Method for preparation of nanoceria supported atomic noble metal catalysts and the application of platinum single atom catalysts for direct methane conversion

Wang, Chao; Xie, Pengfei; Pu, Tiancheng

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Title: Method for preparation of nanoceria supported atomic noble metal catalysts and the application of platinum single atom catalysts for direct methane conversion

Abstract

Described are methods for converting methane to olefins, aromatics, or a combination thereof using a single atom catalyst comprising CeO2 nanoparticles impregnated with individual atoms of noble metals including Pt, Pd, Rh, Ru, Ag, Au, Ir, or a combination thereof. These single atom catalysts of the present invention are heated with methane to form olefins and aromatics.

Inventors:: Wang, Chao; Xie, Pengfei; Pu, Tiancheng

Issue Date:: 2022-12-06

Research Org.:: Johns Hopkins University, Baltimore, MD (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1986891

Patent Number(s):: 11518722

Application Number:: 16/971,562

Assignee:: The Johns Hopkins University (Baltimore, MD)

DOE Contract Number:: AR0000708

Resource Type:: Patent

Resource Relation:: Patent File Date: 02/19/2019

Country of Publication:: United States

Language:: English

Citation Formats


                    Wang, Chao, Xie, Pengfei, and Pu, Tiancheng. Method for preparation of nanoceria supported atomic noble metal catalysts and the application of platinum single atom catalysts for direct methane conversion.  United States: N. p., 2022. 
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                    Wang, Chao, Xie, Pengfei, & Pu, Tiancheng. Method for preparation of nanoceria supported atomic noble metal catalysts and the application of platinum single atom catalysts for direct methane conversion.  United States.

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                    Wang, Chao, Xie, Pengfei, and Pu, Tiancheng. Tue .  
        "Method for preparation of nanoceria supported atomic noble metal catalysts and the application of platinum single atom catalysts for direct methane conversion".  United States.  https://www.osti.gov/servlets/purl/1986891.

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@article{osti_1986891,

  title        = {Method for preparation of nanoceria supported atomic noble metal catalysts and the application of platinum single atom catalysts for direct methane conversion},

  author       = {Wang, Chao and Xie, Pengfei and Pu, Tiancheng},

  abstractNote = {Described are methods for converting methane to olefins, aromatics, or a combination thereof using a single atom catalyst comprising CeO2 nanoparticles impregnated with individual atoms of noble metals including Pt, Pd, Rh, Ru, Ag, Au, Ir, or a combination thereof. These single atom catalysts of the present invention are heated with methane to form olefins and aromatics.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2022},

  month        = {12}

}

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Similar Records

Title: Method for preparation of nanoceria supported atomic noble metal catalysts and the application of platinum single atom catalysts for direct methane conversion

Abstract

Citation Formats

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Nanocatalyst for Anode of Solid Oxide Fuel Cell and Preparation Method Thereof patent-application, September 2019

Using probe molecule FTIR spectroscopy to identify and characterize Pt-group metal based single atom catalysts journal, September 2017

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Method for Enhancing Degradation of Ester VOCs with Cerium Oxide Supported Palladium Single Atom Catalyst under Low-Temperature Microwave patent-application, January 2020

Structure, Activity, and Stability of Atomically Dispersed Rh in Methane Steam Reforming journal, March 2014

Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation journal, July 2017

Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit journal, October 2015

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Surface-Structure Sensitivity of CeO 2 Nanocrystals in Photocatalysis and Enhancing the Reactivity with Nanogold journal, June 2015

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Heterogeneities of the Nanostructure of Platinum/Zeolite Y Catalysts Revealed by Electron Tomography journal, March 2013

Direct conversion of methane to aromatics in a catalytic co-ionic membrane reactor journal, August 2016

Direct Conversion of Methane to Value-Added Chemicals over Heterogeneous Catalysts: Challenges and Prospects journal, March 2017

Postextraction Separation, On-Board Storage, and Catalytic Conversion of Methane in Natural Gas: A Review journal, August 2016

Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane journal, February 2009

Catalytic Converters with Age-Suppressing Catalysts patent-application, March 2018

Catalytic Dehydrocondensation of Methane with CO and CO2toward Benzene and Naphthalene on Mo/HZSM-5 and Fe/Co-Modified Mo/HZSM-5 journal, February 1999

One-Pot Synthesis of Platinum-Ceria/Graphene Nanosheet as Advanced Electrocatalysts for Alcohol Oxidation journal, March 2015

Synthesis of ethylene via oxidative coupling of methane I. Determination of active catalysts journal, January 1982

n-Heptane hydroisomerization over Pt/MFI zeolite nanosheets: Effects of zeolite crystal thickness and platinum location journal, May 2013

Production of Hydrogen and Carbon Nanostructures by Non-oxidative Catalytic Dehydrogenation of Ethane and Propane journal, March 2004

Bifunctional Catalysis of Mo/HZSM-5 in the Dehydroaromatization of Methane to Benzene and Naphthalene XAFS/TG/DTA/MASS/FTIR Characterization and Supporting Effects journal, January 1999

Cerium Dioxide Nanoparticles and Methods for their Preparation and Use patent-application, December 2016

Remarkable Performance of Ir 1 /FeO x Single-Atom Catalyst in Water Gas Shift Reaction journal, October 2013

Direct evidence by in situ IR CO monitoring of the formation and the surface segregation of a Pt–Sn alloy journal, January 2014

Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D journal, September 2016

Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis journal, April 2013

Catalytic Dehydrogenation of Light Alkanes on Metals and Metal Oxides journal, August 2014

Unravelling single atom catalysis: The surface science approach journal, September 2017

Process for the Preparation of Nanocrystalline Pt-Ce Oxide Catalyst for the Selective Hydrogenation of Phenol and its Derivatives patent-application, March 2015

Oleylamine-Mediated Synthesis of Pd Nanoparticles for Catalytic Formic Acid Oxidation journal, April 2009

Oxygen vacancies on nanosized ceria govern the NO x storage capacity of NSR catalysts journal, January 2016

Rational syntheses of core–shell Fe@(PtRu) nanoparticle electrocatalysts for the methanol oxidation reaction with complete suppression of CO-poisoning and highly enhanced activity journal, January 2015

Single-atom catalysis of CO oxidation using Pt1/FeOx journal, July 2011

Supported Iron Nanoparticles as Catalysts for Sustainable Production of Lower Olefins journal, February 2012

A Selection of Recent Advances in C1 Chemistry
journal, June 2016

Gas-to-liquids (GTL): A review of an industry offering several routes for monetizing natural gas
journal, November 2012

Nanocatalyst for Anode of Solid Oxide Fuel Cell and Preparation Method Thereof
patent-application, September 2019

Using probe molecule FTIR spectroscopy to identify and characterize Pt-group metal based single atom catalysts
journal, September 2017

Supported metal catalysts at the single-atom limit – A viewpoint
journal, September 2017

Thermally stable single-atom platinum-on-ceria catalysts via atom trapping
journal, July 2016

Dehydrogenation and aromatization of methane under non-oxidizing conditions
journal, January 1993

Sulfur as a selective ‘soft’ oxidant for catalytic methane conversion probed by experiment and theory
journal, December 2012

Can the state of platinum species be unambiguously determined by the stretching frequency of an adsorbed CO probe molecule?
journal, January 2016

Creating single-atom Pt-ceria catalysts by surface step decoration
journal, February 2016

Method for Enhancing Degradation of Ester VOCs with Cerium Oxide Supported Palladium Single Atom Catalyst under Low-Temperature Microwave
patent-application, January 2020

Structure, Activity, and Stability of Atomically Dispersed Rh in Methane Steam Reforming
journal, March 2014

Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation
journal, July 2017

Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit
journal, October 2015

Mesoporous Silica/Ceria-Silica Composite and Method for Preparing Same
patent-application, November 2016

Surface-Structure Sensitivity of CeO ₂ Nanocrystals in Photocatalysis and Enhancing the Reactivity with Nanogold
journal, June 2015

