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Title: Tin(II) alkoxide hydrolysis products for use as base catalysts

Abstract

Tin alkoxide compounds are provided with accessible electrons. The compounds are a polymeric tin alkoxide, [Sn(OCH.sub.2 C(CH.sub.3).sub.3).sub.2 ].sub.n, and the hydrolysis products Sn.sub.6 O.sub.4 (OCH.sub.2 C(CH.sub.3).sub.3).sub.4 and Sn.sub.5 O.sub.2 (OCH.sub.2 C(CH.sub.3).sub.3).sub.6. The hydrolysis products are formed by hydrolyzing the [Sn(OCH.sub.2 C(CH.sub.3).sub.3).sub.2 ].sub.n in a solvent with controlled amounts of water, between 0.1 and 2 moles of water per mole of the polymeric tin alkoxide.

Inventors:
 [1]
  1. Albuquerque, NM
Issue Date:
Research Org.:
Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA (United States)
OSTI Identifier:
874555
Patent Number(s):
6414174
Assignee:
Sandia Corporation (Albuquerque, NM)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
tinii; alkoxide; hydrolysis; products; base; catalysts; compounds; provided; accessible; electrons; polymeric; snochsub2; cchsub3sub3sub2; subn; snsub6; osub4; ochsub2; cchsub3sub3sub4; snsub5; osub2; cchsub3sub3sub6; formed; hydrolyzing; solvent; controlled; amounts; water; 01; moles; mole; controlled amount; oxide compounds; alkoxide compound; /999/502/

Citation Formats

Boyle, Timothy J. Tin(II) alkoxide hydrolysis products for use as base catalysts. United States: N. p., 2002. Web.
Boyle, Timothy J. Tin(II) alkoxide hydrolysis products for use as base catalysts. United States.
Boyle, Timothy J. Tue . "Tin(II) alkoxide hydrolysis products for use as base catalysts". United States. https://www.osti.gov/servlets/purl/874555.
@article{osti_874555,
title = {Tin(II) alkoxide hydrolysis products for use as base catalysts},
author = {Boyle, Timothy J},
abstractNote = {Tin alkoxide compounds are provided with accessible electrons. The compounds are a polymeric tin alkoxide, [Sn(OCH.sub.2 C(CH.sub.3).sub.3).sub.2 ].sub.n, and the hydrolysis products Sn.sub.6 O.sub.4 (OCH.sub.2 C(CH.sub.3).sub.3).sub.4 and Sn.sub.5 O.sub.2 (OCH.sub.2 C(CH.sub.3).sub.3).sub.6. The hydrolysis products are formed by hydrolyzing the [Sn(OCH.sub.2 C(CH.sub.3).sub.3).sub.2 ].sub.n in a solvent with controlled amounts of water, between 0.1 and 2 moles of water per mole of the polymeric tin alkoxide.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2002},
month = {1}
}

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