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Title: Ternary compound electrode for lithium cells

Abstract

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.

Inventors:
 [1];  [2];  [2]
  1. Menlo Park, CA
  2. Stanford, CA
Issue Date:
Research Org.:
Stanford Univ., CA (United States)
OSTI Identifier:
864276
Patent Number(s):
4340652
Assignee:
United States of America as represented by United States (Washington, DC)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AC02-77ET25402
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
ternary; compound; electrode; lithium; cells; lithium-based; promising; applications; electric; vehicles; load-leveling; power; plants; electropositive; light; weight; type; cell; utilizes; molten; salt; electrolyte; normally; operated; temperature; range; 350; degree; -500; operation; accelerates; corrosion; provides; electrochemical; electroactive; species; positive; represented; li-m-o; transition; metal; inventive; considerably; reduced; cell utilizes; temperature operation; power plants; light weight; electric vehicle; positive electrode; temperature range; electrochemical cell; molten salt; transition metal; power plant; salt electrolyte; electric vehicles; accelerates corrosion; lithium-based cells; operation accelerates; ternary compound; active species; lithium-based cell; lithium cells; /429/252/

Citation Formats

Raistrick, Ian D, Godshall, Ned A, and Huggins, Robert A. Ternary compound electrode for lithium cells. United States: N. p., 1982. Web.
Raistrick, Ian D, Godshall, Ned A, & Huggins, Robert A. Ternary compound electrode for lithium cells. United States.
Raistrick, Ian D, Godshall, Ned A, and Huggins, Robert A. Fri . "Ternary compound electrode for lithium cells". United States. https://www.osti.gov/servlets/purl/864276.
@article{osti_864276,
title = {Ternary compound electrode for lithium cells},
author = {Raistrick, Ian D and Godshall, Ned A and Huggins, Robert A},
abstractNote = {Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Jan 01 00:00:00 EST 1982},
month = {Fri Jan 01 00:00:00 EST 1982}
}