High resolution characterization of soil dissolved organic matter with FTICR-MS (Fourier-transform ion cyclotron resonance mass spectrometry) from soil samples in control and warming plots in Blodgett Forest, CA (2014 and 2018)

Karaoz, Ulas; J. Eloy Alves, Ricardo; Chu, Rosalie; K. Eder, Elizabeth; Nicora, Carrie; Torn, Margaret; L. Brodie, Eoin

doi:10.15485/2569200

Title: High resolution characterization of soil dissolved organic matter with FTICR-MS (Fourier-transform ion cyclotron resonance mass spectrometry) from soil samples in control and warming plots in Blodgett Forest, CA (2014 and 2018)

Dataset
Other Related Research

Abstract

The pathways of carbon transport and loss through and from soils—soil organic matter (SOM) depolymerization to dissolved organic carbon and mineralization to carbon dioxide (CO2)—are fundamentally driven by microbial activity, which is strongly regulated by environmental conditions. As part of Lawrence Berkeley National Laboratory (LBNL) Terrestrial Ecosystem Science (TES) Belowground Biogeochemistry Science Focus Area (SFA), we have established a novel whole-soil long-term warming experiment at the University of California (UC) Blodgett Forest Research Station (Sierra Nevada) in 2014, where we study the role of biogeochemical, microbial and geochemical process interactions in SOM decomposition and stabilization.This package contains Fourier transform ion cyclotron resonance mass spectrometry (21 Tesla FTICR-MS) data measured in negative and positive ionization mode from water and methanol soil extracts. Soil samples were collected in 2014/06/03 and 2018/06/04 from 3 replicated paired plots that had been subjected to experimental warming since June 2014 to simulate a predicted climate change scenario for northern California. The following files are included: (1) fticr_neg_h2oMeoh_data_raw.csv: raw data from combined water (H2O) and methanol (MeOH) extracts in negative ion mode, (2) fticr_neg_h2oMeoh_data_processed.csv: processed data from combined water (H2O) and methanol (MeOH) extracts in negative ion mode, (3) fticr_neg_metadata.csv: metadata for samples/measurements in negative ion mode,more »« less

Authors:

;

Lawrence Berkeley National Laboratory
Pacific Northwest National Laboratory (PNNL)

Publication Date:: Wed Jan 01 04:00:00 UTC 2025

DOE Contract Number:: AC02-05CH11231

Research Org.:: Belowground Biogeochemistry Scientific Focus Area

Sponsoring Org.:: U.S. DOE > Office of Science > Biological and Environmental Research (BER)

Subject:: 54 ENVIRONMENTAL SCIENCES; Belowground Biogeochemistry Science Focus Area; Blodgett Forest Research Station; EARTH SCIENCE > LAND SURFACE > SOILS; FTICR-MS; Fourier transform ion cyclotron resonance mass spectrometry; METABOLOMICS; Terrestrial Ecosystem Science (TES); dissolved organic matter; metabolomics; methanol; soil metabolomics; soil organic matter; soil warming

OSTI Identifier:: 2569200

DOI:: https://doi.org/10.15485/2569200

Citation Formats


                    Karaoz, Ulas, J. Eloy Alves, Ricardo, Chu, Rosalie, K. Eder, Elizabeth, Nicora, Carrie, Torn, Margaret, and L. Brodie, Eoin. High resolution characterization of soil dissolved organic matter with FTICR-MS (Fourier-transform ion cyclotron resonance mass spectrometry) from soil samples in control and warming plots in Blodgett Forest, CA (2014 and 2018).  United States: N. p., 2025. 
        Web.  doi:10.15485/2569200.

Copy to clipboard


                    Karaoz, Ulas, J. Eloy Alves, Ricardo, Chu, Rosalie, K. Eder, Elizabeth, Nicora, Carrie, Torn, Margaret, & L. Brodie, Eoin. High resolution characterization of soil dissolved organic matter with FTICR-MS (Fourier-transform ion cyclotron resonance mass spectrometry) from soil samples in control and warming plots in Blodgett Forest, CA (2014 and 2018).  United States.  doi:https://doi.org/10.15485/2569200

Copy to clipboard


                    Karaoz, Ulas, J. Eloy Alves, Ricardo, Chu, Rosalie, K. Eder, Elizabeth, Nicora, Carrie, Torn, Margaret, and L. Brodie, Eoin. 2025.  
"High resolution characterization of soil dissolved organic matter with FTICR-MS (Fourier-transform ion cyclotron resonance mass spectrometry) from soil samples in control and warming plots in Blodgett Forest, CA (2014 and 2018)".  United States.  doi:https://doi.org/10.15485/2569200.  https://www.osti.gov/servlets/purl/2569200. Pub date:Wed Jan 01 04:00:00 UTC 2025

