Compositions for, solutions for, and methods of use of siloxane based aromatic trisureas as viscosifiers

Doherty, Mark Daniel; O'Brien, Michael Joseph; Lee, Jason; Perry, Robert James; Enick, Robert

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A - human necessities
A01 - agriculture
A21 - baking
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Title: Compositions for, solutions for, and methods of use of siloxane based aromatic trisureas as viscosifiers

Abstract

A compound represented by the following formula is provided: ##STR00001## Also provided is a solution including a compound disclosed herein, a volume of dense carbon dioxide (CO.sub.2), and a co-solvent, where the solution has an increased viscosity greater than the viscosity of dense CO.sub.2. Methods of increasing the viscosity of dense CO.sub.2 and natural gas liquids (NGLs) by, for example, dissolving a compound disclosed herein to form a solution, are also provided.

Inventors:: Doherty, Mark Daniel; O'Brien, Michael Joseph; Lee, Jason; Perry, Robert James; Enick, Robert

Issue Date:: 2018-05-01

Research Org.:: US Department of Energy (USDOE), Washington, DC (United States). Advanced Research Projects Agency-Energy (ARPA-E)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1439420

Patent Number(s):: 9957438

Application Number:: 15/006,201

Assignee:: General Electric Company (Schenectady, NY)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM

C - CHEMISTRY C09 - DYES C09K - MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F7/0838 - {Compounds with one or more Si-O-Si sequences
C07F7/21 - Cyclic compounds having at least one ring containing silicon, but no carbon in the ring

C - CHEMISTRY C09 - DYES C09K - MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
C09K8/594 - Compositions used in combination with injected gas {, e.g. CO2 orcarbonated gas}
C09K8/64 - Oil-based compositions
C09K8/82 - Oil-based compositions

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DOE Contract Number:: AR0000292

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016 Jan 26

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Doherty, Mark Daniel, O'Brien, Michael Joseph, Lee, Jason, Perry, Robert James, and Enick, Robert. Compositions for, solutions for, and methods of use of siloxane based aromatic trisureas as viscosifiers.  United States: N. p., 2018. 
        Web.

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                    Doherty, Mark Daniel, O'Brien, Michael Joseph, Lee, Jason, Perry, Robert James, & Enick, Robert. Compositions for, solutions for, and methods of use of siloxane based aromatic trisureas as viscosifiers.  United States.

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                    Doherty, Mark Daniel, O'Brien, Michael Joseph, Lee, Jason, Perry, Robert James, and Enick, Robert. Tue .  
        "Compositions for, solutions for, and methods of use of siloxane based aromatic trisureas as viscosifiers".  United States.  https://www.osti.gov/servlets/purl/1439420.

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@article{osti_1439420,

  title        = {Compositions for, solutions for, and methods of use of siloxane based aromatic trisureas as viscosifiers},

  author       = {Doherty, Mark Daniel and O'Brien, Michael Joseph and Lee, Jason and Perry, Robert James and Enick, Robert},

  abstractNote = {A compound represented by the following formula is provided: ##STR00001## Also provided is a solution including a compound disclosed herein, a volume of dense carbon dioxide (CO.sub.2), and a co-solvent, where the solution has an increased viscosity greater than the viscosity of dense CO.sub.2. Methods of increasing the viscosity of dense CO.sub.2 and natural gas liquids (NGLs) by, for example, dissolving a compound disclosed herein to form a solution, are also provided.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {5}

}

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Works referenced in this record:

Polysilylenesiloxane polymers useful in enhanced oil recovery using carbon dioxide flooding
patent, June 1992

Davis, Bruce W.
US Patent Document 5,123,486
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5123486

Polysiloxanes with amino functionalities having reversible thickening and adhesion properties and systems and methods for crude oil, petroleum product or chemical spill containment and remediation
patent, September 2014

Weiss, Richard G.; Yu, Tao; Wakuda, Koji
US Patent Document 8,828,173
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8828173

Polysiloxane polymer having pendant aromatic groups useful in enhanced oil recovery using carbon dioxide flooding
patent, September 1992

