skip to main content
DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Conductive open frameworks

Abstract

The disclosure relates generally to materials that comprise conductive covalent organic frameworks. The disclosure also relates to materials that are useful to store and separate gas molecules and sensors.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
Univ. of California, Oakland, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1239667
Patent Number(s):
9269473
Application Number:
13/876,126
Assignee:
The Regents of the University of California (Oakland, CA)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01B - CABLES
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
FG36-05GO15001
Resource Type:
Patent
Resource Relation:
Patent File Date: 2011 Sep 27
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Yaghi, Omar M., Wan, Shun, Doonan, Christian J., Wang, Bo, and Deng, Hexiang. Conductive open frameworks. United States: N. p., 2016. Web.
Yaghi, Omar M., Wan, Shun, Doonan, Christian J., Wang, Bo, & Deng, Hexiang. Conductive open frameworks. United States.
Yaghi, Omar M., Wan, Shun, Doonan, Christian J., Wang, Bo, and Deng, Hexiang. Tue . "Conductive open frameworks". United States. https://www.osti.gov/servlets/purl/1239667.
@article{osti_1239667,
title = {Conductive open frameworks},
author = {Yaghi, Omar M. and Wan, Shun and Doonan, Christian J. and Wang, Bo and Deng, Hexiang},
abstractNote = {The disclosure relates generally to materials that comprise conductive covalent organic frameworks. The disclosure also relates to materials that are useful to store and separate gas molecules and sensors.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {2}
}

Patent:

Save / Share:

Works referenced in this record:

Post-Synthetic Modification of Tagged Metal-Organic Frameworks
journal, October 2008


High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture
journal, February 2008


Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties
journal, March 2009


Azulene based metal–organic frameworks for strong adsorption of H2
journal, January 2010


Tailored Porous Materials
journal, October 1999


Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine
journal, October 2010


1,4-Benzenedicarboxylate derivatives as links in the design of paddle-wheel units and metal–organic frameworks
journal, November 2001


Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites
journal, November 2009


Polycatenation, polythreading and polyknotting in coordination network chemistry
journal, November 2003


Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008

  • Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
  • https://doi.org/10.1021/ja8036096

Raman spectra of hydrogen and deuterium adsorbed on a metal–organic framework
journal, August 2005


Tertiary Building Units:  Synthesis, Structure, and Porosity of a Metal−Organic Dendrimer Framework (MODF-1)
October 2001


Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology
journal, August 2003


A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004


Cu2(ATC)·6H2O:  Design of Open Metal Sites in Porous Metal−Organic Crystals (ATC:  1,3,5,7-Adamantane Tetracarboxylate)
journal, November 2000


Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores
journal, February 2001


Transformation of a Metal−Organic Framework from the NbO to PtS Net
journal, January 2005


High H2 Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites
journal, July 2005


A Microporous Metal–Organic Framework for Gas-Chromatographic Separation of Alkanes
journal, February 2006


A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation
journal, January 2006


Heterogeneity within Order in Crystals of a Porous Metal–Organic Framework
journal, August 2011


Industrial applications of metal–organic frameworks
journal, January 2009


Three-periodic nets and tilings: regular and quasiregular nets
journal, December 2002


Three-periodic nets and tilings: semiregular nets
journal, October 2003


The CdSO4, rutile, cooperite and quartz dual nets: interpenetration and catenation
journal, January 2003


Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks
journal, March 2005


What do we know about three-periodic nets?
journal, August 2005


Three-periodic nets and tilings: edge-transitive binodal structures
journal, August 2006


Taxonomy of periodic nets and the design of materials
journal, January 2007


Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
journal, February 2010


Robust dynamics
journal, May 2010


Isoreticular Metalation of Metal−Organic Frameworks
journal, July 2009

  • Doonan, Christian J.; Morris, William; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 131, Issue 27, p. 9492-9493
  • https://doi.org/10.1021/ja903251e

Design of New Materials for Methane Storage
journal, March 2004


Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties
journal, February 2000


Porous Metal−Organic Polyhedra:  25 Å Cuboctahedron Constructed from 12 Cu2(CO2)4 Paddle-Wheel Building Blocks
journal, May 2001


Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
journal, April 2001


Geometric requirements and examples of important structures in the assembly of square building blocks
journal, April 2002


Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002


Cu2[o-Br-C6H3(CO2)2]2(H2O)2·(DMF)8(H2O)2:  A Framework Deliberately Designed To Have the NbO Structure Type
journal, January 2002


Positronium formation in porous materials for antihydrogen production
journal, April 2010


Crystal Structure, Dissolution, and Deposition of a 5 nm Functionalized Metal−Organic Great Rhombicuboctahedron
journal, July 2006


Independent verification of the saturation hydrogen uptake in MOF-177 and establishment of a benchmark for hydrogen adsorption in metal–organic frameworks
journal, January 2007


Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal−Organic Frameworks and Polyhedra
journal, September 2008


Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010


MOF-74 building unit has a direct impact on toxic gas adsorption
journal, January 2011


Amphidynamic Character of Crystalline MOF-5: Rotational Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered Environment
journal, March 2008

  • Gould, Stephanie L.; Tranchemontagne, David; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 130, Issue 11, p. 3246-3247
  • https://doi.org/10.1021/ja077122c

Polymer-Induced Heteronucleation for the Discovery of New Extended Solids
journal, April 2006


Topological Control in Heterometallic Metal−Organic Frameworks by Anion Templating and Metalloligand Design
journal, November 2006


Improved Designs of Metal-Organic Frameworks for Hydrogen Storage
journal, July 2007


Zeolite A imidazolate frameworks
journal, May 2007


Thermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement
journal, February 2007


Metal-organic frameworks—New materials for hydrogen storage
journal, April 2007


Asymmetric catalytic reactions by NbO-type chiral metal–organic frameworks
journal, January 2011


Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)
journal, November 2007


Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units:  New Examples and Simplifying Principles for Complex Structures
journal, August 2001


A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008


Establishing Microporosity in Open Metal−Organic Frameworks:  Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate)
journal, August 1998


Porous Germanates:  Synthesis, Structure, and Inclusion Properties of Ge7O14.5F2·[(CH3)2NH2]3(H2O)0.86
journal, August 1998


Transformation of Germanium Dioxide to Microporous Germanate 4-Connected Nets
journal, October 1998


An Open-Framework Germanate with Polycubane-Like Topology
journal, March 1999


Supertetrahedral Sulfide Crystals with Giant Cavities and Channels
journal, February 1999


Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999


Ge2ZrO6F2·(H2DAB)H2O:1  A 4-Connected Microporous Material with “Bow Tie” Building Units and an Exceptional Proportion of 3-Rings
journal, December 2000


20 Å Cd4In16S3514- Supertetrahedral T4 Clusters as Building Units in Decorated Cristobalite Frameworks
journal, May 2001


[Cd16In64S134]44-: 31-Å Tetrahedron with a Large Cavity
journal, April 2003


A metal–organic framework replete with ordered donor–acceptor catenanes
journal, January 2010


A Catenated Strut in a Catenated Metal-Organic Framework
journal, August 2010


MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF
journal, September 2007


Synthesis and Structure of Chemically Stable Metal−Organic Polyhedra
journal, September 2009


Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature
journal, December 2005


Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks
journal, September 2008

  • Morris, William; Doonan, Christian J.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 130, Issue 38, p. 12626-12627
  • https://doi.org/10.1021/ja805222x

A Combined Experimental−Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks
journal, August 2010


Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake
journal, August 2011


Non-carboxylate based metal-organic frameworks (MOFs) and related aspects
journal, June 2009


Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links
journal, September 2005


Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs
journal, May 2008


Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach
journal, June 2008


Exceptional H2 Saturation Uptake in Microporous Metal−Organic Frameworks
journal, March 2006


Selective binding and removal of guests in a microporous metal–organic framework
journal, December 1995


Conversion of hydrogen-bonded manganese(II) and zinc(II) squarate (C4O42–) molecules, chains and sheets to three-dimensional cage networks
journal, January 1995


Mutually Interpenetrating Sheets and Channels in the Extended Structure of [Cu(4,4′-bpy)Cl]
journal, February 1995


Preparation of Single Crystals of Coordination Solids in Silica Gels: Synthesis and Structure of CuII(1,4-C4H4N2)(C4O4)(OH2)4
journal, July 1995


Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels
journal, October 1995


Construction of Microporous Materials from Molecular Building Blocks
book, January 2002


T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4‘-bpy)·NO3
journal, January 1996


Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid
journal, January 1996


Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)−Benzenetricarboxylate Network
journal, March 1997


Crystal Growth of Extended Solids by Nonaqueous Gel Diffusion
journal, May 1997


A Molecular Railroad with Large Pores:  Synthesis and Structure of Ni(4,4‘-bpy)2.5(H2O)2(ClO4)2·1.5(4,4‘-bpy)·2H2O
journal, September 1997


Construction of a new open-framework solid from 1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks
journal, January 1997

  • Yaghi, Omar M.; Jernigan, Ryan; Li, Hailian
  • Journal of the Chemical Society, Dalton Transactions, Vol. 0, Issue 14, p. 2383-2384
  • https://doi.org/10.1039/A702287E

Synthesis and Structure of a Metal-Organic Solid Having the Cadmium(II) Sulfate Net
journal, January 1996


Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry
journal, June 2000


Reticular synthesis and the design of new materials
journal, June 2003


Reticular Chemistry and Metal-Organic Frameworks for Clean Energy
journal, September 2009


