Preparation of cerium halide solvate complexes
Abstract
Crystals of a solvated cerium(III) halide solvate complex resulted from a process of forming a paste of a cerium(III) halide in an ionic liquid, adding a solvent to the paste, removing any undissolved solid, and then cooling the liquid phase. Diffusing a solvent vapor into the liquid phase also resulted in crystals of a solvated cerium(III) halide complex.
- Inventors:
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1089402
- Patent Number(s):
- 8501484
- Application Number:
- 13/420,159
- Assignee:
- Los Alamos National Security, LLC (Los Alamos, NM)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- DOE Contract Number:
- AC52-06NA25396
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Vasudevan, Kalyan V, Smith, Nickolaus A, Gordon, John C, McKigney, Edward A, and Muenchaussen, Ross E. Preparation of cerium halide solvate complexes. United States: N. p., 2013.
Web.
Vasudevan, Kalyan V, Smith, Nickolaus A, Gordon, John C, McKigney, Edward A, & Muenchaussen, Ross E. Preparation of cerium halide solvate complexes. United States.
Vasudevan, Kalyan V, Smith, Nickolaus A, Gordon, John C, McKigney, Edward A, and Muenchaussen, Ross E. Tue .
"Preparation of cerium halide solvate complexes". United States. https://www.osti.gov/servlets/purl/1089402.
@article{osti_1089402,
title = {Preparation of cerium halide solvate complexes},
author = {Vasudevan, Kalyan V and Smith, Nickolaus A and Gordon, John C and McKigney, Edward A and Muenchaussen, Ross E},
abstractNote = {Crystals of a solvated cerium(III) halide solvate complex resulted from a process of forming a paste of a cerium(III) halide in an ionic liquid, adding a solvent to the paste, removing any undissolved solid, and then cooling the liquid phase. Diffusing a solvent vapor into the liquid phase also resulted in crystals of a solvated cerium(III) halide complex.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 06 00:00:00 EDT 2013},
month = {Tue Aug 06 00:00:00 EDT 2013}
}
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Works referenced in this record:
CeBr/sub 3/ scintillators for gamma-ray spectroscopy
journal, December 2005
- Shah, K. S.; Glodo, J.; Higgins, W.
- IEEE Transactions on Nuclear Science, Vol. 52, Issue 6
Speciation of Rare-Earth Metal Complexes in Ionic Liquids: A Multiple-Technique Approach
journal, January 2009
- Nockemann, Peter; Thijs, Ben; Lunstroot, Kyra
- Chemistry - A European Journal, Vol. 15, Issue 6
Lanthanides and Actinides in Ionic Liquids
journal, June 2007
- Binnemans, Koen
- Chemical Reviews, Vol. 107, Issue 6
Phase transition and decomposition temperatures, heat capacities and viscosities of pyridinium ionic liquids
journal, June 2005
- Crosthwaite, Jacob M.; Muldoon, Mark J.; Dixon, JaNeille K.
- The Journal of Chemical Thermodynamics, Vol. 37, Issue 6
Room-Temperature Molten Salts Based on the Quaternary Ammonium Ion
journal, October 1998
- Sun, J.; Forsyth, M.; MacFarlane, D. R.
- The Journal of Physical Chemistry B, Vol. 102, Issue 44
An Ionic Liquid-Mediated Route to Cerium(III) Bromide Solvates
journal, May 2011
- Vasudevan, Kalyan V.; Smith, Nickolaus A.; Scott, Brian L.
- Inorganic Chemistry, Vol. 50, Issue 10
Controlled Hydrolysis of Lanthanide Complexes of the N-Donor Tripod Tris(2-pyridylmethyl)amine versus Bisligand Complex Formation
journal, May 2005
- Natrajan, Louise; Pécaut, Jacques; Mazzanti, Marinella
- Inorganic Chemistry, Vol. 44, Issue 13
Oxidation in Nonclassical Organolanthanide Chemistry: Synthesis, Characterization, and X-ray Crystal Structures of Cerium(III) and -(IV) Amides
journal, February 2004
- Hitchcock, Peter B.; Hulkes, Alexander G.; Lappert, Michael F.
- Inorganic Chemistry, Vol. 43, Issue 3
Dissolution of Lanthanide and Actinide Metals Using Iodine and 2-Propanol. Synthesis and x-ray Crystal Structures of LnI3(HO-i-Pr)4 (Ln = La, Ce) and Th2I4(O-i-Pr)4(HO-i-Pr)2
journal, September 1995
- Barnhart, David M.; Frankcom, Tracey M.; Gordon, Pamela L.
- Inorganic Chemistry, Vol. 34, Issue 19
Synthesis of Heteroleptic Cerium(III) Anionic Amido-Tethered N-Heterocyclic Carbene Complexes
journal, April 2005
- Liddle, Stephen T.; Arnold, Polly L.
- Organometallics, Vol. 24, Issue 11
Room temperature ionic liquids of alkylimidazolium cations and fluoroanions
journal, September 2000
- Hagiwara, Rika; Ito, Yasuhiko
- Journal of Fluorine Chemistry, Vol. 105, Issue 2
Competitive Complexation of Nitrates and Chlorides to Uranyl in a Room Temperature Ionic Liquid
journal, July 2010
- Gaillard, C.; Chaumont, A.; Billard, I.
- Inorganic Chemistry, Vol. 49, Issue 14
A Convenient Route to Lanthanide Triiodide THF Solvates. Crystal Structures of LnI 3 (THF) 4 [Ln = Pr] and LnI 3 (THF) 3.5 [Ln = Nd, Gd, Y]
journal, January 2004
- Izod, Keith; Liddle, Stephen T.; Clegg, William
- Inorganic Chemistry, Vol. 43, Issue 1
A short history of SHELX
journal, December 2007
- Sheldrick, George M.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
Hydrophobic ionic liquids
patent, October 1998
- Koch, Victor R.; Nanjundiah, Chenniah; Carlin, Richard T.
- US Patent Document 5,827,602
Ionic Liquids for Lanthanide and Actinide Chemistry
journal, May 2010
- Mudring, Anja-Verena; Tang, Sifu
- European Journal of Inorganic Chemistry, Vol. 2010, Issue 18
Ionic liquid mediated routes to polydentate oxygen-donor adducts of cerium( iii ) bromide
journal, January 2012
- Vasudevan, Kalyan V.; Smith, Nickolaus A.; Scott, Brian L.
- Dalton Trans., Vol. 41, Issue 7