Sulfur resistant nickel based catalysts, methods of forming and using such catalysts

Goyal, Amit; Gangwal, Santosh; Lucero, Andrew

Title: Sulfur resistant nickel based catalysts, methods of forming and using such catalysts

Abstract

Nickel based catalyst structures are described herein that include a plurality of metal oxides formed as crystalline phases within the catalyst structures. Each metal oxide of a catalyst structure includes nickel and/or aluminum, where one or more metal oxides includes a nickel aluminum oxide, and the one or more nickel aluminum oxides is greater than 50% by weight of the catalyst structure. The catalyst structures further have surface areas of at least 13 m²/g. The catalyst structures are resistant to high concentrations of sulfur and are effective in reforming operations for converting methane and other light hydrocarbons to hydrogen and one or more other components. For example, the catalyst structures are effective in coal and biomass gasification systems for the forming and cleanup of synthetic gas.

Inventors:: Goyal, Amit; Gangwal, Santosh; Lucero, Andrew

Issue Date:: 2018-12-04

Research Org.:: Southern Research Institute, Birmingham, AL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1496635

Patent Number(s):: 10144000

Application Number:: 15/175,817

Assignee:: Southern Research Institute (Birmingham, AL)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J19/245 - {placed in series}
B01J2219/00 - Chemical, physical or physico-chemical processes in general
B01J2219/00033 - Continuous processes
B01J2219/24 - Stationary reactors without moving elements inside
B01J23/002 - {Mixed oxides other than spinels, e.g. perovskite}
B01J23/005 - {Spinels}
B01J23/755 - Nickel
B01J23/88 - Molybdenum
B01J23/883 - and nickel
B01J2523/00 - Constitutive chemical elements of heterogeneous catalysts
B01J2523/31 - Aluminium
B01J2523/68 - Molybdenum
B01J2523/847 - Nickel
B01J35/0006 - {Catalysts containing parts with different compositions}
B01J35/002 - {Catalysts characterised by their physical properties}
B01J35/006 - {metal crystallite size}
B01J35/1014 - {10-100 m2/g}
B01J35/1038 - {less than 0.5 ml/g}
B01J35/1061 - {2-50 nm}
B01J37/0018 - {Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,
B01J37/04 - Mixing {
B01J37/088 - {Decomposition of a metal salt}
B01J7/02 - by wet methods
B01J8/0005 - {Catalytic processes under superatmospheric pressure

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/0233 - the reforming step being a steam reforming step
C01B2203/0244 - the reforming step being an autothermal reforming step, e.g. secondary reforming processes
C01B2203/025 - containing a partial oxidation step
C01B2203/0485 - the impurity being a sulfur compound
C01B2203/062 - Hydrocarbon production, e.g. Fischer-Tropsch process
C01B2203/066 - with fuel cells
C01B2203/1058 - Nickel catalysts
C01B2203/1088 - Non-supported catalysts
C01B2203/1241 - Natural gas or methane
C01B2203/141 - At least two reforming, decomposition or partial oxidation steps in parallel
C01B3/382 - {Multi-step processes}
C01B3/40 - characterised by the catalyst

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2/30 - {from carbon monoxide with hydrogen}
C10G5/00 - Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/0913 - Carbonaceous raw material
C10J2300/0916 - Biomass
C10J2300/093 - Coal
C10J2300/0956 - Air or oxygen enriched air
C10J2300/0959 - Oxygen
C10J2300/0976 - as steam
C10J2300/1618 - Modification of synthesis gas composition, e.g. to meet some criteria
C10J2300/1659 - to liquid hydrocarbons
C10J3/00 - Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
C10J3/72 - Other features

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10K - PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
C10K1/004 - {Sulfur containing contaminants, e.g. hydrogen sulfide}
C10K1/005 - {Carbon dioxide}
C10K3/04 - reducing the carbon monoxide content {, e.g. water-gas shift [WGS]}

