Lithium metal oxide electrodes for lithium cells and batteries

Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kim, Jaekook

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Title: Lithium metal oxide electrodes for lithium cells and batteries

Abstract

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2M'O.sub.3 in which 0<1, and where M is more than one ion with an average trivalent oxidation state and with at least one ion being Ni, and where M' is one or more ions with an average tetravalent oxidation state. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

Inventors:: Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kim, Jaekook

Issue Date:: 2006-11-14

Research Org.:: UChicago Argonne LLC, Chicago, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1175985

Patent Number(s):: 7135252

Application Number:: 10/688,004

Assignee:: UChicago Argonne LLC (Chicago, IL)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G23/003 - {Titanates
C01G25/006 - {Compounds containing, besides zirconium, two or more other elements, with the exception of oxygen or hydrogen}
C01G45/1221 - {Manganates or manganites with a manganese oxidation state of Mn
C01G45/1228 - {of the type [MnO2]n- , e.g. LiMnO2, Li[MxMn1-x]O2}
C01G45/1257 - {containing lithium, e.g. Li2MnO3, Li2[MxMn1-xO3}
C01G53/42 - {containing alkali metals, e.g. LiNiO2}
C01G53/44 - {containing manganese}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/22 - layered hydroxide-type, e.g. of the hydrotalcite-type
C01P2002/52 - containing elements as dopants
C01P2002/72 - by d-values or two theta-values, e.g. as X-ray diagram
C01P2004/82 - two phases having the same anion, e.g. both oxidic phases
C01P2006/40 - Electric properties

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M2004/021 - {Physical characteristics, e.g. porosity, surface area}
H01M4/485 - of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: W-31-109-ENG-38

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Thackeray, Michael M., Johnson, Christopher S., Amine, Khalil, and Kim, Jaekook. Lithium metal oxide electrodes for lithium cells and batteries.  United States: N. p., 2006. 
        Web.

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                    Thackeray, Michael M., Johnson, Christopher S., Amine, Khalil, & Kim, Jaekook. Lithium metal oxide electrodes for lithium cells and batteries.  United States.

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                    Thackeray, Michael M., Johnson, Christopher S., Amine, Khalil, and Kim, Jaekook. Tue .  
        "Lithium metal oxide electrodes for lithium cells and batteries".  United States.  https://www.osti.gov/servlets/purl/1175985.

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@article{osti_1175985,

  title        = {Lithium metal oxide electrodes for lithium cells and batteries},

  author       = {Thackeray, Michael M. and Johnson, Christopher S. and Amine, Khalil and Kim, Jaekook},

  abstractNote = {A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2M'O.sub.3 in which 0<1, and where M is more than one ion with an average trivalent oxidation state and with at least one ion being Ni, and where M' is one or more ions with an average tetravalent oxidation state. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2006},

  month        = {11}

}

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Works referenced in this record:

Synthesis and Structural Characterization of a Novel Layered Lithium Manganese Oxide, Li0.36Mn0.91O2, and Its Lithiated Derivative, Li1.09Mn0.91O2
journal, June 1993

Rossouw, M. H.; Liles, D. C.; Thackeray, M. M.
Journal of Solid State Chemistry, Vol. 104, Issue 2
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Characterization of Layered Lithium Nickel Manganese Oxides Synthesized by a Novel Oxidative Coprecipitation Method and Their Electrochemical Performance as Lithium Insertion Electrode Materials
journal, January 1998

Spahr, Michael E.
Journal of The Electrochemical Society, Vol. 145, Issue 4
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The Layered Intercalation Compounds Li(Mn1−yCoy)O2: Positive Electrode Materials for Lithium–Ion Batteries
journal, July 1999

Armstrong, A. Robert; Robertson, Alastair D.; Gitzendanner, Robert
Journal of Solid State Chemistry, Vol. 145, Issue 2
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The intercalation compound Li(Mn0.9Co0.1)O2 as a positive electrode for rechargeable lithium batteries
journal, January 1998

Robert Armstrong, A.; Gitzendanner, Robert
Chemical Communications, Issue 17
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Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries
journal, January 2001

Lu, Zhonghua; MacNeil, D. D.; Dahn, J. R.
Electrochemical and Solid-State Letters, Vol. 4, Issue 11
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Layered Lithium Insertion Material of LiCo _1/3 Ni _1/3 Mn _1/3 O ₂ for Lithium-Ion Batteries
journal, July 2001

Ohzuku, Tsutomu; Makimura, Yoshinari
Chemistry Letters, Vol. 30, Issue 7
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Preparation and electrochemical properties of layered lithium–cobalt–manganese oxides
journal, March 1999

Numata, K.
Solid State Ionics, Vol. 118, Issue 1-2
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Structure and electrochemistry of LixMnyNi1−yO2
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Rossen, E.; Jones, C.; Dahn, J.
Solid State Ionics, Vol. 57, Issue 3-4
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Structural and electrochemical analysis of layered compounds from Li2MnO3
journal, September 1999

Johnson, C. S.; Korte, S. D.; Vaughey, J. T.
Journal of Power Sources, Vol. 81-82
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Morphology Effects on the Electrochemical Performance of LiNi1 − x Co x O 2
journal, August 1997

