Zintl compounds with high thermoelectric performance and methods of manufacture thereof

Ren, Zhifeng; Shuai, Jing

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Title: Zintl compounds with high thermoelectric performance and methods of manufacture thereof

Abstract

Systems and methods discussed herein relate to Zintl-type thermoelectric materials, including a p-type thermoelectric material according to the formula AM_yX_y, and includes at least one of calcium (Ca), europium (Eu), ytterbium (Yb), and strontium (Sr), and has a ZT of the above about 0.60 above 675K. The n-type thermoelectric component includes magnesium (Mg), tellurium (Te), antimony (Sb), and bismuth (Bi) according to the formula Mg_3.2Sb_1.3Bi_0.5-xTe_x that has an average ZT above 0.8 from 400K to 800K. The p-type and n-type materials discussed herein may be used alone, in combination with other materials, or in combination with each other in various configurations.

Inventors:: Ren, Zhifeng; Shuai, Jing

Issue Date:: 2023-04-11

Research Org.:: Univ. of Houston, TX (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1998293

Patent Number(s):: 11627691

Application Number:: 15/999,846

Assignee:: University of Houston System (Houston, TX)

DOE Contract Number:: SC0001299; SC0010831

Resource Type:: Patent

Resource Relation:: Patent File Date: 02/17/2017

Country of Publication:: United States

Language:: English

Subject:: 30 DIRECT ENERGY CONVERSION

Citation Formats


                    Ren, Zhifeng, and Shuai, Jing. Zintl compounds with high thermoelectric performance and methods of manufacture thereof.  United States: N. p., 2023. 
        Web.

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                    Ren, Zhifeng, & Shuai, Jing. Zintl compounds with high thermoelectric performance and methods of manufacture thereof.  United States.

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                    Ren, Zhifeng, and Shuai, Jing. Tue .  
        "Zintl compounds with high thermoelectric performance and methods of manufacture thereof".  United States.  https://www.osti.gov/servlets/purl/1998293.

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@article{osti_1998293,

  title        = {Zintl compounds with high thermoelectric performance and methods of manufacture thereof},

  author       = {Ren, Zhifeng and Shuai, Jing},

  abstractNote = {Systems and methods discussed herein relate to Zintl-type thermoelectric materials, including a p-type thermoelectric material according to the formula AMyXy, and includes at least one of calcium (Ca), europium (Eu), ytterbium (Yb), and strontium (Sr), and has a ZT of the above about 0.60 above 675K. The n-type thermoelectric component includes magnesium (Mg), tellurium (Te), antimony (Sb), and bismuth (Bi) according to the formula Mg3.2Sb1.3Bi0.5-xTex that has an average ZT above 0.8 from 400K to 800K. The p-type and n-type materials discussed herein may be used alone, in combination with other materials, or in combination with each other in various configurations.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2023},

  month        = {4}

}

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Works referenced in this record:

Synthesis and high thermoelectric efficiency of Zintl phase YbCd2−xZnxSb2
journal, March 2009

Wang, Xiao-Jun; Tang, Mei-Bo; Chen, Hao-Hong
Applied Physics Letters, Vol. 94, Issue 9
https://doi.org/10.1063/1.3040321

Thermoelectric Properties of Zintl Phase Compounds of Ca1−x Eu x Zn2Sb2 (0 ≤ x ≤ 1)
journal, December 2015

Wubieneh, Tessera Alemneh; Wei, Pai-Chun; Yeh, Chien-Chih
Journal of Electronic Materials, Vol. 45, Issue 3
https://doi.org/10.1007/s11664-015-4303-6

Thermoelectric Material and Device Incorporating Same
patent-application, August 2009

Sharp, Jeff; Thompson, Alan J.
US Patent Application 12/391037; 20090211619
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090211619

Thermoelectric Conversion Material
patent-application, April 2017

Tamaki, Hiromasa; Kanno, Tsutomo; Sato, Hiroki
US Patent Application 15/243832; 20170117453
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170117453

Valence band study of thermoelectric Zintl-phase ${SrZn}_{2} {Sb}_{2}$ and ${YbZn}_{2} {Sb}_{2}$ : X-ray photoelectron spectroscopy and density functional theory
journal, May 2010

Flage-Larsen, Espen; Diplas, Spyros; Prytz, Øystein
Physical Review B, Vol. 81, Issue 20
https://doi.org/10.1103/PhysRevB.81.205204

Enhancement of thermoelectric performance of phase pure Zintl compounds Ca1−Yb Zn2Sb2, Ca1−Eu Zn2Sb2, and Eu1−Yb Zn2Sb2 by mechanical alloying and hot pressing
journal, July 2016

