Method for determining thermodynamic and molecular properties in the liquid phase
Abstract
A method for calculating the average molecular weight of individual molecules in a sample, where the molecules in solution associate to form clusters. Data sets of apparent molecular weight of the sample versus concentration of the sample in the solvent are generated. The basic principles and technology in generation of the data is the well understood action of a solute upon the solvent vapor pressure above the solution. By observing the effect of a sample solute on the temperature/vapor pressure properties of a solvent, it is possible by known methods to determine its molecular weight. When dealing with a solute material that tends to form clusters, however, the molecular weight found is an apparent molecular weight, i.e. the average molecular weight of all of the particles, which are the clusters and any unassociated molecules, if any. To determine the true molecular weight, a method employing the determined apparent molecular weights, referred to herein as the BRD method, is used. Since the method is based upon cluster thermodynamics and equilibrium properties, it reflects more accurately the behavior of the clusters at various dilutions. The method provides a basis for the prediction of thermodynamic and equilibrium properties, which was not possible withmore »
- Inventors:
- Issue Date:
- Research Org.:
- National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1531420
- Patent Number(s):
- 5574215
- Application Number:
- 08/396,378
- Assignee:
- James W. Bunger & Associates, Inc. (Salt Lake City, UT)
- Patent Classifications (CPCs):
-
G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- DOE Contract Number:
- AC21-93MC29240
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 1995-02-28
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Bunger, James W., Russell, Christopher P., and Devineni, Prasad A. V. Method for determining thermodynamic and molecular properties in the liquid phase. United States: N. p., 1996.
Web.
Bunger, James W., Russell, Christopher P., & Devineni, Prasad A. V. Method for determining thermodynamic and molecular properties in the liquid phase. United States.
Bunger, James W., Russell, Christopher P., and Devineni, Prasad A. V. Tue .
"Method for determining thermodynamic and molecular properties in the liquid phase". United States. https://www.osti.gov/servlets/purl/1531420.
@article{osti_1531420,
title = {Method for determining thermodynamic and molecular properties in the liquid phase},
author = {Bunger, James W. and Russell, Christopher P. and Devineni, Prasad A. V.},
abstractNote = {A method for calculating the average molecular weight of individual molecules in a sample, where the molecules in solution associate to form clusters. Data sets of apparent molecular weight of the sample versus concentration of the sample in the solvent are generated. The basic principles and technology in generation of the data is the well understood action of a solute upon the solvent vapor pressure above the solution. By observing the effect of a sample solute on the temperature/vapor pressure properties of a solvent, it is possible by known methods to determine its molecular weight. When dealing with a solute material that tends to form clusters, however, the molecular weight found is an apparent molecular weight, i.e. the average molecular weight of all of the particles, which are the clusters and any unassociated molecules, if any. To determine the true molecular weight, a method employing the determined apparent molecular weights, referred to herein as the BRD method, is used. Since the method is based upon cluster thermodynamics and equilibrium properties, it reflects more accurately the behavior of the clusters at various dilutions. The method provides a basis for the prediction of thermodynamic and equilibrium properties, which was not possible with previous methods.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Nov 12 00:00:00 EST 1996},
month = {Tue Nov 12 00:00:00 EST 1996}
}
Works referenced in this record:
Method for measurement of polymer molecular weight based upon a temperature difference
patent, August 1994
- Kawanami, Norio; Kondo, Kiyotaka; Ikeda, Yoshihiro
- US Patent Document 5,341,672
Works referencing / citing this record:
Method for predicting sediment content of a hydroprocessed hydrocarbon product
patent, March 2018
- Rogel, Estrella; Ovalles, Cesar; Leung, Pak
- US Patent Document 9,921,203
Method for estimating processability of a hydrocarbon-containing feedstock for hydroprocessing
patent, January 2014
- Schabron, John F.; Rovani, Jr., Joseph F.
- US Patent Document 8,628,970
Hydrocarbon separation and analysis apparatus and methods
patent, May 2016
- Schabron, John F.; Boysen, Ryan B.; Kalberer, Eric W.
- US Patent Document 9,353,317
Method for determining asphaltene stability of a hydrocarbon-containing material
patent, February 2013
- Schabron, John F.; Rovani, Jr., Joseph F.
- US Patent Document 8,367,425
Method for predicting catalyst performance
patent, September 2015
- Komalarajun, Varut; Ovalles, Cesar; Rogel, Estrella
- US Patent Document 9,127,213
Method for predicting fouling tendency of a hydrocarbon-containing feedstock
patent, July 2013
- Schabron, John F.; Rovani, Jr., Joseph F.
- US Patent Document 8,492,154
Methods of successive elution of components of hydrocarbons
patent, March 2019
- Schabron, John F.; Boysen, Ryan B.; Kalberer, Eric W.
- US Patent Document 10,221,363
Process for determining the distillation characteristics of liquid petroleum products by express mini-distillation and apparatus permitting implementation of this process
patent, June 2003
- Abaev, Guenrikh; Andreeva, Raissa; Urvantsau, Viachaslau
- US Patent Document 6,581,443
Processing and analysis techniques involving in-vessel material generation
patent, January 2011
- Schabron, John F.; Rovani, Jr., Joseph F.
- US Patent Document 7,875,464
Processing and analysis techniques involving in-vessel material generation
patent, September 2012
- Schabron, John F.; Rovani, Jr., Joseph F.
- US Patent Document 8,273,581
Method for determining processability of a hydrocarbon containing feedstock
patent, September 2013
- Schabron, John F.; Rovani, Jr., Joseph F.
- US Patent Document 8,530,240
Parallel high-performance liquid chromatography with post-separation treatment
patent, August 2004
- Petro, Miroslav
- US Patent Document 6,776,902
Methods for estimating properties of hydrocarbons comprising asphaltenes based on their solubility
patent, October 2016
- Schabron, John F.; Rovani, Jr., Joseph F.
- US Patent Document 9,458,389
Method for determining thermodynamic and molecular properties in the liquid phase
patent, April 1998
- Bunger, James W.; Russell, Christopher P.; Devineni, Prasad A. V.
- US Patent Document 5,739,423
Processing and analysis techniques involving in-vessel material generation
patent, August 2012
- Schabron, John F.; Rovani, Jr., Joseph F.
- US Patent Document 8,241,920
Continuous on-line process control of residua distillation
patent, May 2007
- Rovani, Jr., Joseph F.; Schabron, John F.; Turner, Thomas F.
- US Patent Document 7,223,603
Parallel high-performance liquid chromatography with post-separation treatment
patent, August 2002
- Petro, Miroslav
- US Patent Document 6,436,292