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Title: Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups

Abstract

The disclosure provides for metal organic frameworks (MOFs) which comprise a plurality of SBUs comprising different metals or metal ions and/or a plurality of organic linking moieties comprising different functional groups.

Inventors:
; ; ;
Issue Date:
Research Org.:
Univ. of California, Oakland, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1491835
Patent Number(s):
10087205
Application Number:
15/128,225
Assignee:
The Regents of the University of California (Oakland, CA)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
DOE Contract Number:  
DE-AR0000185
Resource Type:
Patent
Resource Relation:
Patent File Date: 2015 Mar 27
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Yaghi, Omar M., Suzuki, Mitsuharu, Deng, Hexiang, and Wang, Lisa. Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups. United States: N. p., 2018. Web.
Yaghi, Omar M., Suzuki, Mitsuharu, Deng, Hexiang, & Wang, Lisa. Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups. United States.
Yaghi, Omar M., Suzuki, Mitsuharu, Deng, Hexiang, and Wang, Lisa. Tue . "Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups". United States. https://www.osti.gov/servlets/purl/1491835.
@article{osti_1491835,
title = {Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups},
author = {Yaghi, Omar M. and Suzuki, Mitsuharu and Deng, Hexiang and Wang, Lisa},
abstractNote = {The disclosure provides for metal organic frameworks (MOFs) which comprise a plurality of SBUs comprising different metals or metal ions and/or a plurality of organic linking moieties comprising different functional groups.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Oct 02 00:00:00 EDT 2018},
month = {Tue Oct 02 00:00:00 EDT 2018}
}

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Polycatenation, polythreading and polyknotting in coordination network chemistry
journal, November 2003


What do we know about three-periodic nets?
journal, August 2005


Crystalline Covalent Organic Frameworks with Hydrazone Linkages
journal, August 2011

  • Uribe-Romo, Fernando J.; Doonan, Christian J.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 133, Issue 30, p. 11478-11481
  • https://doi.org/10.1021/ja204728y

Crystal Structure, Dissolution, and Deposition of a 5 nm Functionalized Metal−Organic Great Rhombicuboctahedron
journal, July 2006


Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology
journal, August 2003


Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011


Raman Spectroscopic Investigation of CH4 and N2 Adsorption in Metal−Organic Frameworks
journal, July 2007


Process for the alkoxylation of organic compounds in the presence of novel framework materials
patent-application, April 2003


Docking in Metal-Organic Frameworks
journal, August 2009


Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks
journal, March 2005


Reticular synthesis and the design of new materials
journal, June 2003


Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006


Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
journal, September 2008


Reversible Interpenetration in a Metal-Organic Framework Triggered by Ligand Removal and Addition
journal, July 2012


From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites
journal, March 1999


Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake
journal, August 2011


Process for the alkoxylation of monools in the presence of metallo-organic framework materials
patent-application, June 2006


Improved Designs of Metal-Organic Frameworks for Hydrogen Storage
journal, July 2007


Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
journal, May 2005

  • Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W.
  • Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118
  • https://doi.org/10.1021/ja042802q

Construction of a new open-framework solid from 1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks
journal, January 1997

  • Yaghi, Omar M.; Jernigan, Ryan; Li, Hailian
  • Journal of the Chemical Society, Dalton Transactions, Vol. 0, Issue 14, p. 2383-2384
  • https://doi.org/10.1039/a702287e

CRYSTALLINE 3D- AND 2D COVALENT ORGANIC FRAMEWORKS
patent-application, June 2010


Non-regenerating carbon monoxide sensor
patent, March 1998


High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture
journal, February 2008


Zeolitic imidazolate framework materials: recent progress in synthesis and applications
journal, January 2014


Gas storage system
patent, December 2007


Syntheses, Structures, and Porous/Luminescent Properties of Silver 3-Alkyl-1,2,4-Triazolate Frameworks with Rare 3-Connected Topologies
journal, March 2011


A new structure type in polyoxoanion chemistry: synthesis and structure of the V5O143- anion
journal, June 1989


MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF
journal, September 2007


A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate–Metal Organic Framework for Aerobic Decontamination
journal, October 2011


Polymer-Induced Heteronucleation for the Discovery of New Extended Solids
journal, April 2006


A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004


Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions
journal, September 2005


A Microporous Metal–Organic Framework for Gas-Chromatographic Separation of Alkanes
journal, February 2006


Carbon Dioxide Capture and Storage Using Open Frameworks
patent-application, May 2012


Directed Transformation of Molecules to Solids: Synthesis of a Microporous Sulfide from Molecular Germanium Sulfide Cages
journal, January 1994


Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework
journal, October 2011

  • Gassensmith, Jeremiah J.; Furukawa, Hiroyasu; Smaldone, Ronald A.
  • Journal of the American Chemical Society, Vol. 133, Issue 39, p. 15312-15315
  • https://doi.org/10.1021/ja206525x

Post-Synthetic Modification of Tagged Metal-Organic Frameworks
journal, October 2008


20 Å Cd4In16S3514- Supertetrahedral T4 Clusters as Building Units in Decorated Cristobalite Frameworks
journal, May 2001


Structural study of new hydrocarbon nano-crystals by energy-filtered electron diffraction
journal, January 2004


Characterization of H2 Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering
journal, October 2005

  • Rowsell, Jesse L. C.; Eckert, Juergen; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 127, Issue 42, p. 14904-14910
  • https://doi.org/10.1021/ja0542690

