Synthesis of platinum single-site centers through metal-ligand self-assembly on metal oxide supports

Tait, Steven L.; Chen, Linxiao

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Title: Synthesis of platinum single-site centers through metal-ligand self-assembly on metal oxide supports

Abstract

The invention describes single-site metal catalysts such as Pt single-site centers with a 3,6-di-2-pyridyl-1,2,4,5-tetrazine (DPTZ) ligand on support such as a powdered MgO, Al₂O₃, CeO₂ or mixtures thereof.

Inventors:: Tait, Steven L.; Chen, Linxiao

Issue Date:: 2022-10-18

Research Org.:: Indiana Univ., Bloomington, IN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1986702

Patent Number(s):: 11471865

Application Number:: 16/717,069

Assignee:: The Trustees of Indiana University (Bloomington, IN)

DOE Contract Number:: SC0016367

Resource Type:: Patent

Resource Relation:: Patent File Date: 12/17/2019

Country of Publication:: United States

Language:: English

Citation Formats


                    Tait, Steven L., and Chen, Linxiao. Synthesis of platinum single-site centers through metal-ligand self-assembly on metal oxide supports.  United States: N. p., 2022. 
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                    Tait, Steven L., & Chen, Linxiao. Synthesis of platinum single-site centers through metal-ligand self-assembly on metal oxide supports.  United States.

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                    Tait, Steven L., and Chen, Linxiao. Tue .  
        "Synthesis of platinum single-site centers through metal-ligand self-assembly on metal oxide supports".  United States.  https://www.osti.gov/servlets/purl/1986702.

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@article{osti_1986702,

  title        = {Synthesis of platinum single-site centers through metal-ligand self-assembly on metal oxide supports},

  author       = {Tait, Steven L. and Chen, Linxiao},

  abstractNote = {The invention describes single-site metal catalysts such as Pt single-site centers with a 3,6-di-2-pyridyl-1,2,4,5-tetrazine (DPTZ) ligand on support such as a powdered MgO, Al2O3, CeO2 or mixtures thereof.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2022},

  month        = {10}

}

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Synthesis of platinum single-site centers through metal-ligand self-assembly on powdered metal oxide supports

Journal Article Chen, Linxiao [Indiana Univ., Bloomington, IN (United States)]; Sterbinsky, George E. [Argonne National Lab. (ANL), Argonne, IL (United States)]; Tait, Steven L. [Indiana Univ., Bloomington, IN (United States)] - Journal of Catalysis

Developing single-site metal catalysts has been regarded as a promising strategy to improve activity and selectivity in heterogeneous catalysis. Here, we report a metal-ligand self-assembly method to create Pt single-site centers on powdered oxide supports. Impregnating Pt and a ligand 3,6-di-2-pyridyl-1,2,4,5- tetrazine (DPTZ) simultaneously (one-step) creates Pt-DPTZ single-sites on powdered MgO, Al₂O₃, and CeO₂. MgO has the most uniform single-sites due to a strong, non-competitive support-ligand interaction, and a support-metal interaction of appropriate strength. Pt(II) centers are stabilized between the N binding pockets of DPTZ, with minimal metallic nanoparticle formation. This system was characterized by XAS, XPS, TEM, XRD, andmore » « less
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DOI: https://doi.org/10.1016/j.jcat.2018.07.004

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Title: Synthesis of platinum single-site centers through metal-ligand self-assembly on metal oxide supports

Abstract

Citation Formats

Creation of Low-Coordination Gold Sites on Au(111) Surface by 1,4-phenylene Diisocyanide Adsorption journal, January 2011

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal, June 2005

Promoting Effect of CeO 2 in Combustion Synthesized Pt/CeO 2 Catalyst for CO Oxidation journal, June 2003

Pt/MgO as Catalyst for Hydrogenolysis Reactions of C5 and C6 Hydrocarbons: Evidence for Metal-Support Interactions journal, September 1993

Oxygen Dissociation by Concerted Action of Di-Iron Centers in Metal–Organic Coordination Networks at Surfaces: Modeling Non-Heme Iron Enzymes journal, December 2011

Design of Efficient Catalysts with Double Transition Metal Atoms on C 2 N Layer journal, April 2016

Graphyne as a promising substrate for the noble-metal single-atom catalysts journal, December 2015

Tackling CO Poisoning with Single-Atom Alloy Catalysts journal, May 2016

Ionic Dispersion of Pt over CeO 2 by the Combustion Method: Structural Investigation by XRD, TEM, XPS, and EXAFS journal, May 2003