Shuai, Jing; Wang, Yumei; Liu, Zihang
Nano Energy, Vol. 25
https://doi.org/10.1016/j.nanoen.2016.04.023

Electronic structure and transport in thermoelectric compounds AZn2Sb2 (A = Sr, Ca, Yb, Eu)
journal, January 2010

Toberer, Eric S.; May, Andrew F.; Melot, Brent C.
Dalton Trans., Vol. 39, Issue 4
https://doi.org/10.1039/B914172C

Thermoelectric properties of Bi-based Zintl compounds Ca _1−x Yb _x Mg ₂ Bi ₂
journal, January 2016

Shuai, Jing; Liu, Zihang; Kim, Hee Seok
Journal of Materials Chemistry A, Vol. 4, Issue 11
https://doi.org/10.1039/C6TA00507A

Zintl Phases as Thermoelectric Materials: Tuned Transport Properties of the Compounds CaxYb1-xZn2Sb2
journal, November 2005

Gascoin, F.; Ottensmann, S.; Stark, D.
Advanced Functional Materials, Vol. 15, Issue 11
https://doi.org/10.1002/adfm.200500043

Improved thermoelectric performance in the Zintl phase compounds YbZn2−xMnxSb2 via isoelectronic substitution in the anionic framework
journal, July 2008

Yu, C.; Zhu, T. J.; Zhang, S. N.
Journal of Applied Physics, Vol. 104, Issue 1
https://doi.org/10.1063/1.2939372

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Similar Records

Title: Zintl compounds with high thermoelectric performance and methods of manufacture thereof

Abstract

Citation Formats

Synthesis and high thermoelectric efficiency of Zintl phase YbCd2−xZnxSb2 journal, March 2009

Thermoelectric Properties of Zintl Phase Compounds of Ca1−x Eu x Zn2Sb2 (0 ≤ x ≤ 1) journal, December 2015

Thermoelectric Material and Device Incorporating Same patent-application, August 2009

Thermoelectric Conversion Material patent-application, April 2017

Valence band study of thermoelectric Zintl-phase SrZn 2 Sb 2 and YbZn 2 Sb 2 : X-ray photoelectron spectroscopy and density functional theory journal, May 2010

Enhancement of thermoelectric performance of phase pure Zintl compounds Ca1−Yb Zn2Sb2, Ca1−Eu Zn2Sb2, and Eu1−Yb Zn2Sb2 by mechanical alloying and hot pressing journal, July 2016

Electronic structure and transport in thermoelectric compounds AZn2Sb2 (A = Sr, Ca, Yb, Eu) journal, January 2010

Thermoelectric properties of Bi-based Zintl compounds Ca 1−x Yb x Mg 2 Bi 2 journal, January 2016

Zintl Phases as Thermoelectric Materials: Tuned Transport Properties of the Compounds CaxYb1-xZn2Sb2 journal, November 2005

Improved thermoelectric performance in the Zintl phase compounds YbZn2−xMnxSb2 via isoelectronic substitution in the anionic framework journal, July 2008

Synthesis and high thermoelectric efficiency of Zintl phase YbCd2−xZnxSb2
journal, March 2009

Thermoelectric Properties of Zintl Phase Compounds of Ca1−x Eu x Zn2Sb2 (0 ≤ x ≤ 1)
journal, December 2015

Thermoelectric Material and Device Incorporating Same
patent-application, August 2009

Thermoelectric Conversion Material
patent-application, April 2017

Valence band study of thermoelectric Zintl-phase ${SrZn}_{2} {Sb}_{2}$ and ${YbZn}_{2} {Sb}_{2}$ : X-ray photoelectron spectroscopy and density functional theory
journal, May 2010

Enhancement of thermoelectric performance of phase pure Zintl compounds Ca1−Yb Zn2Sb2, Ca1−Eu Zn2Sb2, and Eu1−Yb Zn2Sb2 by mechanical alloying and hot pressing
journal, July 2016

Electronic structure and transport in thermoelectric compounds AZn2Sb2 (A = Sr, Ca, Yb, Eu)
journal, January 2010

Thermoelectric properties of Bi-based Zintl compounds Ca _1−x Yb _x Mg ₂ Bi ₂
journal, January 2016

Zintl Phases as Thermoelectric Materials: Tuned Transport Properties of the Compounds CaxYb1-xZn2Sb2
journal, November 2005

Improved thermoelectric performance in the Zintl phase compounds YbZn2−xMnxSb2 via isoelectronic substitution in the anionic framework
journal, July 2008