Functionalized expanded porphyrins

Sessler, Jonathan L; Pantos, Patricia J

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Title: Functionalized expanded porphyrins

Abstract

Disclosed are functionalized expanded porphyrins that can be used as spectrometric sensors for high-valent actinide cations. The disclosed functionalized expanded porphyrins have the advantage over unfunctionalized systems in that they can be immobilized via covalent attachment to a solid support comprising an inorganic or organic polymer or other common substrates. Substrates comprising the disclosed functionalized expanded porphyrins are also disclosed. Further, disclosed are methods of making the disclosed compounds (immobilized and free), methods of using them as sensors to detect high valent actinides, devices that comprise the disclosed compounds, and kits.

Inventors:: Sessler, Jonathan L; Pantos, Patricia J

Issue Date:: 2013-11-12

Research Org.:: The University of Texas (Austin, TX)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1107917

Patent Number(s):: 8580845

Application Number:: 12/664,524

Assignee:: Board of Regents, The University of Texas System (Austin, TX)

Patent Classifications (CPCs):: A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61K - PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES

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A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61K - PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
A61K31/407 - condensed with other heterocyclic ring systems, e.g. ketorolac, physostigmine
A61K41/0076 - {PDT with expanded

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DOE Contract Number:: FG03-01ER15186

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Sessler, Jonathan L, and Pantos, Patricia J. Functionalized expanded porphyrins.  United States: N. p., 2013. 
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                    Sessler, Jonathan L, & Pantos, Patricia J. Functionalized expanded porphyrins.  United States.

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                    Sessler, Jonathan L, and Pantos, Patricia J. Tue .  
        "Functionalized expanded porphyrins".  United States.  https://www.osti.gov/servlets/purl/1107917.

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@article{osti_1107917,

  title        = {Functionalized expanded porphyrins},

  author       = {Sessler, Jonathan L and Pantos, Patricia J},

  abstractNote = {Disclosed are functionalized expanded porphyrins that can be used as spectrometric sensors for high-valent actinide cations. The disclosed functionalized expanded porphyrins have the advantage over unfunctionalized systems in that they can be immobilized via covalent attachment to a solid support comprising an inorganic or organic polymer or other common substrates. Substrates comprising the disclosed functionalized expanded porphyrins are also disclosed. Further, disclosed are methods of making the disclosed compounds (immobilized and free), methods of using them as sensors to detect high valent actinides, devices that comprise the disclosed compounds, and kits.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2013},

  month        = {11}

}

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Similar Records

Title: Functionalized expanded porphyrins

Abstract

Citation Formats

Texaphyrin-oligonucleotide conjugates patent, December 1996

Detection system based on an analyte reactive particle patent, August 2003

Synthetic Expanded Porphyrin Chemistry journal, November 2003

Hexaphyrin(1.0.1.0.0.0). A new colorimetric actinide sensor journal, November 2004

Metal complexes of water soluble texaphyrins patent, October 1993

Schiff base oligopyrrolic macrocycles as ligands for lanthanides and actinides journal, July 2006

Sapphyrin derivatives and conjugates patent, October 1995

A non-ionic water-soluble pentaphyrin derivative. Synthesis and cytotoxicity journal, May 1995

A Facile and Efficient Method for the Preparation of New meso-Arylbisdipyrrins journal, January 2000

Cyclo[n]pyrroles and methods thereto patent, January 2006

Discovery of Powerful Uranyl Ligands from Efficient Synthesis and Screening journal, June 2005

Poly(methyl methacrylate)s with pendant calixpyrroles: polymeric extractants for halide anion salts journal, January 2008

Synthesis of Orthogonally Protected Pyrrole Tricarboxylic Acid Derivatives: Versatile Building Blocks for Pyrrole-Containing Compounds journal, January 2006

Microfabricated capillary electrophoresis sensor for uranium (VI) journal, June 2001

Development of Multianalyte Sensor Arrays Composed of Chemically Derivatized Polymeric Microspheres Localized in Micromachined Cavities journal, February 2001

Multishell Microspheres with Integrated Chromatographic and Detection Layers for Use in Array Sensors journal, February 2003

Expanded porphyrins: large porphyrin-like tripyrroledimethine-derived macrocycles patent, November 1994

