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Title: Electrochemical cell with high discharge/charge rate capability

Abstract

A fully charged positive electrode composition for an electrochemical cell includes FeS.sub.2 and NiS.sub.2 in about equal molar amounts along with about 2-20 mole percent of the reaction product Li.sub.2 S. Through selection of appropriate electrolyte compositions, high power output or low operating temperatures can be obtained. The cell includes a substantially constant electrode impedance through most of its charge and discharge range. Exceptionally high discharge rates and overcharge protection are obtainable through use of the inventive electrode composition.

Inventors:
 [1]
  1. Downers Grove, IL
Issue Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
OSTI Identifier:
866513
Patent Number(s):
4728590
Assignee:
United States of America as represented by United States (Washington, DC)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
W-31109-ENG-38
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
electrochemical; cell; discharge; charge; rate; capability; charged; positive; electrode; composition; fes; nis; equal; molar; amounts; 2-20; mole; percent; reaction; product; selection; appropriate; electrolyte; compositions; power; output; operating; temperatures; obtained; substantially; constant; impedance; range; exceptionally; rates; overcharge; protection; obtainable; inventive; electrolyte composition; substantially constant; power output; positive electrode; electrochemical cell; mole percent; reaction product; operating temperature; electrode composition; operating temperatures; overcharge protection; rate capability; discharge rate; charge rate; molar amount; electrolyte compositions; molar amounts; charged positive; /429/252/

Citation Formats

Redey, Laszlo. Electrochemical cell with high discharge/charge rate capability. United States: N. p., 1988. Web.
Redey, Laszlo. Electrochemical cell with high discharge/charge rate capability. United States.
Redey, Laszlo. Fri . "Electrochemical cell with high discharge/charge rate capability". United States. https://www.osti.gov/servlets/purl/866513.
@article{osti_866513,
title = {Electrochemical cell with high discharge/charge rate capability},
author = {Redey, Laszlo},
abstractNote = {A fully charged positive electrode composition for an electrochemical cell includes FeS.sub.2 and NiS.sub.2 in about equal molar amounts along with about 2-20 mole percent of the reaction product Li.sub.2 S. Through selection of appropriate electrolyte compositions, high power output or low operating temperatures can be obtained. The cell includes a substantially constant electrode impedance through most of its charge and discharge range. Exceptionally high discharge rates and overcharge protection are obtainable through use of the inventive electrode composition.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Jan 01 00:00:00 EST 1988},
month = {Fri Jan 01 00:00:00 EST 1988}
}