Propylene Hydrogenation and Propane Dehydrogenation by a Single-Site Zn 2+ on Silica Catalyst journal, March 2014

(4-Amino-2,2′-bipyridine)dichloroplatinum(II) dihydrate journal, June 2003

Thermally stable single-atom platinum-on-ceria catalysts via atom trapping journal, July 2016

Photochemical route for synthesizing atomically dispersed palladium catalysts journal, May 2016

Pt–dipyridyl tetrazine metal–organic network on the Au(100) surface: insights from first principles calculations journal, January 2017

Platinum nanoparticles on Al2O3: Correlation between the particle size and activity in total methane oxidation journal, November 2009

Structure and catalytic combustion activity of atomically dispersed Pt species at MgO surface journal, November 1999

Ordered Array of Single Adatoms with Remarkable Thermal Stability: Au / Fe 3 O 4 ( 001 ) journal, May 2012

Single-site SBA-15 supported zirconium catalysts. Synthesis, characterization and toward cyanosilylation reaction journal, January 2015

Isolated, well-defined organovanadium( iii ) on silica: single-site catalyst for hydrogenation of alkenes and alkynes journal, January 2017

A molecular Pd( ii ) complex incorporated into a MOF as a highly active single-site heterogeneous catalyst for C–Cl bond activation journal, January 2014

Unusual catalytic activity after simultaneous immobilization of two metalloporphyrins on hydrozincite/nanocrystalline anatase journal, August 2017

Ligand-tailored single-site silica supported titanium catalysts: Synthesis, characterization and towards cyanosilylation reaction journal, January 2015

Single-Atom Pd 1 /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene journal, August 2015

Single-Site Cobalt Catalysts at New Zr 8 (μ 2 -O) 8 (μ 2 -OH) 4 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, Imines, Carbonyls, and Heterocycles journal, September 2016

Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit journal, October 2015

Effect of Pt/Al2O3 catalyst preparation conditions upon its activity in nitric oxide reduction journal, April 1995

Precision Measurements of the Lattice Constants of Twelve Common Metals journal, June 1925

Single-Site Organozirconium Catalyst Embedded in a Metal–Organic Framework journal, December 2015

EXAFS analysis using FEFF and FEFFIT journal, March 2001

Sintering and redispersion behavior of Pt on Pt/MgO journal, July 2008

Attempt To Determine Pristine Points of Zero Charge of Nb 2 O 5 , Ta 2 O 5 , and HfO 2 journal, November 1997

Hydroxo-bridged platinum(II) complexes. 1. Di-.mu.-hydroxo-bis[diammineplatinum(II)] nitrate, [(NH3)2Pt(OH)2Pt(NH3)2](NO3)2. Crystalline structure and vibrational spectra journal, February 1977

In Situ Determination of the Active Catalyst in Hydrosilylation Reactions Using Highly Reactive Pt(0) Catalyst Precursors journal, April 1999

Low-Temperature Water-Gas Shift: In-Situ DRIFTS−Reaction Study of a Pt/CeO 2 Catalyst for Fuel Cell Reformer Applications journal, September 2003

Design of a highly active Pt/Al 2 O 3 catalyst for low-temperature CO oxidation journal, January 2014

Alumina-supported platinum catalysts: Local atomic structure and catalytic activity for complete methane oxidation journal, September 2014

Comparison of Metal-Support Interactions in Pt/TiO2 and Pt/CeO2 journal, August 1995

MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification journal, March 2013

The stoichiometry for hydrogen titration of oxygen on supported platinum journal, October 1967

Single-Atom Gold Catalysis in the Context of Developments in Parahydrogen-Induced Polarization journal, March 2015

Why Does Industry Not Use Immobilized Transition Metal Complexes as Catalysts? journal, December 2015

Towards Surface-Supported Supramolecular Architectures: Tailored Coordination Assembly of 1,4-Benzenedicarboxylate and Fe on Cu(100) journal, April 2004

Pt/Al2O3Catalysts and Pt–Sn/Al2O3Catalysts Prepared by Two Different Methods: Hydrogen Pressure Effects in the Reactions ofn-Hexane journal, June 1997

Synthesis and structural characterization of Pt/amorphous Al2O3 catalyst journal, February 2003

Hydrogen-oxygen titration method for the measurement of supported platinum surface areas journal, December 1965