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/9025 - {Oxides specially used in fuel cell operating at high temperature, e.g. SOFC}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E20/18 - Integrated gasification combined cycle [IGCC]
Y02E60/36 - Hydrogen production from non-carbon containing sources
Y02E60/50 - Fuel cells

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/52 - using catalysts, e.g. selective catalysts

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DOE Contract Number:: FE0012054

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016 Jun 07

Country of Publication:: United States

Language:: English

Citation Formats


                    Goyal, Amit, Gangwal, Santosh, and Lucero, Andrew. Sulfur resistant nickel based catalysts, methods of forming and using such catalysts.  United States: N. p., 2018. 
        Web.

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                    Goyal, Amit, Gangwal, Santosh, & Lucero, Andrew. Sulfur resistant nickel based catalysts, methods of forming and using such catalysts.  United States.

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                    Goyal, Amit, Gangwal, Santosh, and Lucero, Andrew. Tue .  
        "Sulfur resistant nickel based catalysts, methods of forming and using such catalysts".  United States.  https://www.osti.gov/servlets/purl/1496635.

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@article{osti_1496635,

  title        = {Sulfur resistant nickel based catalysts, methods of forming and using such catalysts},

  author       = {Goyal, Amit and Gangwal, Santosh and Lucero, Andrew},

  abstractNote = {Nickel based catalyst structures are described herein that include a plurality of metal oxides formed as crystalline phases within the catalyst structures. Each metal oxide of a catalyst structure includes nickel and/or aluminum, where one or more metal oxides includes a nickel aluminum oxide, and the one or more nickel aluminum oxides is greater than 50% by weight of the catalyst structure. The catalyst structures further have surface areas of at least 13 m2/g. The catalyst structures are resistant to high concentrations of sulfur and are effective in reforming operations for converting methane and other light hydrocarbons to hydrogen and one or more other components. For example, the catalyst structures are effective in coal and biomass gasification systems for the forming and cleanup of synthetic gas.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {12}

}

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Similar Records

Title: Sulfur resistant nickel based catalysts, methods of forming and using such catalysts

Abstract

Citation Formats

Process for the Production of a Reforming Catalyst patent, February 1974

Process for steam reforming of hydrocarbons patent, November 1977

Poisoning effect of thiophene on the catalytic activity of molybdenum carbide during tri-methyl pentane reforming for hydrogen generation journal, June 2005

Catalysts and Methods Including Steam Reforming patent-application, December 2010

Method for preparing synthesis gas using nickel catalysts patent, March 1995

Preparing synthesis gas using hydrotalcite-derived nickel catalysts patent, October 2005

Sulfur resistant molybdenum catalysts for methanation patent, April 1979

Synthesis and characterization of the NiAl2O4, CoAl2O4 and ZnAl2O4 spinels by the polymeric precursors method journal, August 2009

Development of novel highly active and sulphur-tolerant catalysts for steam reforming of liquid hydrocarbons to produce hydrogen journal, January 2004

Supported catalyst for stream methane reforming and autothermal reforming reactions patent, September 2009

Sulfur poisoning of CeO2–Al2O3-supported mono- and bi-metallic Ni and Rh catalysts in steam reforming of liquid hydrocarbons at low and high temperatures journal, December 2010

Sulfur tolerant zeolite catalyst patent, May 2000

Catalytic activity of molybdenum carbide for hydrogen generation via diesel reforming journal, July 2006

Ordered Mesoporous Alumina-Supported Metal Oxides journal, November 2008

Method for steam reforming hydrocarbons using a sulfur-tolerant catalyst patent, May 2001

Reforming sulfur-containing hydrocarbons using a sulfur resistant catalyst patent, March 2011

Method for preparing and using nickel catalysts patent, August 1999

Nickel-based reforming catalysts patent, November 2013

Multi-brand electronic apparatus and multi-band signal processing method patent, August 2010