Docking in Metal-Organic Frameworks
journal, August 2009


Rigid-Strut-Containing Crown Ethers and [2]Catenanes for Incorporation into Metal-Organic Frameworks
journal, November 2009


A Nearly Planar Water Sheet Sandwiched between Strontium−Imidazolium Carboxylate Coordination Polymers
journal, July 2005


Phthalocyanine-based nanoporous network polymers
journal, October 2002


Porphyrin-based nanoporous network polymers
journal, October 2002


Lewis acid-catalysed formation of two-dimensional phthalocyanine covalent organic frameworks
journal, June 2010


A Belt-Shaped, Blue Luminescent, and Semiconducting Covalent Organic Framework
journal, November 2008


Covalent Organic Frameworks with High Charge Carrier Mobility
journal, September 2011


A Metal−Organic Framework with Covalently Bound Organometallic Complexes
journal, July 2010


Frameworks for Extended Solids: Geometrical Design Principles
journal, June 2000


The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets
journal, December 2008


Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006


Hyperpolarized 129Xe Nuclear Magnetic Resonance Studies of Isoreticular Metal-Organic Frameworks
journal, April 2007


Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks
journal, January 2010


Metal–Organic Frameworks of Vanadium as Catalysts for Conversion of Methane to Acetic Acid
journal, August 2011


A Flexible Germanate Structure Containing 24-Ring Channels and with Very Low Framework Density
journal, December 2001


Synthesis and Characterization of Zirconogermanates
journal, September 2003


Layered Structures Constructed from New Linkages of Ge7(O,OH,F)19 Clusters
journal, February 2003


From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites
journal, March 1999


A Microporous Lanthanide-Organic Framework
journal, September 1999


Large Free Volume in Maximally Interpenetrating Networks:  The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO]1
journal, May 2000


Hydrogen Storage in Microporous Metal-Organic Frameworks
journal, May 2003


Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units
journal, February 2005


Hydrogen Sorption in Functionalized Metal−Organic Frameworks
journal, May 2004

  • Rowsell, Jesse L. C.; Millward, Andrew R.; Park, Kyo Sung
  • Journal of the American Chemical Society, Vol. 126, Issue 18, p. 5666-5667
  • https://doi.org/10.1021/ja049408c

Metal–organic frameworks: a new class of porous materials
journal, August 2004


Strategies for Hydrogen Storage in Metal-Organic Frameworks
journal, July 2005


Gas Adsorption Sites in a Large-Pore Metal-Organic Framework
journal, August 2005


Characterization of H2 Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering
journal, October 2005

  • Rowsell, Jesse L. C.; Eckert, Juergen; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 127, Issue 42, p. 14904-14910
  • https://doi.org/10.1021/ja0542690

Raman Spectroscopic Investigation of CH4 and N2 Adsorption in Metal−Organic Frameworks
journal, July 2007


Metal-Organic Frameworks from Edible Natural Products
journal, August 2010


Determination of the hydrogen absorption sites in Zn4O(1,4-benzenedicarboxylate) by single crystal neutron diffraction
journal, January 2006


NMR Studies on the Diffusion of Hydrocarbons on the Metal-Organic Framework Material MOF-5
journal, March 2006


Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
journal, May 2005

  • Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W.
  • Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118
  • https://doi.org/10.1021/ja042802q

Metal-Organic Frameworks Based on Trigonal Prismatic Building Blocks and the New “acs” Topology
journal, May 2005


A Metal–Organic Framework with a Hierarchical System of Pores and Tetrahedral Building Blocks
journal, April 2006


Metal-organic frameworks with high capacity and selectivity for harmful gases
journal, August 2008


Reticular Chemistry of Metal–Organic Polyhedra
journal, June 2008


Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0
journal, September 2008


A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
journal, April 2009

  • Uribe-Romo, Fernando J.; Hunt, Joseph R.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 131, Issue 13, p. 4570-4571
  • https://doi.org/10.1021/ja8096256

Crystalline Covalent Organic Frameworks with Hydrazone Linkages
journal, August 2011

  • Uribe-Romo, Fernando J.; Doonan, Christian J.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 133, Issue 30, p. 11478-11481
  • https://doi.org/10.1021/ja204728y

Synthesis of Metal−Organic Complex Arrays
journal, February 2011

  • Vairaprakash, Pothiappan; Ueki, Hisanori; Tashiro, Kentaro
  • Journal of the American Chemical Society, Vol. 133, Issue 4, p. 759-761
  • https://doi.org/10.1021/ja1097644

Metal–organic frameworks with designed chiral recognition sites
journal, January 2010


Metal–organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units
journal, November 2001


Computation of Aromatic C3N4 Networks and Synthesis of the Molecular Precursor N(C3N3)3Cl6
journal, September 2003


Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks
journal, January 2008


Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework
journal, October 2007