Methods of refining and producing dibasic esters and acids from natural oil feedstocks
Abstract
Methods and systems for making dibasic esters and/or dibasic acids using metathesis are generally disclosed. In some embodiments, the methods comprise reacting a terminal olefin ester with an internal olefin ester in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In some embodiments, the terminal olefin ester or the internal olefin ester are derived from a renewable feedstock, such as a natural oil feedstock. In some such embodiments, the natural oil feedstock, or a transesterified derivative thereof, is metathesized to make the terminal olefin ester or the internal olefin ester.
- Inventors:
- Issue Date:
- Research Org.:
- Elevance Renewable Sciences, Inc., Woodridge, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1257360
- Patent Number(s):
- 9365487
- Application Number:
- 14/048,673
- Assignee:
- Elevance Renewable Sciences, Inc. (Woodridge, IL)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
- DOE Contract Number:
- EE0002872/001
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2013 Oct 08
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 59 BASIC BIOLOGICAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 09 BIOMASS FUELS
Citation Formats
Snead, Thomas E., Cohen, Steven A., and Gildon, Demond L. Methods of refining and producing dibasic esters and acids from natural oil feedstocks. United States: N. p., 2016.
Web.
Snead, Thomas E., Cohen, Steven A., & Gildon, Demond L. Methods of refining and producing dibasic esters and acids from natural oil feedstocks. United States.
Snead, Thomas E., Cohen, Steven A., and Gildon, Demond L. Tue .
"Methods of refining and producing dibasic esters and acids from natural oil feedstocks". United States. https://www.osti.gov/servlets/purl/1257360.
@article{osti_1257360,
title = {Methods of refining and producing dibasic esters and acids from natural oil feedstocks},
author = {Snead, Thomas E. and Cohen, Steven A. and Gildon, Demond L.},
abstractNote = {Methods and systems for making dibasic esters and/or dibasic acids using metathesis are generally disclosed. In some embodiments, the methods comprise reacting a terminal olefin ester with an internal olefin ester in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In some embodiments, the terminal olefin ester or the internal olefin ester are derived from a renewable feedstock, such as a natural oil feedstock. In some such embodiments, the natural oil feedstock, or a transesterified derivative thereof, is metathesized to make the terminal olefin ester or the internal olefin ester.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {6}
}
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- Kim, Yong Woo; Min, Joon-Seok; Kim, Sung-Hyoan
- US Patent Document 7,431,749
Process of removing transition metals
patent, November 2008
- Brenner, Michael; Donsbach, Kai; Nicola, Thomas
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System for creating a biofuel
patent, November 2008
- Lafleur, Christof; Bouknight, Jr., Harry; Bouknight, Sr., Harry
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Method and apparatus for refining biodiesel
patent, March 2009
- Pelly, Michael F.
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Impurity reduction in Olefin metathesis reactions
patent, March 2009
- Lee, Choon Woo; Hong, Soon Hyeok; Sanders, Daniel P.
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Plug flow reactor and polymers prepared therewith
patent, March 2009
- Nguyen, Thanh T.; Reimers, Jay L.
- US Patent Document 7,511,101
Bio-fuel and process for making bio-fuel
patent, June 2009
- Morris, Martin Allan
- US Patent Document 7,553,982
Green biodiesel
patent, July 2009
- Matson, Jack V.; Kannan, Dheeban Chakravarthi
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Integrate chemical processes for industrial utilization of seed oils
patent, August 2009
- Lysenko, Zenon; Maughon, Bob R.; Bicerano, Josef
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Low trans-fatty acid fat compositions; low-temperature hydrogenation, e.g., of edible oils
patent, September 2009
- van Toor, Hans; Van Rossum, Gijsbertus; Kruidenberg, Marco
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Method and apparatus for processing vegetable oils
patent, October 2009
- Kruidenberg, Marco
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Method for processing vegetable oils
patent, October 2009
- Kruidenberg, Marco
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Metathesis unit pretreatment process with formation of octene
patent, October 2009
- Krupa, Steven L.; Meister, Jill M.
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Production of fatty acid alkyl esters
patent, November 2009
- Haas, Michael; Marmer, William N.; Foglia, Thomas A.
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Method of producing fatty acid alkyl ester for diesel fuel oil
patent, December 2009
- Nakayama, Masaru; Tsuto, Keiichi
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Methods and apparatus for removal of degradation byproducts and contaminants from oil for use in preparation of biodiesel
patent, December 2009
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Production of biodiesel and a side stream of crude glycerol which is converted to methanol
patent, January 2010
- Goetsch, Duane A.; Machay, Ian S.; White, Lloyd R.