Texaphyrin Metal Complex Mediated Ester Hydrolysis patent, September 1996

Characterization of the interactions between neptunyl and plutonyl cations and expanded porphyrins journal, December 2002

High-yielding ullmann reaction for the preparation of bipyrroles patent, May 1998

Uranium complexes of multidentate N-donor ligands journal, April 2006

Water-soluble sapphyrins patent, August 1996

The first “crowned” expanded porphyrin journal, February 1995

Texaphyrins: Synthesis and Applications journal, February 1994

POLYMER PULLS ION PAIRS FROM WATER: POLYMER CHEMISTRY: Bifunctional material could have medical and environmental applications journal, October 2008

A new procedure for the spectrophotometric determination of uranium(VI) in the presence of a large excess of thorium(IV) journal, January 2002

Synthesis and characterization of a hexaphyrin(1.0.1.0.0.0) bearing both meso - and β-substituents journal, April 2007

Crosslinked amine polymers patent, February 2008

Process for preparing expanded porphyrins: large porphyrin-like tripyrroledimethine-derived macrocycles patent, November 1992

Poly(methyl methacrylate)s with Pendant Calixpyrroles and Crown Ethers: Polymeric Extractants for Potassium Halides journal, December 2008

Schiff-base porphyrin and expanded porphyrin analogs journal, January 2004

Water soluble texaphyrin metal complex preparation patent, October 1996

An Efficient, High-Yield Preparation of Substituted 2,2′-Bipyrroles journal, January 1994

Texaphyrins journal, April 2000

Method of expanded porphyrin-oligonucleotide conjugate synthesis patent, October 1996

Calixpyrroles, calixpyridinopyrroles and calixpyridines patent, July 2001

Sapphyrins, derivatives and syntheses patent, October 1992

Interactions of uranium and thorium with arsenazo III in an aqueous medium journal, April 1997

Method of cleaving DNA patent, September 1997

A uranyl ion-sensitive chromoionophore based on calix[6]arene journal, January 1994

Expanded porphyrins: large porphyrin-like tripyrroledimethine-derived macrocycles for singlet oxygen production patent, March 1994

The synthesis of a new 22 π-electron macrocycle: pentaphyrin journal, January 1983

Texaphyrin compounds having improved functionalization patent, February 1997

5,15,25-tris-nor-Hexapyrrin: the first structurally characterized linear hexapyrrin journal, January 1994

Rational tetraarylporphyrin syntheses: tetraarylporphyrins from the MacDonald route journal, December 1993

New polyethyleneglycol-functionalized texaphyrins: synthesis and in vitro biological studies journal, January 2006

Actinide Carbonte Complexes and Their Importance in Actinide Environmental Chemistry journal, January 1995

Halogenated calixpyrroles and uses thereof patent, May 2006

Calixpyrroles patent, October 2006

A New and Convenient Method of Generating Alkyl Isocyanates from Alcohols­, Thiols and Trimethylsilyl Ethers Using Triphenylphosphine/2,3-Dichloro-5,6-dicyanobenzoquinone/Bu 4 NOCN journal, January 2005

Sensor arrays for the measurement and identification of multiple analytes in solutions patent, January 2004

Synthesis and Biolocalization of Water-Soluble Sapphyrins journal, January 2002

Redox Behavior of Cyclo[6]pyrrole in the Formation of a Uranyl Complex journal, June 2007

Texaphyrin-oligonucleotide conjugates
patent, December 1996

Detection system based on an analyte reactive particle
patent, August 2003

Synthetic Expanded Porphyrin Chemistry
journal, November 2003

Hexaphyrin(1.0.1.0.0.0). A new colorimetric actinide sensor
journal, November 2004

Metal complexes of water soluble texaphyrins
patent, October 1993

Schiff base oligopyrrolic macrocycles as ligands for lanthanides and actinides
journal, July 2006

Sapphyrin derivatives and conjugates
patent, October 1995

A non-ionic water-soluble pentaphyrin derivative. Synthesis and cytotoxicity
journal, May 1995

A Facile and Efficient Method for the Preparation of New meso-Arylbisdipyrrins
journal, January 2000

Cyclo[n]pyrroles and methods thereto
patent, January 2006

Discovery of Powerful Uranyl Ligands from Efficient Synthesis and Screening
journal, June 2005

