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Title: Compositions and methods comprising conductive metal organic frameworks and uses thereof

Abstract

Compositions and methods comprising metal organic frameworks (MOFs) and related uses are generally provided. In some embodiments, a MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two sets of ortho-diimine groups arranged about an organic core.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1771577
Patent Number(s):
10822364
Application Number:
16/240,629
Assignee:
Massachusetts Institute of Technology (Cambridge, MA)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
DOE Contract Number:  
SC0001088; SC0006937
Resource Type:
Patent
Resource Relation:
Patent File Date: 01/04/2019
Country of Publication:
United States
Language:
English

Citation Formats

Dinca, Mircea, Sheberla, Dennis, Sun, Lei, Wade, Casey R., and Campbell, Michael Glenn. Compositions and methods comprising conductive metal organic frameworks and uses thereof. United States: N. p., 2020. Web.
Dinca, Mircea, Sheberla, Dennis, Sun, Lei, Wade, Casey R., & Campbell, Michael Glenn. Compositions and methods comprising conductive metal organic frameworks and uses thereof. United States.
Dinca, Mircea, Sheberla, Dennis, Sun, Lei, Wade, Casey R., and Campbell, Michael Glenn. Tue . "Compositions and methods comprising conductive metal organic frameworks and uses thereof". United States. https://www.osti.gov/servlets/purl/1771577.
@article{osti_1771577,
title = {Compositions and methods comprising conductive metal organic frameworks and uses thereof},
author = {Dinca, Mircea and Sheberla, Dennis and Sun, Lei and Wade, Casey R. and Campbell, Michael Glenn},
abstractNote = {Compositions and methods comprising metal organic frameworks (MOFs) and related uses are generally provided. In some embodiments, a MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two sets of ortho-diimine groups arranged about an organic core.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {11}
}

Works referenced in this record:

Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π-Nanosheet: A Potential Organic Two-Dimensional Topological Insulator
journal, October 2014


Crystallisation Facilitators for the Synthesis of Metal Organic Frameworks
patent-application, August 2013


Application of absorption heat pumps to multi-effect distillation: a case study of solar desalination
journal, June 2007


Water Sorption Cycle Measurements on Functionalized MIL-101Cr for Heat Transformation Application
journal, February 2013


Methane storage in advanced porous materials
journal, January 2012


Prediction of a Two-Dimensional Organic Topological Insulator
journal, May 2013


Metal-Organic Frameworks: Opportunities for Catalysis
journal, September 2009


Selective Propene Oligomerization with Nickel(II)-Based Metal–Organic Frameworks
journal, January 2014


Metal-Organic Frameworks for Sensing Applications in the Gas Phase
journal, March 2009


Water adsorption characteristics of novel materials for heat transformation applications
journal, September 2010


Single-Walled Carbon Nanotube–Metalloporphyrin Chemiresistive Gas Sensor Arrays for Volatile Organic Compounds
journal, May 2015


Dimerization of ethylene to butene-1 catalyzed by Ti(OR')4-AlR3
journal, November 1993


High volumetric uptake of ammonia using Cu-MOF-74/Cu-CPO-27
journal, January 2016


Evaluation of Commercial Off-the-Shelf Ammonia Sorbents and Carbon Monoxide Oxidation Catalysts
conference, June 2008


Design of Hydrophilic Metal Organic Framework Water Adsorbents for Heat Reallocation
journal, July 2015


Measuring and Reporting Electrical Conductivity in Metal–Organic Frameworks: Cd 2 (TTFTB) as a Case Study
journal, October 2016


Single-Site Organozirconium Catalyst Embedded in a Metal–Organic Framework
journal, December 2015


Optimised room temperature, water-based synthesis of CPO-27-M metal–organic frameworks with high space-time yields
journal, January 2015


Metal-Organic Frameworks (MOF) for Gas Capture
patent-application, February 2015


Multicycle water vapour stability of microporous breathing MOF aluminium isophthalate CAU-10-H
journal, January 2014


A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
journal, September 2005


MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification
journal, March 2013


Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks
journal, October 2015


Conductive MOF electrodes for stable supercapacitors with high areal capacitance
journal, October 2016


Highly active self-immobilized FI-Zr catalysts in a PCP framework for ethylene polymerization
journal, January 2015


Catalyst Precursors, Catalysts and Methods of Producing the Same
patent-application, December 2011


Cation exchange at the secondary building units of metal–organic frameworks
journal, January 2014


The Performance of Small-Pore Microporous Aluminophosphates in Low-Temperature Solar Energy Storage: The Structure-Property Relationship
journal, February 2012


High thermal and chemical stability in pyrazolate-bridged metal–organic frameworks with exposed metal sites
journal, January 2011


Metal organic frameworks based on aluminum, iron and chromium
patent, February 2013


Heterogeneous Single-Site Catalysts for Olefin Polymerization
journal, April 2000


Enhanced ammonia adsorption on functionalized nanoporous carbons
journal, December 2015


Enhanced heat mirror films
patent, May 2007


Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates
journal, June 2009


Tris(pyrazolyl)methane–chromium(III) complexes as highly active catalysts for ethylene polymerization
journal, December 2006


Supported single-site catalysts for slurry and gas-phase olefin polymerisation
journal, June 2011


Adsorption Sites and Binding Nature of CO 2 in Prototypical Metal−Organic Frameworks: A Combined Neutron Diffraction and First-Principles Study
journal, June 2010


Solvent-Dependent Cation Exchange in Metal-Organic Frameworks
journal, April 2014


Water Adsorption Characteristics of MIL-101 for Heat-Transformation Applications of MOFs
journal, December 2010


First-principles design of a half-filled flat band of the kagome lattice in two-dimensional metal-organic frameworks
journal, August 2016


Toward Understanding Reactive Adsorption of Ammonia on Cu-MOF/Graphite Oxide Nanocomposites
journal, November 2011


MOFs as Adsorbents for Low Temperature Heating and Cooling Applications
journal, March 2009


Electrically Conductive Porous Metal-Organic Frameworks
journal, January 2016


Gas Storage and Release Using Piezoelectric Materials
patent-application, December 2010


Compositions and Methods or Selective Olefin Oligomerization Comprising Metal Organic Frameworks
patent-application, September 2018


Heterogeneous Epoxide Carbonylation by Cooperative Ion-Pair Catalysis in Co(CO) 4 -Incorporated Cr-MIL-101
journal, March 2017


Metal-Organic Framework Catalysts and Their Use in Hydrocarbon Transformation
patent-application, December 2008


The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013


Selective, Adsorbate-induced Spin State Changes in Transition Metal-based Metal-organic Frameworks
patent-application, February 2019


MFU-4 - A Metal-Organic Framework for Highly Effective H 2 /D 2 Separation
journal, November 2012


Facile Deposition of Multicolored Electrochromic Metal-Organic Framework Thin Films
journal, October 2013


Practical β-Lactone Synthesis:  Epoxide Carbonylation at 1 atm
journal, August 2006


Compositions and Methods Comprising Porous Metal Organic Frameworks and Related Uses
patent-application, November 2014


Drastic Enhancement of Catalytic Activity via Post-oxidation of a Porous Mn II Triazolate Framework
journal, July 2014


Programming MOFs for water sorption: amino-functionalized MIL-125 and UiO-66 for heat transformation and heat storage applications
journal, January 2013


A review on adsorption working pairs for refrigeration
journal, April 2009


Adsorption-Driven Heat Pumps: The Potential of Metal–Organic Frameworks
journal, October 2015


Single-Crystal to Single-Crystal Mechanical Contraction of Metal–Organic Frameworks through Stereoselective Postsynthetic Bromination
journal, July 2015


Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011


Ethylene Polymerization Behavior of Tris(pyrazolyl)borate Titanium(IV) Complexes
journal, March 2002


Receptor Function and Response of Semiconductor Gas Sensor
journal, January 2009


Intermolecularly Bound Transition Element Complexes for Oxygen-selective Adsorption
patent-application, June 2001


