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Title: Tunable electrical conductivity in metal-organic framework thin film devices

A composition including a porous metal organic framework (MOF) including an open metal site and a guest species capable of charge transfer that can coordinate with the open metal site, wherein the composition is electrically conductive. A method including infiltrating a porous metal organic framework (MOF) including an open metal site with a guest species that is capable of charge transfer; and coordinating the guest species to the open metal site to form a composition including an electrical conductivity greater than an electrical conductivity of the MOF.
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Issue Date:
OSTI Identifier:
Sandia Corporation (Albuquerque, NM) SNL-A
Patent Number(s):
Application Number:
Contract Number:
Resource Relation:
Patent File Date: 2014 Aug 26
Research Org:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org:
Country of Publication:
United States

Works referenced in this record:

Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method
journal, June 2012
  • Gándara, Felipe; Uribe-Romo, Fernando J.; Britt, David K.
  • Chemistry - A European Journal, Vol. 18, Issue 34, p. 10595-10601
  • DOI: 10.1002/chem.201103433

Degree of charge transfer in organic conductors by infrared absorption spectroscopy
journal, May 1981
  • Chappell, J. S.; Bloch, A. N.; Bryden, W. A.
  • Journal of the American Chemical Society, Vol. 103, Issue 9, p. 2442-2443
  • DOI: 10.1021/ja00399a066

A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n
journal, February 1999

Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
journal, April 2001
  • Eddaoudi, Mohamed; Moler, David B.; Li, Hailian
  • Accounts of Chemical Research, Vol. 34, Issue 4, p. 319-330
  • DOI: 10.1021/ar000034b

Hybrid porous solids past, present, future
journal, January 2008
  • Férey, Gérard
  • Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214
  • DOI: 10.1039/B618320B

Electrochemistry and electron spin resonance of tetracyanoquinodimethane modified electrodes. Evidence for mixed-valence radical anions in the reduction process
journal, November 1983
  • Inzelt, Gyorgy; Day, Roger W.; Kinstle, James F.
  • The Journal of Physical Chemistry, Vol. 87, Issue 23, p. 4592-4598
  • DOI: 10.1021/j100246a012

The UV spectra and their calculation of TCNQ and its mono- and di-valent anion
journal, September 1972

Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011
  • Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
  • Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
  • DOI: 10.1021/cr200324t

Metal–Organic Frameworks for Separations
journal, September 2011
  • Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
  • Chemical Reviews, Vol. 112, Issue 2, p. 869-932
  • DOI: 10.1021/cr200190s

Growth Mechanism of Metal-Organic Frameworks: Insights into the Nucleation by Employing a Step-by-Step Route
journal, June 2009
  • Shekhah, Osama; Wang, Hui; Zacher, Denise
  • Angewandte Chemie International Edition, Vol. 48, Issue 27, p. 5038-5041
  • DOI: 10.1002/anie.200900378

MOF-Based Catalysts for Selective Hydrogenolysis of Carbon–Oxygen Ether Bonds
journal, November 2015
  • Stavila, Vitalie; Parthasarathi, Ramakrishnan; Davis, Ryan W.
  • ACS Catalysis, Vol. 6, Issue 1, p. 55-59
  • DOI: 10.1021/acscatal.5b02061

EasySpin, a comprehensive software package for spectral simulation and analysis in EPR
journal, January 2006

Hydrogen Storage in Metal–Organic Frameworks
journal, September 2011
  • Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri
  • Chemical Reviews, Vol. 112, Issue 2, p. 782-835
  • DOI: 10.1021/cr200274s

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
  • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
  • DOI: 10.1021/cr2003272

Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices
journal, December 2013
  • Talin, A. Alec; Centrone, Andrea; Ford, Alexandra C.
  • Science, Vol. 343, Issue 6166, p. 66-69
  • DOI: 10.1126/science.1246738

Reticular synthesis and the design of new materials
journal, June 2003
  • Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W.
  • Nature, Vol. 423, Issue 6941, p. 705-714
  • DOI: 10.1038/nature01650