Catalytic Dephosphorylation Using Ceria Nanocrystals
journal, February 2017

Unconventional Chemistry for Unconventional Natural Gas
journal, October 2012

Catalytically Stable and Active CeO ₂ Mesoporous Spheres
journal, September 2010

Direct, Nonoxidative Conversion of Methane to Ethylene, Aromatics, and Hydrogen
journal, May 2014

Platinum-Promoted Ga/Al ₂ O ₃ as Highly Active, Selective, and Stable Catalyst for the Dehydrogenation of Propane
journal, July 2014

The state of natural gas
journal, July 2009

Reactivity of Chemisorbed Oxygen Atoms and Their Catalytic Consequences during CH ₄ –O ₂ Catalysis on Supported Pt Clusters
journal, October 2011

Catalyst Materials, Systems, and Methods of Making
patent-application, May 2019

Catalysis by Supported Single Metal Atoms
journal, November 2016

Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation
journal, August 2011

Atomically Dispersed Au–(OH) _x Species Bound on Titania Catalyze the Low-Temperature Water-Gas Shift Reaction
journal, March 2013

Heterogeneities of the Nanostructure of Platinum/Zeolite Y Catalysts Revealed by Electron Tomography
journal, March 2013

Direct conversion of methane to aromatics in a catalytic co-ionic membrane reactor
journal, August 2016

Direct Conversion of Methane to Value-Added Chemicals over Heterogeneous Catalysts: Challenges and Prospects
journal, March 2017

Postextraction Separation, On-Board Storage, and Catalytic Conversion of Methane in Natural Gas: A Review
journal, August 2016

Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane
journal, February 2009

Catalytic Converters with Age-Suppressing Catalysts
patent-application, March 2018

Catalytic Dehydrocondensation of Methane with CO and CO2toward Benzene and Naphthalene on Mo/HZSM-5 and Fe/Co-Modified Mo/HZSM-5
journal, February 1999

One-Pot Synthesis of Platinum-Ceria/Graphene Nanosheet as Advanced Electrocatalysts for Alcohol Oxidation
journal, March 2015

Synthesis of ethylene via oxidative coupling of methane I. Determination of active catalysts
journal, January 1982

n-Heptane hydroisomerization over Pt/MFI zeolite nanosheets: Effects of zeolite crystal thickness and platinum location
journal, May 2013

Production of Hydrogen and Carbon Nanostructures by Non-oxidative Catalytic Dehydrogenation of Ethane and Propane
journal, March 2004

Bifunctional Catalysis of Mo/HZSM-5 in the Dehydroaromatization of Methane to Benzene and Naphthalene XAFS/TG/DTA/MASS/FTIR Characterization and Supporting Effects
journal, January 1999

Cerium Dioxide Nanoparticles and Methods for their Preparation and Use
patent-application, December 2016

Remarkable Performance of Ir ₁ /FeO _x Single-Atom Catalyst in Water Gas Shift Reaction
journal, October 2013

Direct evidence by in situ IR CO monitoring of the formation and the surface segregation of a Pt–Sn alloy
journal, January 2014

Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D
journal, September 2016

Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
journal, April 2013

Catalytic Dehydrogenation of Light Alkanes on Metals and Metal Oxides
journal, August 2014

Unravelling single atom catalysis: The surface science approach
journal, September 2017

Process for the Preparation of Nanocrystalline Pt-Ce Oxide Catalyst for the Selective Hydrogenation of Phenol and its Derivatives
patent-application, March 2015

Oleylamine-Mediated Synthesis of Pd Nanoparticles for Catalytic Formic Acid Oxidation
journal, April 2009

Oxygen vacancies on nanosized ceria govern the NO _x storage capacity of NSR catalysts
journal, January 2016

Rational syntheses of core–shell Fe@(PtRu) nanoparticle electrocatalysts for the methanol oxidation reaction with complete suppression of CO-poisoning and highly enhanced activity
journal, January 2015

Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011

Supported Iron Nanoparticles as Catalysts for Sustainable Production of Lower Olefins
journal, February 2012