Mesoporous Metal-Organic Framework
patent-application, August 2008


Hydrogenstorage in water-stable metal–organic frameworks incorporating 1,3- and 1,4-benzenedipyrazolate
journal, January 2010


Conductivity, Doping, and Redox Chemistry of a Microporous Dithiolene-Based Metal−Organic Framework
journal, July 2010


Specific and non-specific interactions between ammonia and activated carbons
journal, January 2004


Selective Turn-On Ammonia Sensing Enabled by High-Temperature Fluorescence in Metal–Organic Frameworks with Open Metal Sites
journal, August 2013


Compositions and Methods for Olefin Polymerization Comprising Metal Organic Frameworks
patent-application, September 2018


Water and methanol adsorption on MOFs for cycling heat transformation processes
journal, January 2014


Gas Adsorption on Metal-Organic Frameworks
patent-application, March 2010


When the Solvent Locks the Cage: Theoretical Insight into the Transmetalation of MOF-5 Lattices and Its Kinetic Limitations
journal, April 2015


Carbonylation of heterocycles by homogeneous catalysts
journal, January 2007


MOFs for Use in Adsorption Heat Pump Processes
journal, December 2011


Functionalization of Organic Molecules Using Metal-organic Frameworks (MOFS) As Catalysts
patent-application, January 2014


Process for Beta-lactone Production
patent-application, April 2016


Single-Ion Li + , Na + , and Mg 2+ Solid Electrolytes Supported by a Mesoporous Anionic Cu–Azolate Metal–Organic Framework
journal, September 2017


Fundamental and application aspects of adsorption cooling and desalination
journal, March 2016


Nickel-based solid catalysts for ethylene oligomerization – a review
journal, January 2014


A Readily Synthesized and Highly Active Epoxide Carbonylation Catalyst Based on a Chromium Porphyrin Framework:  Expanding the Range of Available β-Lactones
journal, February 2004


An overview on adsorption pairs for cooling
journal, March 2013


Chromium(III) Octaethylporphyrinato Tetracarbonylcobaltate:  A Highly Active, Selective, and Versatile Catalyst for Epoxide Carbonylation
journal, August 2005


New synthesis of chromium trichloride tetrahydrofuranate
journal, February 1989


Cu 3 (hexaiminotriphenylene) 2 : An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing
journal, February 2015


Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008

  • Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
  • https://doi.org/10.1021/ja8036096

Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework
journal, August 2016


Reversible Capture and Release of Cl 2 and Br 2 with a Redox-Active Metal–Organic Framework
journal, April 2017


Ethylene Oligomerization Over Heterogeneous Catalysts
journal, September 2014


Compositions Comprising Metal Organic Frameworks for the Uptake of Compounds and Related Methods
patent-application, November 2017


Adsorption of NH3 onto activated carbon prepared from palm shells impregnated with H2SO4
journal, January 2005


MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application
journal, January 2012


Optimization of adsorption processes for climate control and thermal energy storage
journal, October 2014


Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
journal, March 2014


Techno-economic Analysis of Metal–Organic Frameworks for Hydrogen and Natural Gas Storage
journal, January 2017


Ti 3+ -, V 2+/3+ -, Cr 2+/3+ -, Mn 2+ -, and Fe 2+ -Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5
journal, August 2013


A New Multicomponent Reaction Catalyzed by a [Lewis Acid] + [Co(CO) 4 ] - Catalyst:  Stereospecific Synthesis of 1,3-Oxazinane-2,4-diones from Epoxides, Isocyanates, and CO
journal, July 2007


MOF-based electronic and opto-electronic devices
journal, January 2014


Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues
journal, July 2015


Experimental investigation of the silica gel–water adsorption isotherm characteristics
journal, November 2001


Hydrogen Storage in Metal–Organic Frameworks
journal, September 2011


π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet
journal, February 2013


Materials for Gas Capture, Methods of Making Materials for Gas Capture, and Methods of Capturing Gas
patent-application, June 2013