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Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis
patent, January 2010
- Herrmann, Wolfgang Anton; Schattenmann, Wolfgang; Weskamp, Thomas
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Refined method for manufacturing ethyl esters from fatty substances of natural origin
patent, January 2010
- Hillion, Gerard; Delfort, Bruno
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Process for the preparation of fatty acid methyl ester from triglyceride oil by transesterification
patent, February 2010
- Ghosh, Pushpito Kumar; Adimurthy, Subbarayappa; Gandhi, Mahesh Ramnikbhai
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Use of a phosphorus containing ligand and a cyclic organic ligand in a transition metal compound
patent, March 2010
- Winde, Roland; Karch, Ralf; Rivas-Nass, Andreas
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Method for transesterifying vegetable oils
patent, April 2010
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Method for manufacture of esters by transesterification
patent, April 2010
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Stabilization of olefin metathesis product mixtures
patent, April 2010
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Purification of glycerin obtained as a bioproduct from the transesterification of triglycerides in the synthesis of biofuel
patent, May 2010
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Catalyst systems and their use for metathesis reactions
patent, June 2010
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Methods of cementing in subterranean formations using cement kiln cement kiln dust in compositions having reduced Portland cement content
patent, June 2010
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Integrated chemical processes for industrial utilization of seed oils
patent, June 2010
- Lysenko, Zenon; Maughon, Bob R.; Bicerano, Jozef
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High metathesis activity ruthenium and osmium carbene complexes
patent, July 2010
- Grubbs, Robert H.; Schwab, Peter; Nguyen, SonBinh T.
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Porous silica and metal oxide composite-based catalysts for conversion of fatty acids and oils to biodiesel
patent, September 2010
- Lin, Victor Shang-Yi; Nieweg, Jennifer A.; Verkade, John G.
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Production of biodiesel and glycerin from high free fatty acid feedstocks
patent, October 2010
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Metathesis process for preparing an alpha, omega-functionalized olefin
patent, October 2010
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Process for production of fatty acid alkyl ester and production apparatus for fatty acid alkyl ester
patent, October 2010
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Process for continuous ruthenium-catalysed metathesis
patent, November 2010
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Process for removing ruthenium-containing catalyst residues from optionally hydrogenated nitrile rubber
patent, December 2010
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Highly organized polyolefin structures
patent, December 2010
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Process for the transesterification of esters
patent, January 2011
- Krause, Eberhard; Rohm, Valentin
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Intermediate compounds and processes for the preparation of 7-benzyloxy-3-(4-methoxyphenyl)-2H-1-benzopyran
patent, January 2011
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Dual catalyst system for alkane metathesis
patent, March 2011
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Olefin metathesis for kerogen upgrading
patent, March 2011
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Solid catalyst system for biodiesel production
patent, March 2011
- Lin, Victor Shang-Yi; Cai, Yang; Kern, Carla
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Process for preparing nitriles by elimination reactions
patent, May 2011
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Method and apparatus for preparing fatty acid alkyl ester using fatty acid
patent, May 2011
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Selective, integrated processing of bio-derived ester species to yield low molecular weight hydrocarbons and hydrogen for the production of biofuels
patent, June 2011
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Methods for producing biodiesel
patent, October 2011
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Methods and apparatus for removal of degradation byproducts and contaminants from oil for use in preparation of biodiesel
patent, October 2011
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Process for production of hydrogenated polymers and hydrogenated polymers
patent, October 2011
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Plug flow reactor and polymers prepared therewith
patent, November 2011
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Chain-selective synthesis of fuel components and chemical feedstocks
patent, December 2011
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Selective, integrated processing of bio-derived ester species to yield low molecular weight hydrocarbons and hydrogen for the production of biofuels
patent, April 2012
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Tubular flow reactor and method of manufacturing polymeric resin fine particle
patent, April 2012
- Saita, Yasuharu; Mamino, Masashi
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Methods and catalysts for making biodiesel from the transesterification and esterification of unrefined oils
patent, April 2012
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System and process of biodiesel production
patent, June 2012
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Bio-fuel and process for making bio-fuel
patent, June 2012
- Morris, Martin Allan
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Class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof
patent, July 2012
- Holtcamp, Matthew W.; Bedoya, Matthew S.; McCullough, Laughlin G.
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Apparatus and method for carrying out multiple reactions
patent, July 2012
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Metathesis catalyst and process for use thereof
patent, August 2012
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Tubular flow reactor and method for producing resin particle using the same
patent, October 2012
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PET radiotracers
patent, November 2012
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Telechelic olefin metathesis polymers from renewable feedstocks
patent, December 2012
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Low melting point triglycerides for use in fuels
patent, December 2012
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Process for the manufacture of saturated fatty acid esters
patent, December 2012
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Metathesis of unsaturated fatty acid esters or unsaturated fatty acids with lower olefins
patent-application, March 2005
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Process for the synthesis of unsaturated alcohols
patent-application, April 2005
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Integrate chemical processes for industrial utilization of seed oils
patent-application, July 2005
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Fuel products from plant or animal lipids
patent-application, March 2006
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Methods, compositions, and apparatuses for forming macrocyclic compounds
patent-application, September 2007
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Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis
patent-application, January 2008
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Synthesis of Liquid Fuels and Chemicals from Oxygenated Hydrocarbons
patent-application, December 2008
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Method of Making Hydrogenated Metathesis Products
patent-application, February 2009
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Methods of Making Organic Compounds by Metathesis
patent-application, October 2009
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Hot Melt Adhesive Compositions Comprising Metathesized Unsaturated Polyol Ester Wax
patent-application, February 2010
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Metathesis Methods Involving Hydrogenation and Compositions Relating to Same
patent-application, April 2010
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Methods for Producing Biodiesel
patent-application, October 2010
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Adiabatic Plug Flow Reactors and Processes Incorporating the Same
patent-application, April 2011
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Fuel and Chemical Production from Oleaginous Yeast
patent-application, October 2011
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