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Title: Tunable electrical conductivity in metal-organic framework thin film devices

Abstract

A composition including a porous metal organic framework (MOF) including an open metal site and a guest species capable of charge transfer that can coordinate with the open metal site, wherein the composition is electrically conductive. A method including infiltrating a porous metal organic framework (MOF) including an open metal site with a guest species that is capable of charge transfer; and coordinating the guest species to the open metal site to form a composition including an electrical conductivity greater than an electrical conductivity of the MOF.

Inventors:
; ; ;
Issue Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1254264
Patent Number(s):
9346831
Application Number:
14/469,459
Assignee:
Sandia Corporation (Albuquerque, NM)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Patent
Resource Relation:
Patent File Date: 2014 Aug 26
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Talin, Albert Alec, Allendorf, Mark D., Stavila, Vitalie, and Leonard, Francois. Tunable electrical conductivity in metal-organic framework thin film devices. United States: N. p., 2016. Web.
Talin, Albert Alec, Allendorf, Mark D., Stavila, Vitalie, & Leonard, Francois. Tunable electrical conductivity in metal-organic framework thin film devices. United States.
Talin, Albert Alec, Allendorf, Mark D., Stavila, Vitalie, and Leonard, Francois. Tue . "Tunable electrical conductivity in metal-organic framework thin film devices". United States. https://www.osti.gov/servlets/purl/1254264.
@article{osti_1254264,
title = {Tunable electrical conductivity in metal-organic framework thin film devices},
author = {Talin, Albert Alec and Allendorf, Mark D. and Stavila, Vitalie and Leonard, Francois},
abstractNote = {A composition including a porous metal organic framework (MOF) including an open metal site and a guest species capable of charge transfer that can coordinate with the open metal site, wherein the composition is electrically conductive. A method including infiltrating a porous metal organic framework (MOF) including an open metal site with a guest species that is capable of charge transfer; and coordinating the guest species to the open metal site to form a composition including an electrical conductivity greater than an electrical conductivity of the MOF.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {5}
}

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