Elucidating Gating Effects for Hydrogen Sorption in MFU-4-Type Triazolate-Based Metal-Organic Frameworks Featuring Different Pore Sizes
journal, January 2011


Temperature-Triggered Collection and Release of Water from Fogs by a Sponge-Like Cotton Fabric
journal, January 2013


Post-Metallocenes in the Industrial Production of Polyolefins
journal, August 2014


The role of sulfur-containing groups in ammonia retention on activated carbons
journal, March 2010


New Porous Crystals of Extended Metal-Catecholates
journal, August 2012


Reductive Electrosynthesis of Crystalline Metal–Organic Frameworks
journal, August 2011


Highly Selective Nickel Ethylene Oligomerization Catalysts Based on Sterically Hindered Tris(pyrazolyl)borate Ligands
journal, November 2003


Ammonia Capture in Porous Organic Polymers Densely Functionalized with Brønsted Acid Groups
journal, January 2014

  • Van Humbeck, Jeffrey F.; McDonald, Thomas M.; Jing, Xiaofei
  • Journal of the American Chemical Society, Vol. 136, Issue 6, p. 2432-2440
  • https://doi.org/10.1021/ja4105478

Effect of Water Adsorption on Retention of Structure and Surface Area of Metal–Organic Frameworks
journal, April 2012


The Myth of Nickel(III) and Nickel(IV) in Planar Complexes 1
journal, July 1965


Transition Metal Complexes Supported on Metal-Organic Frameworks for Heterogeneous Catalysts
patent-application, February 2016


A series of isoreticular chiral metal–organic frameworks as a tunable platform for asymmetric catalysis
journal, July 2010


Reversible gas-phase redox processes catalyzed by Co-exchanged MFU-4l(arge)
journal, January 2012


Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method
journal, June 2012


Catalytic oligomerization of ethylene over Ni-containing dealuminated Y zeolites
journal, February 2006


An electroactive porous network from covalent metal–dithiolene links
journal, January 2014


High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework
journal, July 2012


Process for the Separation of Unbranched Hydrocarbons from their Branched Isomers
patent-application, August 2010


Organic topological insulators in organometallic lattices
journal, February 2013


Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999


Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011


Water adsorption in MOFs: fundamentals and applications
journal, January 2014


Evaluation of alternative refrigerant—adsorbent pairs for refrigeration cycles
journal, November 1996


A review of potential materials for thermal energy storage in building applications
journal, February 2013


Process for Coating a Support Surface with a Porous Metal-Organic Framework
patent-application, June 2012


Structure–property relationships of water adsorption in metal–organic frameworks
journal, January 2014


Metal–Organic Frameworks in Adsorption-Driven Heat Pumps: The Potential of Alcohols as Working Fluids
journal, November 2015


“Bound but Not Gagged”Immobilizing Single-Site α-Olefin Polymerization Catalysts
journal, November 2005


Synthesis of β-Lactones:  A Highly Active and Selective Catalyst for Epoxide Carbonylation
journal, February 2002

  • Getzler, Yutan D. Y. L.; Mahadevan, Viswanath; Lobkovsky, Emil B.
  • Journal of the American Chemical Society, Vol. 124, Issue 7, p. 1174-1175
  • https://doi.org/10.1021/ja017434u

Destruction of chemical warfare agents using metal–organic frameworks
journal, March 2015


Broadly Hysteretic H 2 Adsorption in the Microporous Metal−Organic Framework Co(1,4-benzenedipyrazolate)
journal, June 2008


High gas adsorption metal-organic framework
patent, February 2010


Adjusting the Stability of Metal–Organic Frameworks under Humid Conditions by Ligand Functionalization
journal, October 2012


Olefin Oligomerization Method Involving a Catalytic System Based on Organometallic Complexes and a Porous Solid
patent-application, June 2011


Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices
journal, December 2013


A Homochiral Porous Metal−Organic Framework for Highly Enantioselective Heterogeneous Asymmetric Catalysis
journal, June 2005