Dehydrocyclization or catalytic reforming sulfur tolerant zeolite catalyst patent, December 1992

Nickel/aluminum oxide catalyst, preparation thereof, use thereof and hydrogenation of aromatic hydrocarbons with the aid of the catalyst patent, December 1995

Dehydrocyclization or catalytic reforming using sulfur tolerant zeolite catalyst patent, October 1994

Ni catalysts from NiAl2O4 spinel for CO2 reforming of methane journal, April 2006

Reforming sulfur-containing hydrocarbons using a sulfur resistant catalyst patent, March 2011

The properties of nickel aluminate nanoparticles prepared by sol–gel and impregnation methods journal, May 2016

Sulfur-tolerant catalysts and related precursors and processes patent, August 2010

Process for steam reforming of hydrocarbons patent, November 1980

High surface area nickel aluminate spinel catalyst for steam reforming patent, June 1984

Nickel and Nickel Oxide Catalysts on a Nickel Spinel Base patent, February 1968

Methanation catalyst patent, January 1979

Process for the Production of a Reforming Catalyst
patent, February 1974

Process for steam reforming of hydrocarbons
patent, November 1977

Poisoning effect of thiophene on the catalytic activity of molybdenum carbide during tri-methyl pentane reforming for hydrogen generation
journal, June 2005

Catalysts and Methods Including Steam Reforming
patent-application, December 2010

Method for preparing synthesis gas using nickel catalysts
patent, March 1995

Preparing synthesis gas using hydrotalcite-derived nickel catalysts
patent, October 2005

Sulfur resistant molybdenum catalysts for methanation
patent, April 1979

Synthesis and characterization of the NiAl2O4, CoAl2O4 and ZnAl2O4 spinels by the polymeric precursors method
journal, August 2009

Development of novel highly active and sulphur-tolerant catalysts for steam reforming of liquid hydrocarbons to produce hydrogen
journal, January 2004

Supported catalyst for stream methane reforming and autothermal reforming reactions
patent, September 2009

Sulfur poisoning of CeO2–Al2O3-supported mono- and bi-metallic Ni and Rh catalysts in steam reforming of liquid hydrocarbons at low and high temperatures
journal, December 2010

Sulfur tolerant zeolite catalyst
patent, May 2000

Catalytic activity of molybdenum carbide for hydrogen generation via diesel reforming
journal, July 2006

Ordered Mesoporous Alumina-Supported Metal Oxides
journal, November 2008

Method for steam reforming hydrocarbons using a sulfur-tolerant catalyst
patent, May 2001

Reforming sulfur-containing hydrocarbons using a sulfur resistant catalyst
patent, March 2011

Method for preparing and using nickel catalysts
patent, August 1999

Nickel-based reforming catalysts
patent, November 2013

Multi-brand electronic apparatus and multi-band signal processing method
patent, August 2010

Dehydrocyclization or catalytic reforming sulfur tolerant zeolite catalyst
patent, December 1992

Nickel/aluminum oxide catalyst, preparation thereof, use thereof and hydrogenation of aromatic hydrocarbons with the aid of the catalyst
patent, December 1995

Dehydrocyclization or catalytic reforming using sulfur tolerant zeolite catalyst
patent, October 1994

Ni catalysts from NiAl2O4 spinel for CO2 reforming of methane
journal, April 2006

Reforming sulfur-containing hydrocarbons using a sulfur resistant catalyst
patent, March 2011

The properties of nickel aluminate nanoparticles prepared by sol–gel and impregnation methods
journal, May 2016

Sulfur-tolerant catalysts and related precursors and processes
patent, August 2010

Process for steam reforming of hydrocarbons
patent, November 1980

High surface area nickel aluminate spinel catalyst for steam reforming
patent, June 1984

Nickel and Nickel Oxide Catalysts on a Nickel Spinel Base
patent, February 1968

Methanation catalyst
patent, January 1979