Woo, Gar L.
US Patent Document 5,143,632
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5143632

Urea Compound, Self-Assembly of Urea Compounds, Organogel Containing Self-Assembly, and Method for Producing Organogel
patent-application, August 2011

Yamanaka, Masamichi
US Patent Application 13/120388; 20110198534
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110198534

CO₂: a wild solvent, tamed
journal, January 2011

Cummings, Stephen; Trickett, Kieran; Enick, Robert
Physical Chemistry Chemical Physics, Vol. 13, Issue 4, p. 1276-1289
https://doi.org/10.1039/C003856C

Enhanced oil recovery using CO.sub.2 flooding
patent, April 1990

Harris, Thomas V.; Irani, Cyrus A.; Pretzer, Wayne R.
US Patent Document 4,913,235
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4913235

Process for the preparation of pulverulent polymers by polymerization in supercritical carbon dioxide in the presence of polyoxyalkylene-polysiloxane copolymers
patent, February 2001

Beckham, Eric; Fink, Ralf; Hildebrandt, Volker
US Patent Document 6,191,215
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6191215

Gelling agents
patent, January 2010

van Bommel, Kjeld Jacobus Cornelis; van Esch, Johannes; de Loos, Maaike
US Patent Document 7,645,805
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7645805

Silane Urea Compound as a Heat-activated Curing Agent for Epoxide Resin Compositions
patent-application, August 2014

Kramer, Andreas
US Patent Application 14/246768; 20140216655
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140216655

Development of Small Molecule CO2 Thickeners for EOR and Fracturing
conference, April 2014

Lee, J. J.; Cummings, S.; Dhuwe, A.
SPE Improved Oil Recovery Symposium
https://doi.org/10.2118/169039-MS

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Similar Records

Title: Compositions for, solutions for, and methods of use of siloxane based aromatic trisureas as viscosifiers

Abstract

Citation Formats

Polysilylenesiloxane polymers useful in enhanced oil recovery using carbon dioxide flooding patent, June 1992

Polysiloxanes with amino functionalities having reversible thickening and adhesion properties and systems and methods for crude oil, petroleum product or chemical spill containment and remediation patent, September 2014

Polysiloxane polymer having pendant aromatic groups useful in enhanced oil recovery using carbon dioxide flooding patent, September 1992

Urea Compound, Self-Assembly of Urea Compounds, Organogel Containing Self-Assembly, and Method for Producing Organogel patent-application, August 2011

CO2: a wild solvent, tamed journal, January 2011

Enhanced oil recovery using CO.sub.2 flooding patent, April 1990

Process for the preparation of pulverulent polymers by polymerization in supercritical carbon dioxide in the presence of polyoxyalkylene-polysiloxane copolymers patent, February 2001

Gelling agents patent, January 2010

Silane Urea Compound as a Heat-activated Curing Agent for Epoxide Resin Compositions patent-application, August 2014

Development of Small Molecule CO2 Thickeners for EOR and Fracturing conference, April 2014

Polysilylenesiloxane polymers useful in enhanced oil recovery using carbon dioxide flooding
patent, June 1992

Polysiloxanes with amino functionalities having reversible thickening and adhesion properties and systems and methods for crude oil, petroleum product or chemical spill containment and remediation
patent, September 2014

Polysiloxane polymer having pendant aromatic groups useful in enhanced oil recovery using carbon dioxide flooding
patent, September 1992

Urea Compound, Self-Assembly of Urea Compounds, Organogel Containing Self-Assembly, and Method for Producing Organogel
patent-application, August 2011

CO₂: a wild solvent, tamed
journal, January 2011

Enhanced oil recovery using CO.sub.2 flooding
patent, April 1990

Process for the preparation of pulverulent polymers by polymerization in supercritical carbon dioxide in the presence of polyoxyalkylene-polysiloxane copolymers
patent, February 2001

Gelling agents
patent, January 2010

Silane Urea Compound as a Heat-activated Curing Agent for Epoxide Resin Compositions
patent-application, August 2014

Development of Small Molecule CO2 Thickeners for EOR and Fracturing
conference, April 2014