Strongly hydrogen-bond acidic polymer and methods of making and using
Abstract
The present invention is a sorbent polymer with the (AB)n sequence where the fluorinated interactive A segment is fluoroalkyl-substituted bisphenol and the oligosiloxane B segment is an oligodimethylsiloxane. More specifically, the fluoroalkyl-substituted bisphenol contains two allyl groups and the oligodimethylsiloxane has terminal Si--H groups. The sorbent polymer may be used as thin films on a variety of chemical sensors, or as a component of a thin film on a chemical sensor. Crosslinked sorbent polymers are processable into stable thin films on sensor devices. Sorbent polymers are also useful in sensor arrays, in surface acoustic wave sensors, and in cladding of optical fibers. Sensor arrays provide better selectivity than single sensors and permit identification and quantification of more than one species in a mixture. The sorbent polymer is synthesized by hydrosilylation polymerization which is achieved by catalyzed heating.
- Inventors:
-
- West Richland, WA
- Kennewick, WA
- Issue Date:
- Research Org.:
- Battelle Memorial Institute, Columbus, OH (United States)
- OSTI Identifier:
- 872819
- Patent Number(s):
- 6015869
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08L - COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- DOE Contract Number:
- AC06-76RL01830
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- strongly; hydrogen-bond; acidic; polymer; methods; sorbent; sequence; fluorinated; interactive; segment; fluoroalkyl-substituted; bisphenol; oligosiloxane; oligodimethylsiloxane; specifically; contains; allyl; terminal; si-h; films; variety; chemical; sensors; component; film; sensor; crosslinked; polymers; processable; stable; devices; useful; arrays; surface; acoustic; wave; cladding; optical; fibers; provide; selectivity; single; permit; identification; quantification; species; mixture; synthesized; hydrosilylation; polymerization; achieved; catalyzed; heating; sensor devices; chemical sensors; surface acoustic; sensor array; chemical sensor; acoustic wave; optical fibers; optical fiber; sensor arrays; single sensor; sensor device; catalyzed heat; wave sensor; wave sensors; substituted bis; /528/
Citation Formats
Grate, Jay W, and Kaganove, Steven N. Strongly hydrogen-bond acidic polymer and methods of making and using. United States: N. p., 2000.
Web.
Grate, Jay W, & Kaganove, Steven N. Strongly hydrogen-bond acidic polymer and methods of making and using. United States.
Grate, Jay W, and Kaganove, Steven N. Sat .
"Strongly hydrogen-bond acidic polymer and methods of making and using". United States. https://www.osti.gov/servlets/purl/872819.
@article{osti_872819,
title = {Strongly hydrogen-bond acidic polymer and methods of making and using},
author = {Grate, Jay W and Kaganove, Steven N},
abstractNote = {The present invention is a sorbent polymer with the (AB)n sequence where the fluorinated interactive A segment is fluoroalkyl-substituted bisphenol and the oligosiloxane B segment is an oligodimethylsiloxane. More specifically, the fluoroalkyl-substituted bisphenol contains two allyl groups and the oligodimethylsiloxane has terminal Si--H groups. The sorbent polymer may be used as thin films on a variety of chemical sensors, or as a component of a thin film on a chemical sensor. Crosslinked sorbent polymers are processable into stable thin films on sensor devices. Sorbent polymers are also useful in sensor arrays, in surface acoustic wave sensors, and in cladding of optical fibers. Sensor arrays provide better selectivity than single sensors and permit identification and quantification of more than one species in a mixture. The sorbent polymer is synthesized by hydrosilylation polymerization which is achieved by catalyzed heating.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jan 01 00:00:00 EST 2000},
month = {Sat Jan 01 00:00:00 EST 2000}
}
Works referenced in this record:
Unexpectedly rapid hydrosilation polymerization of the diallyl derivative of bisphenol A and 2,6-diallylphenol
journal, July 1993
- Mathias, Lon J.; Lewis, Charles M.
- Macromolecules, Vol. 26, Issue 15
Hydrogen bonding. Part 18. Gas–liquid chromatographic measurements for the design and selection of some hydrogen bond acidic phases suitable for use as coatings on piezoelectric sorption detectors
journal, January 1991
- Abraham, Michael H.; Hamerton, Ian; Rose, John B.
- J. Chem. Soc., Perkin Trans. 2, Issue 9, p. 1417-1423