Amino-siloxane composition and methods of using the same

O'Brien, Michael Joseph; Farnum, Rachel Lizabeth; Perry, Robert James

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Title: Amino-siloxane composition and methods of using the same

Abstract

An amino-siloxane composition is presented. The amino-siloxane composition includes structure (I): ##STR00001## wherein R.sup.1 is independently at each occurrence a C.sub.1-C.sub.5 aliphatic radical; R.sup.2 is a C.sub.3-C.sub.4 aliphatic radical; R.sup.3 is a C.sub.1-C.sub.5 aliphatic radical or R.sup.4, wherein R.sup.4 comprises structure (II): ##STR00002## and X is an electron donating group. Methods of reducing an amount of carbon dioxide in a process stream using the amino-siloxane composition are also presented.

Inventors:: O'Brien, Michael Joseph; Farnum, Rachel Lizabeth; Perry, Robert James

Issue Date:: Tue Aug 30 00:00:00 EDT 2016

Research Org.:: GE Global Research, Niskayuna, New York (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1344739

Patent Number(s):: 9427698

Application Number:: 14/051,594

Assignee:: General Electric Company (Niskayuna, NY)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2252/2041 - Diamines
B01D2252/20415 - Tri- or polyamines
B01D2252/20426 - Secondary amines
B01D2252/20431 - Tertiary amines
B01D2252/20452 - containing a morpholine-ring
B01D2252/2053 - Other nitrogen compounds
B01D2258/0283 - Flue gases
B01D53/1475 - {Removing carbon dioxide}
B01D53/1493 - {Selection of liquid materials for use as absorbents}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F7/0838 - {Compounds with one or more Si-O-Si sequences

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10K - PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
C10K1/005 - {Carbon dioxide}
C10K1/128 - {containing organic oxygen transferring compounds, e.g. sulfoxides}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/151 - Reduction of greenhouse gas [GHG] emissions

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DOE Contract Number:: AR0000084

Resource Type:: Patent

Resource Relation:: Patent File Date: 2013 Oct 11

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    O'Brien, Michael Joseph, Farnum, Rachel Lizabeth, and Perry, Robert James. Amino-siloxane composition and methods of using the same.  United States: N. p., 2016. 
        Web.

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                    O'Brien, Michael Joseph, Farnum, Rachel Lizabeth, & Perry, Robert James. Amino-siloxane composition and methods of using the same.  United States.

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                    O'Brien, Michael Joseph, Farnum, Rachel Lizabeth, and Perry, Robert James. Tue .  
        "Amino-siloxane composition and methods of using the same".  United States.  https://www.osti.gov/servlets/purl/1344739.

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@article{osti_1344739,

  title        = {Amino-siloxane composition and methods of using the same},

  author       = {O'Brien, Michael Joseph and Farnum, Rachel Lizabeth and Perry, Robert James},

  abstractNote = {An amino-siloxane composition is presented. The amino-siloxane composition includes structure (I): ##STR00001## wherein R.sup.1 is independently at each occurrence a C.sub.1-C.sub.5 aliphatic radical; R.sup.2 is a C.sub.3-C.sub.4 aliphatic radical; R.sup.3 is a C.sub.1-C.sub.5 aliphatic radical or R.sup.4, wherein R.sup.4 comprises structure (II): ##STR00002## and X is an electron donating group. Methods of reducing an amount of carbon dioxide in a process stream using the amino-siloxane composition are also presented.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Aug 30 00:00:00 EDT 2016},

  month        = {Tue Aug 30 00:00:00 EDT 2016}

}

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Works referenced in this record:

Process for accelerated capture of carbon dioxide
patent, August 2011

Gellett, Wayne L.; Bucholz, Tracy L.; Zvosec, Richard T.
US Patent Document 7,998,714
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7998714

Carbon dioxide absorbent and method of using the same
patent, October 2011

Perry, Robert James; Lewis, Larry Neil; O'Brien, Michael J.
US Patent Document 8,030,509
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8030509

Modified Adsorbent for Dry Scrubbing and Use Thereof
patent-application, July 2006

Sayari, Abdelhamid
US Patent Application 10/539225; 20060165574
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060165574

Liquid Carbon Dioxide Absorbent and Methods of Using the Same
patent-application, June 2010

Genovese, Sarah Elizabeth; Hancu, Dan; Perry, Robert James
US Patent Application 12/343905; 20100154431
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100154431

Liquid Carbon Dioxide Absorbent and Methods of Using the Same
patent-application, June 2010

Perry, Robert James; O'Brien, Michael Joseph; Lam, Tunchiao Hubert
US Patent Application 12/512577; 20100154639
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100154639

Aminosilicone Solvents for CO₂ Capture
journal, August 2010

Perry, Robert J.; Grocela-Rocha, Teresa A.; O'Brien, Michael J.
ChemSusChem, Vol. 3, Issue 8, p. 919-930
https://doi.org/10.1002/cssc.201000077

Amino Disiloxanes for CO ₂ Capture
journal, April 2011

Perry, Robert J.; O’Brien, Michael J.
Energy & Fuels, Vol. 25, Issue 4
https://doi.org/10.1021/ef101564h

CO ₂ Capture Using Solutions of Alkanolamines and Aminosilicones
journal, March 2012

Perry, Robert J.; Davis, Jason L.
Energy & Fuels, Vol. 26, Issue 4
https://doi.org/10.1021/ef201963m

CO₂ Capture Using Phase-Changing Sorbents
journal, March 2012

Perry, Robert J.; Wood, Benjamin R.; Genovese, Sarah
Energy & Fuels, Vol. 26, Issue 4, p. 2528-2538
https://doi.org/10.1021/ef300079w

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Title: Amino-siloxane composition and methods of using the same

Abstract

Citation Formats

Process for accelerated capture of carbon dioxide patent, August 2011

Carbon dioxide absorbent and method of using the same patent, October 2011

Modified Adsorbent for Dry Scrubbing and Use Thereof patent-application, July 2006

Liquid Carbon Dioxide Absorbent and Methods of Using the Same patent-application, June 2010

Liquid Carbon Dioxide Absorbent and Methods of Using the Same patent-application, June 2010

Aminosilicone Solvents for CO2 Capture journal, August 2010

Amino Disiloxanes for CO 2 Capture journal, April 2011

CO 2 Capture Using Solutions of Alkanolamines and Aminosilicones journal, March 2012

CO2 Capture Using Phase-Changing Sorbents journal, March 2012

Process for accelerated capture of carbon dioxide
patent, August 2011

Carbon dioxide absorbent and method of using the same
patent, October 2011

Modified Adsorbent for Dry Scrubbing and Use Thereof
patent-application, July 2006

Liquid Carbon Dioxide Absorbent and Methods of Using the Same
patent-application, June 2010

Liquid Carbon Dioxide Absorbent and Methods of Using the Same
patent-application, June 2010

Aminosilicone Solvents for CO₂ Capture
journal, August 2010

Amino Disiloxanes for CO ₂ Capture
journal, April 2011

CO ₂ Capture Using Solutions of Alkanolamines and Aminosilicones
journal, March 2012

CO₂ Capture Using Phase-Changing Sorbents
journal, March 2012