Determination of the Orientation of Adsorbed Pyridine and γ-MPS on Alumina Surface by Photoacoustic FT-IR Spectroscopy journal, August 1986

Fabrication, characterization, and stability of supported single-atom catalysts journal, January 2017

Selective and Efficient Platinum(0)-Carbene Complexes As Hydrosilylation Catalysts journal, October 2002

Selective Formic Acid Dehydrogenation on Pt-Cu Single-Atom Alloys journal, December 2016

Redox-active ligand controlled selectivity of vanadium oxidation on Au(100) journal, January 2018

Growth, characterization and interfacial reaction of magnetron sputtered Pt/CeO 2 thin films on Si and Si 3 N 4 substrates: Interfacial reaction of Pt/CeO 2 thin films on Si and Si 3 N 4 substrates journal, May 2015

Two- and Three-Electron Oxidation of Single-Site Vanadium Centers at Surfaces by Ligand Design journal, June 2015

The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts journal, February 1957

Low-temperature carbon monoxide oxidation catalysed by regenerable atomically dispersed palladium on alumina journal, September 2014

Niobium–silica catalysts for the selective epoxidation of cyclic alkenes: the generation of the active site by grafting niobocene dichloride journal, January 2013

Redox-active on-surface polymerization of single-site divalent cations from pure metals by a ketone-functionalized phenanthroline journal, February 2015

The support effect on propane combustion over platinum catalyst: control of the oxidation-resistance of platinum by the acid strength of support materials journal, July 2002

Selective propane dehydrogenation with single-site CoII on SiO2 by a non-redox mechanism journal, February 2015

Mimicking Enzymatic Active Sites on Surfaces for Energy Conversion Chemistry journal, June 2015

Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations journal, March 2012

Hydrodechlorination of Carbon Tetrachloride over Pt/MgO journal, July 1996

Nature of ≡SiOCrO 2 Cl and (≡SiO) 2 CrO 2 Sites Prepared by Grafting CrO 2 Cl 2 onto Silica journal, April 2008

Redox-Active On-Surface Assembly of Metal–Organic Chains with Single-Site Pt(II) journal, July 2014

CO Oxidation on Supported Single Pt Atoms: Experimental and ab Initio Density Functional Studies of CO Interaction with Pt Atom on θ-Al 2 O 3 (010) Surface journal, August 2013

Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts journal, August 2003

IFEFFIT : interactive XAFS analysis and FEFF fitting journal, March 2001

Immobilization of catalytic virus-like particles in a flow reactor journal, January 2017

Fresh perspectives for surface coordination chemistry journal, June 2009

Comparative single atom heterogeneous catalysts (SAHCs) on different platforms: a theoretical approach journal, January 2017

Temperature dependence of conformation, chemical state, and metal-directed assembly of tetrapyridyl-porphyrin on Cu(111) journal, December 2008

Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts journal, March 2016

Surface and structural properties of pt/ceo2catalyst under preferential co oxidation in hydrogen (PROX) journal, April 2006

Performance of Cu-Alloyed Pd Single-Atom Catalyst for Semihydrogenation of Acetylene under Simulated Front-End Conditions journal, January 2017

Spectroscopic and structural characterization of Cr(II)/SiO2 active site precursors in model Phillips polymerization catalysts journal, September 2012

The stoichiometry of hydrogen-oxygen titrations on supported platinum catalysts journal, May 1978

Synthesis of platinum single-site centers through metal-ligand self-assembly on powdered metal oxide supports journal, September 2018

Isolated Fe II on Silica As a Selective Propane Dehydrogenation Catalyst journal, May 2015

Creation of Low-Coordination Gold Sites on Au(111) Surface by 1,4-phenylene Diisocyanide Adsorption
journal, January 2011

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

Promoting Effect of CeO ₂ in Combustion Synthesized Pt/CeO ₂ Catalyst for CO Oxidation
journal, June 2003

Pt/MgO as Catalyst for Hydrogenolysis Reactions of C5 and C6 Hydrocarbons: Evidence for Metal-Support Interactions
journal, September 1993

Oxygen Dissociation by Concerted Action of Di-Iron Centers in Metal–Organic Coordination Networks at Surfaces: Modeling Non-Heme Iron Enzymes
journal, December 2011

Design of Efficient Catalysts with Double Transition Metal Atoms on C ₂ N Layer
journal, April 2016

Graphyne as a promising substrate for the noble-metal single-atom catalysts
journal, December 2015

