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Title: High rate, long cycle life battery electrode materials with an open framework structure

A battery includes a cathode, an anode, and an aqueous electrolyte disposed between the cathode and the anode and including a cation A. At least one of the cathode and the anode includes an electrode material having an open framework crystal structure into which the cation A is reversibly inserted during operation of the battery. The battery has a reference specific capacity when cycled at a reference rate, and at least 75% of the reference specific capacity is retained when the battery is cycled at 10 times the reference rate.
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Issue Date:
OSTI Identifier:
The Board of Trustees of the Leland Stanford Junior University (Palo Alto, CA) ORO
Patent Number(s):
Application Number:
Contract Number:
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
Country of Publication:
United States

Works referenced in this record:

Hexacyanoferrate layers as electrodes for secondary cells
journal, May 1987
  • Grabner, E. W.; Kalwellis-Mohn, S.
  • Journal of Applied Electrochemistry, Vol. 17, Issue 3, p. 653-656
  • DOI: 10.1007/BF01084142

Prussian Blue Containing Nafion Composite Film as Rechargeable Battery
journal, January 1987
  • Honda, Kenji; Hayashi, Hideko
  • Journal of The Electrochemical Society, Vol. 134, Issue 6, p. 1330-1334
  • DOI: 10.1149/1.2100668

Charge–discharge characteristics of a solid-state Prussian blue secondary cell
journal, April 2000

Performance characteristics of zinc hexacyanoferrate/Prussian blue and copper hexacyanoferrate/Prussian blue solid state secondary cells
journal, December 2000

A secondary cell based on thin layers of zeolite-like nickel hexacyanometallates
journal, August 1989

A secondary battery composed of multilayer Prussian Blue and its reaction characteristics
journal, November 1988
  • Kaneko, Masao; Okada, Tokuo
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 255, Issue 1-2, p. 45-52
  • DOI: 10.1016/0022-0728(88)80003-2

Na4Mn9O18 as a positive electrode material for an aqueous electrolyte sodium-ion energy storage device
journal, March 2010

Polypyrrole/carbon aerogel composite materials for supercapacitor
journal, October 2010

Electrochemical preparation, characterization and application of electrodes modified with hybrid hexacyanoferrates of copper and cobalt
journal, May 2002
  • Cui, Xingpin; Hong, Li; Lin, Xiangqin
  • Journal of Electroanalytical Chemistry, Vol. 526, Issue 1-2, p. 115-124
  • DOI: 10.1016/S0022-0728(02)00724-6

Effects of surface structure on electrode charge transfer properties: Induction of ion selectivity at the chemically derivatized interface
journal, November 1982
  • Bocarsly, Andrew B.; Sinha, Sujit
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 140, Issue 1, p. 167-172
  • DOI: 10.1016/0368-1874(82)85310-0

Potassium secondary cell based on Prussian blue cathode
journal, February 2004

Polypyrrole/carbon composite electrode for high-power electrochemical capacitors
journal, December 2006

The crystal structure of Prussian Blue: Fe4[Fe(CN)6]3.xH2O
journal, November 1977
  • Buser, H. J.; Schwarzenbach, D.; Petter, W.
  • Inorganic Chemistry, Vol. 16, Issue 11, p. 2704-2710
  • DOI: 10.1021/ic50177a008

Cobalt(III) lithium oxide, CoLiO2: structure refinement by powder neutron diffraction
journal, January 1984
  • Orman, H. J.; Wiseman, P. J.
  • Acta Crystallographica Section C Crystal Structure Communications, Vol. 40, Issue 1, p. 12-14
  • DOI: 10.1107/S0108270184002833

Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997
  • Padhi, A. K.
  • Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194
  • DOI: 10.1149/1.1837571

Application of Stokes' law to ions in aqueous solution
journal, March 1990
  • Pau, Paul Chi Fu.; Berg, J. O.; McMillan, W. G.
  • The Journal of Physical Chemistry, Vol. 94, Issue 6, p. 2671-2679
  • DOI: 10.1021/j100369a080