Li, W.; Currie, J. C.
Journal of The Electrochemical Society, Vol. 144, Issue 8
https://doi.org/10.1149/1.1837894

Novel LiNi[sub 1−x]Ti[sub x/2]Mg[sub x/2]O[sub 2] Compounds as Cathode Materials for Safer Lithium-Ion Batteries
journal, January 1999

Gao, Yuan
Electrochemical and Solid-State Letters, Vol. 1, Issue 3
https://doi.org/10.1149/1.1390656

Preparation of Li Mn Ni1−O2 as a cathode for lithium-ion batteries
journal, July 1998

Yoshio, Masaki; Todorov, Yanko; Yamato, Kohji
Journal of Power Sources, Vol. 74, Issue 1
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Lithium nickelate electrodes with enhanced high-temperature performance and thermal stability
journal, September 2000

Arai, Hajime; Tsuda, Masayuki; Sakurai, Yoji
Journal of Power Sources, Vol. 90, Issue 1
https://doi.org/10.1016/S0378-7753(00)00451-1

LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density
journal, June 1980

Mizushima, K.; Jones, P. C.; Wiseman, P. J.
Materials Research Bulletin, Vol. 15, Issue 6
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Rechargeable cathodes based on Li₂Cr_xMn_2−xO₄
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Lithium manganese oxides from Li2MnO3 for rechargeable lithium battery applications
journal, June 1991

Rossouw, Mh; Thackeray, Mm
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Similar Records

Title: Lithium metal oxide electrodes for lithium cells and batteries

Abstract

Citation Formats

Synthesis and Structural Characterization of a Novel Layered Lithium Manganese Oxide, Li0.36Mn0.91O2, and Its Lithiated Derivative, Li1.09Mn0.91O2 journal, June 1993

Characterization of Layered Lithium Nickel Manganese Oxides Synthesized by a Novel Oxidative Coprecipitation Method and Their Electrochemical Performance as Lithium Insertion Electrode Materials journal, January 1998

The Layered Intercalation Compounds Li(Mn1−yCoy)O2: Positive Electrode Materials for Lithium–Ion Batteries journal, July 1999

The intercalation compound Li(Mn0.9Co0.1)O2 as a positive electrode for rechargeable lithium batteries journal, January 1998

Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries journal, January 2001

Layered Lithium Insertion Material of LiCo 1/3 Ni 1/3 Mn 1/3 O 2 for Lithium-Ion Batteries journal, July 2001

Preparation and electrochemical properties of layered lithium–cobalt–manganese oxides journal, March 1999

Structure and electrochemistry of LixMnyNi1−yO2 journal, October 1992

Structural and electrochemical analysis of layered compounds from Li2MnO3 journal, September 1999

Morphology Effects on the Electrochemical Performance of LiNi1 − x Co x O 2 journal, August 1997

Novel LiNi[sub 1−x]Ti[sub x/2]Mg[sub x/2]O[sub 2] Compounds as Cathode Materials for Safer Lithium-Ion Batteries journal, January 1999

Preparation of Li Mn Ni1−O2 as a cathode for lithium-ion batteries journal, July 1998

Lithium nickelate electrodes with enhanced high-temperature performance and thermal stability journal, September 2000

LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density journal, June 1980

Rechargeable cathodes based on Li2CrxMn2−xO4 journal, April 1995

Lithium manganese oxides from Li2MnO3 for rechargeable lithium battery applications journal, June 1991

Synthesis and Structural Characterization of a Novel Layered Lithium Manganese Oxide, Li0.36Mn0.91O2, and Its Lithiated Derivative, Li1.09Mn0.91O2
journal, June 1993

Characterization of Layered Lithium Nickel Manganese Oxides Synthesized by a Novel Oxidative Coprecipitation Method and Their Electrochemical Performance as Lithium Insertion Electrode Materials
journal, January 1998

The Layered Intercalation Compounds Li(Mn1−yCoy)O2: Positive Electrode Materials for Lithium–Ion Batteries
journal, July 1999

The intercalation compound Li(Mn0.9Co0.1)O2 as a positive electrode for rechargeable lithium batteries
journal, January 1998

Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries
journal, January 2001

Layered Lithium Insertion Material of LiCo _1/3 Ni _1/3 Mn _1/3 O ₂ for Lithium-Ion Batteries
journal, July 2001

Preparation and electrochemical properties of layered lithium–cobalt–manganese oxides
journal, March 1999

Structure and electrochemistry of LixMnyNi1−yO2
journal, October 1992

Structural and electrochemical analysis of layered compounds from Li2MnO3
journal, September 1999

Morphology Effects on the Electrochemical Performance of LiNi1 − x Co x O 2
journal, August 1997

Novel LiNi[sub 1−x]Ti[sub x/2]Mg[sub x/2]O[sub 2] Compounds as Cathode Materials for Safer Lithium-Ion Batteries
journal, January 1999

Preparation of Li Mn Ni1−O2 as a cathode for lithium-ion batteries
journal, July 1998

Lithium nickelate electrodes with enhanced high-temperature performance and thermal stability
journal, September 2000

LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density
journal, June 1980

Rechargeable cathodes based on Li₂Cr_xMn_2−xO₄
journal, April 1995

Lithium manganese oxides from Li2MnO3 for rechargeable lithium battery applications
journal, June 1991