Metal-organic frameworks with exceptionally large pore aperatures
patent, July 2015


Bone graft composition
patent-application, October 2007


Metal-Organic Frameworks from Edible Natural Products
journal, August 2010


Isoreticular Expansion of Metal–Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals
journal, September 2011


Gas Sensor Incorporating a Porous Framework
patent-application, February 2012


Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks
journal, January 2008


Ge2ZrO6F2·(H2DAB)H2O:1  A 4-Connected Microporous Material with “Bow Tie” Building Units and an Exceptional Proportion of 3-Rings
journal, December 2000


A Thermally Stable Pt/Y-Based Metal−Organic Framework:  Exploring the Accessibility of the Metal Centers with Spectroscopic Methods Using H2O, CH3OH, and CH3CN as Probes
journal, November 2006


The CdSO4, rutile, cooperite and quartz dual nets: interpenetration and catenation
journal, January 2003


Preparation of metal-catecholate frameworks
patent, June 2014


Metal–organic frameworks: a new class of porous materials
journal, August 2004


Ammonia Vapor Removal by Cu3(BTC)2 and Its Characterization by MAS NMR
journal, August 2009


Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D Structure
journal, April 2008


Synthesis and characterization of a soluble oxide inclusion complex, [CH3CNC(V12O324-)]
journal, July 1989


Robust dynamics
journal, May 2010


Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012


Exceptional Framework Flexibility and Sorption Behavior of a Multifunctional Porous Cuprous Triazolate Framework
journal, May 2008


Gas Odorous Substance Separation
patent-application, August 2008


[Cd16In64S134]44-: 31-Å Tetrahedron with a Large Cavity
journal, April 2003


Polymeric Foams with Nanocellular Morphology and Methods for Making Them
patent-application, October 2009


Late transition metal catalyst complexes and oligomers therefrom
patent, December 2002


One-Step Synthesis and Structure of an Oligo(spiro-orthocarbonate)
journal, May 2002

  • Vodak, David T.; Braun, Matthew; Iordanidis, Lykourgos
  • Journal of the American Chemical Society, Vol. 124, Issue 18, p. 4942-4943
  • https://doi.org/10.1021/ja017683i

Hydrogen-Bonded Complexes of Aromatic Crown Ethers with (9-Anthracenyl)methylammonium Derivatives. Supramolecular Photochemistry and Photophysics. pH-Controllable Supramolecular Switching
journal, November 1997

  • Ashton, Peter R.; Ballardini, Roberto; Balzani, Vincenzo
  • Journal of the American Chemical Society, Vol. 119, Issue 44, p. 10641-10651
  • https://doi.org/10.1021/ja9715760

MOF-74 building unit has a direct impact on toxic gas adsorption
journal, January 2011


Mapping of Functional Groups in Metal-Organic Frameworks
journal, July 2013


Metal-organic polyhedra
patent-application, June 2005


Crystalline membranes
patent-application, January 2005


Heterogeneity within Order in Crystals of a Porous Metal–Organic Framework
journal, August 2011


A General Thermolabile Protecting Group Strategy for Organocatalytic Metal−Organic Frameworks
journal, April 2011


Layered Structures Constructed from New Linkages of Ge7(O,OH,F)19 Clusters
journal, February 2003


Photoluminescent Metal−Organic Polymer Constructed from Trimetallic Clusters and Mixed Carboxylates
journal, February 2003


Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
journal, February 2010


In Situ Hydrothermal Growth of Metal−Organic Framework 199 Films on Stainless Steel Fibers for Solid-Phase Microextraction of Gaseous Benzene Homologues
journal, December 2009


Mesh-Adjustable Molecular Sieve
patent-application, August 2008


Role of Copper Species in the Oxidative Dimerization of Arylboronic Acids: Synthesis of Symmetrical Biaryls
journal, December 2003


Rotaxanes as ligands: from molecules to materials
journal, January 2007


Process for preparing and organometallic framework material
patent, August 2008


Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs
journal, May 2008


A Catenated Strut in a Catenated Metal-Organic Framework
journal, August 2010


Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
journal, April 2012


Large Free Volume in Maximally Interpenetrating Networks:  The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO]1
journal, May 2000


Role of Exposed Metal Sites in Hydrogen Storage in MOFs
journal, July 2008


A High-Throughput Investigation of the Role of pH, Temperature, Concentration, and Time on the Synthesis of Hybrid Inorganic-Organic Materials
journal, November 2005


Reticular Synthesis of Covalent Organic Borosilicate Frameworks
journal, September 2008

  • Hunt, Joseph R.; Doonan, Christian J.; LeVangie, James D.
  • Journal of the American Chemical Society, Vol. 130, Issue 36, p. 11872-11873
  • https://doi.org/10.1021/ja805064f

Rhenium-selenium-chlorine solid phases: cluster excision and core substitution reactions of molecular species
journal, November 1992


An Efficient High Yielding Approach for the Homocoupling of Aryl Boronic Acids
journal, January 2002


PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS
patent-application, August 2007


A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst
journal, August 2002


Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007


Zeolite synthesis using an alcohol or like molecules
patent, November 1992


Taxonomy of periodic nets and the design of materials
journal, January 2007


Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties
journal, February 2000


Synthesis of inorganic membranes on supports
patent, July 1998


Process for preparing an organometallic framework material
patent-application, July 2005


Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links
journal, September 2005