Copy to clipboard


                    
@article{osti_2569200,

  title        = {High resolution characterization of soil dissolved organic matter with FTICR-MS (Fourier-transform ion cyclotron resonance mass spectrometry) from soil samples in control and warming plots in Blodgett Forest, CA (2014 and 2018)},

  author       = {Karaoz, Ulas and J. Eloy Alves, Ricardo and Chu, Rosalie and K. Eder, Elizabeth and Nicora, Carrie and Torn, Margaret and L. Brodie, Eoin},

  abstractNote = {The pathways of carbon transport and loss through and from soils—soil organic matter (SOM) depolymerization to dissolved organic carbon and mineralization to carbon dioxide (CO2)—are fundamentally driven by microbial activity, which is strongly regulated by environmental conditions. As part of Lawrence Berkeley National Laboratory (LBNL) Terrestrial Ecosystem Science (TES) Belowground Biogeochemistry Science Focus Area (SFA), we have established a novel whole-soil long-term warming experiment at the University of California (UC) Blodgett Forest Research Station (Sierra Nevada) in 2014, where we study the role of biogeochemical, microbial and geochemical process interactions in SOM decomposition and stabilization.This package contains Fourier transform ion cyclotron resonance mass spectrometry (21 Tesla FTICR-MS) data measured in negative and positive ionization mode from water and methanol soil extracts. Soil samples were collected in 2014/06/03 and 2018/06/04 from 3 replicated paired plots that had been subjected to experimental warming since June 2014 to simulate a predicted climate change scenario for northern California. The following files are included: (1) fticr_neg_h2oMeoh_data_raw.csv: raw data from combined water (H2O) and methanol (MeOH) extracts in negative ion mode, (2) fticr_neg_h2oMeoh_data_processed.csv: processed data from combined water (H2O) and methanol (MeOH) extracts in negative ion mode, (3) fticr_neg_metadata.csv: metadata for samples/measurements in negative ion mode, (4) fticr_pos_h2oMeoh_data_raw.csv: raw data from combined water (H2O) and methanol (MeOH) extracts in positive ion mode, (5) fticr_pos_h2oMeoh_data_processed.csv: processed data from combined water (H2O) and methanol (MeOH) extracts in positive ion mode, (6) fticr_pos_metadata.csv: metadata for samples/measurements in positive ion mode.},

  doi          = {10.15485/2569200},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Wed Jan 01 04:00:00 UTC 2025},

  month        = {Wed Jan 01 04:00:00 UTC 2025}

}

Copy to clipboard

Dataset:

View Dataset

DOI: https://doi.org/10.15485/2569200

Save / Share:

Export Metadata

Save to My Library

Similar records in DOE Data Explorer and OSTI.GOV collections:

Soil Organic Matter Characterization by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR MS): A Critical Review of Sample Preparation, Analysis, and Data Interpretation

Journal Article Bahureksa, William ; Tfaily, Malak M. ; Boiteau, Rene M. ; ... - Environmental Science and Technology

Not provided.
Metagenome-assembled genomes from soil samples in control and warming plots in Blodgett Forest, CA (2014-2021)

Dataset Karaoz, Ulas ; L. Brodie, Eoin ; Torn, Margaret ; ...

The pathways of carbon transport and loss through and from soils—soil organic matter (SOM) depolymerization to dissolved organic carbon and mineralization to carbon dioxide (CO2)—are fundamentally driven by microbial activity, which is strongly regulated by environmental conditions. As part of LBNL (Lawrence Berkeley National Laboratory) TES (Terrestrial Ecosystem Science) Belowground Biogeochemistry Science Focus Area (SFA), we have established a novel whole-soil long-term warming experiment at the University of California (UC) Blodgett Forest Research Station (Sierra Nevada) in 2014, where we study the role of biogeochemical, microbial and geochemical process interactions in SOM decomposition and stabilization.Here, we present metagenome-assembled genomes (MAGs)more »« less
Hydrocarbon characterization by ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry

Journal Article Hsu, C S ; Liang, Z ; Campana, J E - Analytical Chemistry (Washington); (United States)

The ultrahigh-resolution capabilities of Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) have been demonstrated for accurate mass measurements of complex hydrocarbon mixtures. Ultrahigh resolution is achievable over a wide mass range by the use of stored waveform inverse Fourier transform (SWIFT) ejection to eliminate space-charge effects. The mass measurement stability under different ionization conditions eliminates the need of mass reference standards during acquisition of sample spectra, thereby increasing sensitivity of the accurate mass measurements under low-voltage electron ionization conditions. 27 refs., 4 figs., 2 tabs.
High Mass Resolving Power Radio Frequency Glow Discharge Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (RFGD-FTICR/MS)

Journal Article Nichols, L S - Journal of American Society for Mass Spectro

The combination of a radio frequency glow discharge (rfGD) external ion source with a Fourier transform ion cyclotron resonance (FTICR) mass spectrometer has resulted in the ability to perform high mass resolution elemental analysis of both conductive and nonconductive materials. Samples investigated in the present study include copper, brass, and a National Institute of Standards and Technology (NIST) glass standard, SRM 1412. Analyses of both the copper and the brass materials resulted in ultra-high mass resolving power (m/Dm > 100,000). A mass resolving power of 280,000 (FWHM) was obtained for the 63Cu+ isotope of the copper sample, the highest reportedmore »« less
Isotope ratio analysis utilizing glow discharge fourier transform ion cyclotron resonance mass spectrometry (GD-FTICR-MS)

Conference Goodner, K L ; Eyler, J R ; Watson, C H

The ability to measure isotope ratios accurately and with good precision is important in such diverse areas as geology and medicine, yet is often difficult to achieve. There has been relatively little work utilizing glow discharge ionization for the determination of isotopic ratios. The authors have analyzed the usefulness of coupling a glow discharge with FTICR-MS for ultra-high resolution isotope ratio analysis.

Similar Records