Tackling CO Poisoning with Single-Atom Alloy Catalysts
journal, May 2016

Ionic Dispersion of Pt over CeO ₂ by the Combustion Method: Structural Investigation by XRD, TEM, XPS, and EXAFS
journal, May 2003

Propylene Hydrogenation and Propane Dehydrogenation by a Single-Site Zn ²⁺ on Silica Catalyst
journal, March 2014

(4-Amino-2,2′-bipyridine)dichloroplatinum(II) dihydrate
journal, June 2003

Thermally stable single-atom platinum-on-ceria catalysts via atom trapping
journal, July 2016

Photochemical route for synthesizing atomically dispersed palladium catalysts
journal, May 2016

Pt–dipyridyl tetrazine metal–organic network on the Au(100) surface: insights from first principles calculations
journal, January 2017

Platinum nanoparticles on Al2O3: Correlation between the particle size and activity in total methane oxidation
journal, November 2009

Structure and catalytic combustion activity of atomically dispersed Pt species at MgO surface
journal, November 1999

Ordered Array of Single Adatoms with Remarkable Thermal Stability: $Au / {Fe}_{3} O_{4} (001)$
journal, May 2012

Single-site SBA-15 supported zirconium catalysts. Synthesis, characterization and toward cyanosilylation reaction
journal, January 2015

Isolated, well-defined organovanadium( iii ) on silica: single-site catalyst for hydrogenation of alkenes and alkynes
journal, January 2017

A molecular Pd( ii ) complex incorporated into a MOF as a highly active single-site heterogeneous catalyst for C–Cl bond activation
journal, January 2014

Unusual catalytic activity after simultaneous immobilization of two metalloporphyrins on hydrozincite/nanocrystalline anatase
journal, August 2017

Ligand-tailored single-site silica supported titanium catalysts: Synthesis, characterization and towards cyanosilylation reaction
journal, January 2015

Single-Atom Pd ₁ /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene
journal, August 2015

Single-Site Cobalt Catalysts at New Zr ₈ (μ ₂ -O) ₈ (μ ₂ -OH) ₄ Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, Imines, Carbonyls, and Heterocycles
journal, September 2016

Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit
journal, October 2015

Effect of Pt/Al2O3 catalyst preparation conditions upon its activity in nitric oxide reduction
journal, April 1995

Precision Measurements of the Lattice Constants of Twelve Common Metals
journal, June 1925

Single-Site Organozirconium Catalyst Embedded in a Metal–Organic Framework
journal, December 2015

EXAFS analysis using FEFF and FEFFIT
journal, March 2001

Sintering and redispersion behavior of Pt on Pt/MgO
journal, July 2008

Attempt To Determine Pristine Points of Zero Charge of Nb ₂ O ₅ , Ta ₂ O ₅ , and HfO ₂
journal, November 1997

Hydroxo-bridged platinum(II) complexes. 1. Di-.mu.-hydroxo-bis[diammineplatinum(II)] nitrate, [(NH3)2Pt(OH)2Pt(NH3)2](NO3)2. Crystalline structure and vibrational spectra
journal, February 1977

In Situ Determination of the Active Catalyst in Hydrosilylation Reactions Using Highly Reactive Pt(0) Catalyst Precursors
journal, April 1999

Low-Temperature Water-Gas Shift: In-Situ DRIFTS−Reaction Study of a Pt/CeO ₂ Catalyst for Fuel Cell Reformer Applications
journal, September 2003

Design of a highly active Pt/Al ₂ O ₃ catalyst for low-temperature CO oxidation
journal, January 2014

Alumina-supported platinum catalysts: Local atomic structure and catalytic activity for complete methane oxidation
journal, September 2014

Comparison of Metal-Support Interactions in Pt/TiO2 and Pt/CeO2
journal, August 1995

MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification
journal, March 2013

The stoichiometry for hydrogen titration of oxygen on supported platinum
journal, October 1967

Single-Atom Gold Catalysis in the Context of Developments in Parahydrogen-Induced Polarization
journal, March 2015

Why Does Industry Not Use Immobilized Transition Metal Complexes as Catalysts?
journal, December 2015

Towards Surface-Supported Supramolecular Architectures: Tailored Coordination Assembly of 1,4-Benzenedicarboxylate and Fe on Cu(100)
journal, April 2004