π-Electron Conjugation in Two Dimensions
journal, October 2013


Synthesis of nitropolychlorinated dibenzo- p -dioxins (NPCDDs) and their photochemical reaction with nucleophiles
journal, June 1995


Virtual High Throughput Screening Confirmed Experimentally: Porous Coordination Polymer Hydration
journal, November 2009


High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue
journal, April 2014


NO Disproportionation at a Mononuclear Site-Isolated Fe 2+ Center in Fe 2+ -MOF-5
journal, June 2015


Non-Platinum Group Metal Electrocatalysts Using Metal Organic Framework Materials And Method Of Preparation
patent-application, March 2012


Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst
journal, February 2016


Compositions and Methods Comprising Conductive Metal Organic Frameworks and Uses Thereof
patent-application, March 2017


Temperature Effect on Adsorption/Desorption Isotherms for a Simple Fluid Confined within Various Nanopores
journal, July 2005


Beyond post-synthesis modification: evolution of metal–organic frameworks via building block replacement
journal, January 2014


Metal−Organic Thin-Film Transistor (MOTFT) Based on a Bis( o -diiminobenzosemiquinonate) Nickel(II) Complex
journal, July 2005


Preparation of Linear α-Olefins Using Cationic Nickel(II) α-Diimine Catalysts
journal, May 1997


Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites
journal, May 2014


Hydrothermal and microwave synthesis of SAPO (CHA) zeolites on aluminium foams for heat pumping applications
journal, February 2013


Characterization of metal-organic frameworks by water adsorption
journal, April 2009


Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks
journal, January 2015


Water Stability of Microporous Coordination Polymers and the Adsorption of Pharmaceuticals from Water
journal, November 2010


Ethylene Oligomerization and Propylene Dimerization Using Cationic (α-Diimine)nickel(II) Catalysts
journal, January 1999


Novel Sorption Materials for Solar Heating and Cooling
journal, January 2012


Carbon–ammonia pairs for adsorption refrigeration applications: ice making, air conditioning and heat pumping
journal, September 2009


Shaped bodies containing metal-organic frameworks
patent, May 2005


Synthesis and characterization of a microporous copper triazolate as a water vapor adsorbent
journal, November 2011


Postsynthetic modification of mixed-linker metal–organic frameworks for ethylene oligomerization
journal, January 2014


Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2
journal, March 2016


Effect of functional groups in MIL-101 on water sorption behavior
journal, July 2012


Desolvation of Ions in Subnanometer Pores and Its Effect on Capacitance and Double-Layer Theory
journal, April 2008


Catalytic Ethylene Dimerization and Oligomerization:  Recent Developments with Nickel Complexes Containing P , N-Chelating Ligands
journal, October 2005


�ber Verbindungen des Nickels mito-Phenylendiamin und 1, 3, 4-Toluylendiamin
journal, July 1927


High and Reversible Ammonia Uptake in Mesoporous Azolate Metal–Organic Frameworks with Open Mn, Co, and Ni Sites
journal, July 2016


Recent Advances in β-Lactone Chemistry
journal, January 1993


Pyrazolate-Based Porphyrinic Metal–Organic Framework with Extraordinary Base-Resistance
journal, January 2016


Novel Nickel-based Catalytic Composition and Method of Oligomerization of Olefins Using Said Composition
patent-application, March 2013


Living alkene polymerization: New methods for the precision synthesis of polyolefins
journal, January 2007


Engineering Metal Organic Frameworks for Heterogeneous Catalysis
journal, August 2010


Thiophene-based covalent organic frameworks
journal, March 2013


Selective Nucleation and Growth of Metal−Organic Open Framework Thin Films on Patterned COOH/CF 3 -Terminated Self-Assembled Monolayers on Au(111)
journal, October 2005


Postsynthetic tuning of hydrophilicity in pyrazolate MOFs to modulate water adsorption properties
journal, January 2013


Sorption properties for different types of molecular sieve and their influence on optimum dehumidification performance of desiccant wheels
journal, August 2006


Method for Production of Highly-Active Metal/Metal Oxide Catalysts
patent-application, September 2009