturated carboxylic acid present in the feedstock is converted into a linear alpha olefin. The method may optionally take place in the presence of water. The solid acid catalyst should preferably have at least 50% Lewis acid catalytic sites.
- Inventors:
- Issue Date:
- Research Org.:
- Wisconsin Alumni Research Foundation, Madison, WI, (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1506947
- Patent Number(s):
- 10,207,960
- Application Number:
- 13/928,811
- Assignee:
- Wisconsin Alumni Research Foundation (Madison, WI)
- DOE Contract Number:
- FC02-07ER64494
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2013 Jun 27
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 59 BASIC BIOLOGICAL SCIENCES
Citation Formats
Dumesic, James Anthony, Wang, Dong, Hakim, Sikander Hussain, and Martin Alonso, David. Selective catalytic production of linear alpha olefins from lactones and unsaturated carboxylic acids. United States: N. p., 2019.
Web.
Dumesic, James Anthony, Wang, Dong, Hakim, Sikander Hussain, & Martin Alonso, David. Selective catalytic production of linear alpha olefins from lactones and unsaturated carboxylic acids. United States.
Dumesic, James Anthony, Wang, Dong, Hakim, Sikander Hussain, and Martin Alonso, David. Tue .
"Selective catalytic production of linear alpha olefins from lactones and unsaturated carboxylic acids". United States. https://www.osti.gov/servlets/purl/1506947.
@article{osti_1506947,
title = {Selective catalytic production of linear alpha olefins from lactones and unsaturated carboxylic acids},
author = {Dumesic, James Anthony and Wang, Dong and Hakim, Sikander Hussain and Martin Alonso, David},
abstractNote = {Described is a method to make linear alpha olefins. The method includes the steps of contacting a feedstock having a lactone and/or an unsaturated carboxylic acid with a solid acid catalyst having acidic catalytic sites including Lewis acid catalytic sites, for a time and a temperature wherein at least a fraction of the lactone and/or unsaturated carboxylic acid present in the feedstock is converted into a linear alpha olefin. The method may optionally take place in the presence of water. The solid acid catalyst should preferably have at least 50% Lewis acid catalytic sites.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {2}
}
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