Pt/Al2O3Catalysts and Pt–Sn/Al2O3Catalysts Prepared by Two Different Methods: Hydrogen Pressure Effects in the Reactions ofn-Hexane
journal, June 1997

Synthesis and structural characterization of Pt/amorphous Al2O3 catalyst
journal, February 2003

Hydrogen-oxygen titration method for the measurement of supported platinum surface areas
journal, December 1965

Determination of the Orientation of Adsorbed Pyridine and γ-MPS on Alumina Surface by Photoacoustic FT-IR Spectroscopy
journal, August 1986

Fabrication, characterization, and stability of supported single-atom catalysts
journal, January 2017

Selective and Efficient Platinum(0)-Carbene Complexes As Hydrosilylation Catalysts
journal, October 2002

Selective Formic Acid Dehydrogenation on Pt-Cu Single-Atom Alloys
journal, December 2016

Redox-active ligand controlled selectivity of vanadium oxidation on Au(100)
journal, January 2018

Growth, characterization and interfacial reaction of magnetron sputtered Pt/CeO ₂ thin films on Si and Si ₃ N ₄ substrates: Interfacial reaction of Pt/CeO ₂ thin films on Si and Si ₃ N ₄ substrates
journal, May 2015

Two- and Three-Electron Oxidation of Single-Site Vanadium Centers at Surfaces by Ligand Design
journal, June 2015

The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts
journal, February 1957

Low-temperature carbon monoxide oxidation catalysed by regenerable atomically dispersed palladium on alumina
journal, September 2014

Niobium–silica catalysts for the selective epoxidation of cyclic alkenes: the generation of the active site by grafting niobocene dichloride
journal, January 2013

Redox-active on-surface polymerization of single-site divalent cations from pure metals by a ketone-functionalized phenanthroline
journal, February 2015

The support effect on propane combustion over platinum catalyst: control of the oxidation-resistance of platinum by the acid strength of support materials
journal, July 2002

Selective propane dehydrogenation with single-site CoII on SiO2 by a non-redox mechanism
journal, February 2015

Mimicking Enzymatic Active Sites on Surfaces for Energy Conversion Chemistry
journal, June 2015

Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations
journal, March 2012

Hydrodechlorination of Carbon Tetrachloride over Pt/MgO
journal, July 1996

Nature of ≡SiOCrO ₂ Cl and (≡SiO) ₂ CrO ₂ Sites Prepared by Grafting CrO ₂ Cl ₂ onto Silica
journal, April 2008

Redox-Active On-Surface Assembly of Metal–Organic Chains with Single-Site Pt(II)
journal, July 2014

CO Oxidation on Supported Single Pt Atoms: Experimental and ab Initio Density Functional Studies of CO Interaction with Pt Atom on θ-Al ₂ O ₃ (010) Surface
journal, August 2013

Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
journal, August 2003

IFEFFIT : interactive XAFS analysis and FEFF fitting
journal, March 2001

Immobilization of catalytic virus-like particles in a flow reactor
journal, January 2017

Fresh perspectives for surface coordination chemistry
journal, June 2009

Comparative single atom heterogeneous catalysts (SAHCs) on different platforms: a theoretical approach
journal, January 2017

Temperature dependence of conformation, chemical state, and metal-directed assembly of tetrapyridyl-porphyrin on Cu(111)
journal, December 2008

Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts
journal, March 2016

Surface and structural properties of pt/ceo2catalyst under preferential co oxidation in hydrogen (PROX)
journal, April 2006

Performance of Cu-Alloyed Pd Single-Atom Catalyst for Semihydrogenation of Acetylene under Simulated Front-End Conditions
journal, January 2017

Spectroscopic and structural characterization of Cr(II)/SiO2 active site precursors in model Phillips polymerization catalysts
journal, September 2012

The stoichiometry of hydrogen-oxygen titrations on supported platinum catalysts
journal, May 1978

Synthesis of platinum single-site centers through metal-ligand self-assembly on powdered metal oxide supports
journal, September 2018

Isolated Fe ^II on Silica As a Selective Propane Dehydrogenation Catalyst
journal, May 2015

Catalytically Active Single-Atom Sites Fabricated from Silver Particles
journal, March 2012

In situ FTIR spectra of pyridine adsorbed on SiO2–Al2O3, TiO2, ZrO2 and CeO2: general considerations for the identification of acid sites on surfaces of finely divided metal oxides
journal, October 2001

Self-assembly of metal–organic coordination structures on surfaces
journal, August 2016