Poly(methyl methacrylate)s with pendant calixpyrroles: polymeric extractants for halide anion salts
journal, January 2008

Synthesis of Orthogonally Protected Pyrrole Tricarboxylic Acid Derivatives: Versatile Building Blocks for Pyrrole-Containing Compounds
journal, January 2006

Microfabricated capillary electrophoresis sensor for uranium (VI)
journal, June 2001

Development of Multianalyte Sensor Arrays Composed of Chemically Derivatized Polymeric Microspheres Localized in Micromachined Cavities
journal, February 2001

Multishell Microspheres with Integrated Chromatographic and Detection Layers for Use in Array Sensors
journal, February 2003

Expanded porphyrins: large porphyrin-like tripyrroledimethine-derived macrocycles
patent, November 1994

Texaphyrin Metal Complex Mediated Ester Hydrolysis
patent, September 1996

Characterization of the interactions between neptunyl and plutonyl cations and expanded porphyrins
journal, December 2002

High-yielding ullmann reaction for the preparation of bipyrroles
patent, May 1998

Uranium complexes of multidentate N-donor ligands
journal, April 2006

Water-soluble sapphyrins
patent, August 1996

The first “crowned” expanded porphyrin
journal, February 1995

Texaphyrins: Synthesis and Applications
journal, February 1994

POLYMER PULLS ION PAIRS FROM WATER: POLYMER CHEMISTRY: Bifunctional material could have medical and environmental applications
journal, October 2008

A new procedure for the spectrophotometric determination of uranium(VI) in the presence of a large excess of thorium(IV)
journal, January 2002

Synthesis and characterization of a hexaphyrin(1.0.1.0.0.0) bearing both meso - and β-substituents
journal, April 2007

Crosslinked amine polymers
patent, February 2008

Process for preparing expanded porphyrins: large porphyrin-like tripyrroledimethine-derived macrocycles
patent, November 1992

Poly(methyl methacrylate)s with Pendant Calixpyrroles and Crown Ethers: Polymeric Extractants for Potassium Halides
journal, December 2008

Schiff-base porphyrin and expanded porphyrin analogs
journal, January 2004

Water soluble texaphyrin metal complex preparation
patent, October 1996

An Efficient, High-Yield Preparation of Substituted 2,2′-Bipyrroles
journal, January 1994

Texaphyrins
journal, April 2000

Method of expanded porphyrin-oligonucleotide conjugate synthesis
patent, October 1996

Calixpyrroles, calixpyridinopyrroles and calixpyridines
patent, July 2001

Sapphyrins, derivatives and syntheses
patent, October 1992

Interactions of uranium and thorium with arsenazo III in an aqueous medium
journal, April 1997

Method of cleaving DNA
patent, September 1997

A uranyl ion-sensitive chromoionophore based on calix[6]arene
journal, January 1994

Expanded porphyrins: large porphyrin-like tripyrroledimethine-derived macrocycles for singlet oxygen production
patent, March 1994

The synthesis of a new 22 π-electron macrocycle: pentaphyrin
journal, January 1983

Texaphyrin compounds having improved functionalization
patent, February 1997

5,15,25-tris-nor-Hexapyrrin: the first structurally characterized linear hexapyrrin
journal, January 1994

Rational tetraarylporphyrin syntheses: tetraarylporphyrins from the MacDonald route
journal, December 1993

New polyethyleneglycol-functionalized texaphyrins: synthesis and in vitro biological studies
journal, January 2006

Actinide Carbonte Complexes and Their Importance in Actinide Environmental Chemistry
journal, January 1995

Halogenated calixpyrroles and uses thereof
patent, May 2006

Calixpyrroles
patent, October 2006

A New and Convenient Method of Generating Alkyl Isocyanates from Alcohols, Thiols and Trimethylsilyl Ethers Using Triphenylphosphine/2,3-Dichloro-5,6-dicyanobenzoquinone/Bu ₄ NOCN
journal, January 2005

Sensor arrays for the measurement and identification of multiple analytes in solutions
patent, January 2004

Synthesis and Biolocalization of Water-Soluble Sapphyrins
journal, January 2002

Redox Behavior of Cyclo[6]pyrrole in the Formation of a Uranyl Complex
journal, June 2007