Compounds and methods for the production of long chain hydrocarbons from biological sources
Abstract
The present invention is directed to the preparation of oxygenated, unsaturated hydrocarbon compounds, such as derivatives of furfural or hydroxymethyl furfural produced by aldol condensation with a ketone or a ketoester, as well as methods of deoxidatively reducing those compounds with hydrogen under acidic conditions to provide saturated hydrocarbons useful as fuels.
- Inventors:
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1303753
- Patent Number(s):
- 9422207
- Application Number:
- 14/344,178
- Assignee:
- Los Alamos National Security, LLC (Los Alamos, NM
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
- DOE Contract Number:
- AC52-06NA25396
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2012 Sep 14
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 09 BIOMASS FUELS; 59 BASIC BIOLOGICAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Gordon, John Cameron, Silks, Louis A, Sutton, Andrew D, Wu, Ruilian, Schlaf, Marcel, Waldie, Fraser, West, Ryan, and Collias, Dimitris Ioannis. Compounds and methods for the production of long chain hydrocarbons from biological sources. United States: N. p., 2016.
Web.
Gordon, John Cameron, Silks, Louis A, Sutton, Andrew D, Wu, Ruilian, Schlaf, Marcel, Waldie, Fraser, West, Ryan, & Collias, Dimitris Ioannis. Compounds and methods for the production of long chain hydrocarbons from biological sources. United States.
Gordon, John Cameron, Silks, Louis A, Sutton, Andrew D, Wu, Ruilian, Schlaf, Marcel, Waldie, Fraser, West, Ryan, and Collias, Dimitris Ioannis. Tue .
"Compounds and methods for the production of long chain hydrocarbons from biological sources". United States. https://www.osti.gov/servlets/purl/1303753.
@article{osti_1303753,
title = {Compounds and methods for the production of long chain hydrocarbons from biological sources},
author = {Gordon, John Cameron and Silks, Louis A and Sutton, Andrew D and Wu, Ruilian and Schlaf, Marcel and Waldie, Fraser and West, Ryan and Collias, Dimitris Ioannis},
abstractNote = {The present invention is directed to the preparation of oxygenated, unsaturated hydrocarbon compounds, such as derivatives of furfural or hydroxymethyl furfural produced by aldol condensation with a ketone or a ketoester, as well as methods of deoxidatively reducing those compounds with hydrogen under acidic conditions to provide saturated hydrocarbons useful as fuels.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 23 00:00:00 EDT 2016},
month = {Tue Aug 23 00:00:00 EDT 2016}
}
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Works referenced in this record:
Acylation of aromatics
patent, January 1990
- Eggersdorfer, Manfred; Siegel, Hardo; Schuhmacher, Alfred
- US Patent Document 4,895,984
Process for preparing 2-methyl-4-(2,2,3-trimethyl-cyclopent-3-en-1-yl)-but-2-en-1-ol
patent, February 2000
- Markert, Thomas
- US Patent Document 6,028,231
Study of Liquid Alkanes Production from Biomass-Derived Carbohydrates by Aldol-Condensation and Hydrogenation Processes
journal, October 2010
- Dedsuksophon, Wassana; Champreda, Verawat; Laosiripojana, Navadol
- Engineering Journal, Vol. 14, Issue 4
Study of Liquid Alkanes Production from Biomass-Derived Carbohydrates by Aldol-Condensation and Hydrogenation Processes
journal, October 2010
- Dedsuksophon, Wassana; Champreda, Verawat; Laosiripojana, Navadol
- Engineering Journal, Vol. 14, Issue 4
Production of Liquid Alkanes by Aqueous-Phase Processing of Biomass-Derived Carbohydrates
journal, June 2005
- Huber, George W.; Chheda, Juben N.; Barrett, Christopher J.
- Science, Vol. 308, Issue 5727, p. 1446-1450
Lanthanide Triflates as Water-Tolerant Lewis Acids. Activation of Commercial Formaldehyde Solution and Use in the Aldol Reaction of Silyl Enol Ethers with Aldehydes in Aqueous Media
journal, July 1994
- Kobayashi, Shu; Hachiya, Iwao
- The Journal of Organic Chemistry, Vol. 59, Issue 13
Upgrading of low-boiling fraction of bio-oil in supercritical methanol and reaction network
journal, April 2011
- Li, Wang; Pan, Chunyan; Zhang, Qijun
- Bioresource Technology, Vol. 102, Issue 7, p. 4884-4889
Virial coefficients of hydrogen and deuterium at temperatures between −175°C and +150°C. Conclusions from the second virial coefficient with regards to the intermolecular potential
journal, June 1960
- Michels, A.; de Graaff, W.; Ten Seldam, C. A.
- Physica, Vol. 26, Issue 6, p. 393-408
Preparation of polyhydroxyalkyl- and C-glycosylfuran derivatives from free sugars catalyzed by cerium(III) chloride in aqueous solution: an improvement of the Garcia González reaction
journal, May 2004
- Misra, Anup Kumar; Agnihotri, Geetanjali
- Carbohydrate Research, Vol. 339, Issue 7, p. 1381-1387
Total hydrogenation of furan derivatives over silica-supported Ni–Pd alloy catalyst
journal, November 2010
- Nakagawa, Yoshinao; Tomishige, Keiichi
- Catalysis Communications, Vol. 12, Issue 3, p. 154-156
A convenient, one-step, synthesis of β-C-glycosidic ketones in aqueous media
journal, January 2000
- Rodrigues, Filipe; Canac, Yves; Lubineau, André
- Chemical Communications, Issue 20
Functional group dependence of the acid catalyzed ring opening of biomass derived furan rings: an experimental and theoretical study
journal, January 2013
- Waidmann, Christopher R.; Pierpont, Aaron W.; Batista, Enrique R.
- Catal. Sci. Technol., Vol. 3, Issue 1, p. 106-115