Membrane separation of olefin and paraffin mixtures
Abstract
A metal exchanged fluorinated ionomer is a copolymer minimally including repeating units of (i) a polymerized derivative of a perfluorinated cyclic or cyclizable monomer and (ii) a strong acid highly fluorinated vinylether compound in which the acid moiety is exchanged with a cation of a Group 11 metal. Metal exchanged fluorinated ionomers are readily soluble and can be formed into thin, selectively gas permeable membranes by solution deposition methods. These membranes are suitable for separating olefins from gas olefin/paraffin mixtures. Good selectivity and transmembrane flux can be obtained without humidifying the membrane feed gas mixture.
- Inventors:
- Issue Date:
- Research Org.:
- Compact Membrane Systems Inc., Newport, DE (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1464455
- Patent Number(s):
- 10029248
- Application Number:
- 14/334,605
- Assignee:
- Compact Membrane Systems Inc. (Newport, DE)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- SC0004672; SC0007510
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Jul 17
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Feiring, Andrew Edward, Lazzeri, Jonathan, Majumdar, Sudipto, and Shangguan, Ning. Membrane separation of olefin and paraffin mixtures. United States: N. p., 2018.
Web.
Feiring, Andrew Edward, Lazzeri, Jonathan, Majumdar, Sudipto, & Shangguan, Ning. Membrane separation of olefin and paraffin mixtures. United States.
Feiring, Andrew Edward, Lazzeri, Jonathan, Majumdar, Sudipto, and Shangguan, Ning. Tue .
"Membrane separation of olefin and paraffin mixtures". United States. https://www.osti.gov/servlets/purl/1464455.
@article{osti_1464455,
title = {Membrane separation of olefin and paraffin mixtures},
author = {Feiring, Andrew Edward and Lazzeri, Jonathan and Majumdar, Sudipto and Shangguan, Ning},
abstractNote = {A metal exchanged fluorinated ionomer is a copolymer minimally including repeating units of (i) a polymerized derivative of a perfluorinated cyclic or cyclizable monomer and (ii) a strong acid highly fluorinated vinylether compound in which the acid moiety is exchanged with a cation of a Group 11 metal. Metal exchanged fluorinated ionomers are readily soluble and can be formed into thin, selectively gas permeable membranes by solution deposition methods. These membranes are suitable for separating olefins from gas olefin/paraffin mixtures. Good selectivity and transmembrane flux can be obtained without humidifying the membrane feed gas mixture.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 24 00:00:00 EDT 2018},
month = {Tue Jul 24 00:00:00 EDT 2018}
}
Works referenced in this record:
Process for Separation of Unsaturated Hydrocarbons
patent, September 1973
- Steigelmann, Edward F.; Hughes, Robert D.
- US Patent Document 3758603
Water-free hydrocarbon separation membrane and process
patent, September 1986
- Kraus, Menahem
- US Patent Document 4,614,524
Method for the preparation of ionomer films
patent, March 1988
- Martin, Charles R.; Moore, Robert B.
- US Patent Document 4,731,263
Polymeric membrane and process for separating aliphatically unsaturated hydrocarbons
patent, May 1991
- Ho, W. S. Winston
- US Patent Document 5,015,268
Polymeric membrane and process for separation of aliphatically unsaturated hydrocarbons
patent, November 1991
- Ho, W. S. Winston
- US Patent Document 5,062,866
Use of silver-exchanged ionomer membranes for gas separation
patent, March 1993
- Eriksen, Odd Ivar; Aksnes, Elin; Dahl, Ivar M.
- US Patent Document 5,191,151
Color concentrates and polymer compositions containing the same, and methods of making the same
patent, September 1997
- Scheibelhoffer, Anthony S.; Abrams, Richard L.; Dusek, Dianna B.
- US Patent Document 5,670,561
Solid state facilitated transport separation membranes using polymer electrolytes for alkene separation
patent, October 2002
- Kang, Yong Soo; Won, Jong Ok; Hong, Seong Uk
- US Patent Document 6,468,331
Silver salt-containing facilitated transport membrane for olefin separation having improved stability and method for producing the same
patent, March 2004
- Kim, Hoon; Kang, Yong Soo; Lee, Byung Gwon
- US Patent Document 6,706,771
Method for producing silver salt-containing facilitated transport membrane for olefin separation having improved stability
patent, April 2005
- Kim, Hoon; Kang, Yong Soo; Lee, Byung Gwon
- US Patent Document 6,878,409
Facilitated transport membranes comprising a porous support and a solid polymer electrolyte consisting of a transition metal salt and a polymer having phthalic structure
patent, February 2007
- Kang, Yong Soo; Kim, Hoon; Kim, Jong Hak
- US Patent Document 7,179,321
Solid polymer electrolyte material, liquid composition, solid polymer fuel cell and fluoropolymer
patent, May 2007
- Watakabe, Atsushi; Eriguchi, Takeshi; Tanuma, Toshihiro
- US Patent Document 7,220,508
Process for the separation of olefins from paraffins using membranes
patent, April 2008
- Herrera, Patricio S.; Feng, Xianshe; Payzant, John Donald
- US Patent Document 7,361,800
Silver nanoparticle/polymer nanocomposite membranes for olefin/paraffin separation and method of preparing the same
patent, February 2009
- Kang, Yong Soo; Char, Kook Heon; Kang, Sang-Wook
- US Patent Document 7,491,262
Perfluorovinyl Ether Monomer Having a Sulfonamido Group
patent-application, April 2007
- Iked, Masanori; Hoshi, Nobuto; Uematsu, Nobuyuki
- US Patent Application 11/537376; 20070088142
Electrode for Fuel Cells
patent-application, June 2016
- Amemiya, Kazuki; Matsunaga, Takuro; Harada, Masashi
- US Patent Application 14/954455; 20160164129