skip to main content
DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Soluble porphyrin polymers

Abstract

Porphyrin polymers of Structure 1, where n is an integer (e.g., 1, 2, 3, 4, 5, or greater) ##STR00001## are synthesized by the method shown in FIGS. 2A and 2B. The porphyrin polymers of Structure 1 are soluble in organic solvents such as 2-MeTHF and the like, and can be synthesized in bulk (i.e., in processes other than electropolymerization). These porphyrin polymers have long excited state lifetimes, making the material suitable as an organic semiconductor for organic electronic devices including transistors and memories, as well as solar cells, sensors, light-emitting devices, and other opto-electronic devices.

Inventors:
;
Issue Date:
Research Org.:
Arizona Board of Regents, A Body Corporate of the State of Arizona Acting for and on Behalf of Arizona State University, Scottsdale, AZ (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1190903
Patent Number(s):
9076972
Application Number:
13/907,452
Assignee:
Arizona Board of Regents, A Body Corporate of the State of Arizona Acting for and on Behalf of Arizona State University (Scottsdale, AZ)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01L - SEMICONDUCTOR DEVICES
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
DOE Contract Number:  
FG02-03ER15393
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 May 31
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 14 SOLAR ENERGY

Citation Formats

Gust, Jr., John Devens, and Liddell, Paul Anthony. Soluble porphyrin polymers. United States: N. p., 2015. Web.
Gust, Jr., John Devens, & Liddell, Paul Anthony. Soluble porphyrin polymers. United States.
Gust, Jr., John Devens, and Liddell, Paul Anthony. Tue . "Soluble porphyrin polymers". United States. https://www.osti.gov/servlets/purl/1190903.
@article{osti_1190903,
title = {Soluble porphyrin polymers},
author = {Gust, Jr., John Devens and Liddell, Paul Anthony},
abstractNote = {Porphyrin polymers of Structure 1, where n is an integer (e.g., 1, 2, 3, 4, 5, or greater) ##STR00001## are synthesized by the method shown in FIGS. 2A and 2B. The porphyrin polymers of Structure 1 are soluble in organic solvents such as 2-MeTHF and the like, and can be synthesized in bulk (i.e., in processes other than electropolymerization). These porphyrin polymers have long excited state lifetimes, making the material suitable as an organic semiconductor for organic electronic devices including transistors and memories, as well as solar cells, sensors, light-emitting devices, and other opto-electronic devices.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {7}
}

Patent:

Save / Share:

Works referenced in this record:

Photoelectrochemical characterisation of porphyrin-coated electrodes
journal, January 1991


Immobilization of metalloporphyrins in electropolymerized films: design and applications
journal, January 1995


Electrochemistry of various substituted aminophenyl iron porphyrins: Part I. Redox properties of dissolved, adsorbed and electropolymerized species
journal, July 1989


Electrocatalysis of dioxygen reduction in aqueous acid and base by multimolecular layer films of electropolymerized cobalt tetra(o-aminophenyl)porphyrin
journal, February 1987


Electrochemical polymerization of amino-, pyrrole-, and hydroxy-substituted tetraphenylporphyrins
journal, April 1987


Fullerene−Porphyrin Constructs
journal, April 2005


Synthesis of covalently-linked linear donor-acceptor copolymers containing porphyrins and oligothiophenes
journal, August 2004


An efficient synthesis of highly functionalized asymmetric porphyrins with organolithium reagents
journal, January 2001


Synthesis and electrochemistry of conductive copolymeric porphyrins
journal, July 1992


Comparative study of electropolymerized cobalt porphyrin and phthalocyanine based films for the electrochemical activation of thiols
journal, January 2002


A Scalable Synthesis of Meso-Substituted Dipyrromethanes
journal, November 2003


Very stable, highly electroactive polymers of zinc(II)-5,15-bisthienylphenyl porphyrin exhibiting charge-trapping effects
journal, June 2005


Porphyrin-Based Hole Conducting Electropolymer
journal, January 2008


Synthesis, electrochemistry, absorption and electro-polymerization of aniline-ethynyl metalloporphyrins
journal, January 2005


Porphyrin electrode films prepared by electrooxidation of metalloprotoporphyrins
journal, August 1983


Oxidative electrochemistry of electropolymerized metalloprotoporphyrin films
journal, March 1984


Electrochemical and resonance Raman spectroscopic characterization of polyaniline and polyaniline-metalloporphyrin electrode films
journal, August 1987


Conductive polymeric Cu(II) tetrakis(3-methoxy-4-hydroxyphenyl) porphyrin as a photosensitizer in a photoelectrochemical Cell
journal, May 1992


Photovoltaic effects in porphyrin polymer films and heterojunctions
journal, September 1996


Electrochromic materials
journal, January 1997


Anodic oxidation and physicochemical properties of various porphyrin-fluorenes or -spirobifluorenes: Synthesis of new polymers for heterogeneous catalytic reactions
journal, September 2005


Polarized Infrared Spectra of Photooriented Matrix-Isolated Free-Base Porphyrin Isotopomers
journal, September 1995


Hole transport in porphyrin thin films
journal, August 2001


Energy and Electron Transfer in Polyacetylene-Linked Zinc-Porphyrin-[60]Fullerene Molecular Wires
journal, May 2005


Electroactive porphyrin films from electropolymerized metallotetra(o-aminophenyl)porphyrins
journal, July 1985


Porphyrins, phthalocyanines and related systems in polymer phases
journal, June 2000


Excited-State Energy-Transfer Dynamics in Self-Assembled Triads Composed of Two Porphyrins and an Intervening Bis(dipyrrinato)metal Complex
journal, October 2003