Replication Data for: Tuning reactivity layer-by-layer: formic acid activation on Ag/Pd(111)

Karatok, Mustafa; Duanmu, Kaining; O'Connor, Christopher; Boscoboinik, Jorge Anibal; Sautet, Philippe; Madix, Robert J.; Friend, Cynthia M.

doi:10.7910/DVN/59TZZ0

Title: Replication Data for: Tuning reactivity layer-by-layer: formic acid activation on Ag/Pd(111)

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Abstract

The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.

Authors:

Karatok, Mustafa; Duanmu, Kaining; O'Connor, Christopher; Boscoboinik, Jorge Anibal; Sautet, Philippe; Madix, Robert J.; Friend, Cynthia M.

Harvard Univ., Cambridge, MA (United States); OSTI
Univ. of California, Los Angeles, CA (United States)
Harvard Univ., Cambridge, MA (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Publication Date:: Thu Sep 24 00:00:00 EDT 2020

DOE Contract Number:: SC0012573

Research Org.:: Harvard Univ., Cambridge, MA (United States). Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC) (EFRC)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

OSTI Identifier:: 1873078

DOI:: https://doi.org/10.7910/DVN/59TZZ0

Citation Formats


                    Karatok, Mustafa, Duanmu, Kaining, O'Connor, Christopher, Boscoboinik, Jorge Anibal, Sautet, Philippe, Madix, Robert J., and Friend, Cynthia M. Replication Data for: Tuning reactivity layer-by-layer: formic acid activation on Ag/Pd(111).  United States: N. p., 2020. 
        Web.  doi:10.7910/DVN/59TZZ0.

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                    Karatok, Mustafa, Duanmu, Kaining, O'Connor, Christopher, Boscoboinik, Jorge Anibal, Sautet, Philippe, Madix, Robert J., & Friend, Cynthia M. Replication Data for: Tuning reactivity layer-by-layer: formic acid activation on Ag/Pd(111).  United States.  doi:https://doi.org/10.7910/DVN/59TZZ0

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                    Karatok, Mustafa, Duanmu, Kaining, O'Connor, Christopher, Boscoboinik, Jorge Anibal, Sautet, Philippe, Madix, Robert J., and Friend, Cynthia M. 2020.  
"Replication Data for: Tuning reactivity layer-by-layer: formic acid activation on Ag/Pd(111)".  United States.  doi:https://doi.org/10.7910/DVN/59TZZ0.  https://www.osti.gov/servlets/purl/1873078. Pub date:Thu Sep 24 00:00:00 EDT 2020

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@article{osti_1873078,

  title        = {Replication Data for: Tuning reactivity layer-by-layer: formic acid activation on Ag/Pd(111)},

  author       = {Karatok, Mustafa and Duanmu, Kaining and O'Connor, Christopher and Boscoboinik, Jorge Anibal and Sautet, Philippe and Madix, Robert J. and Friend, Cynthia M.},

  abstractNote = {The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.},

  doi          = {10.7910/DVN/59TZZ0},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Thu Sep 24 00:00:00 EDT 2020},

  month        = {Thu Sep 24 00:00:00 EDT 2020}

}

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DOI: https://doi.org/10.7910/DVN/59TZZ0

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Tuning reactivity layer-by-layer: formic acid activation on Ag/Pd(111)

Journal Article Karatok, Mustafa ; Duanmu, Kaining ; O'Connor, Christopher R. ; ... - Chemical Science

The potential for tuning the electronic structure of materials to control reactivity and selectivity in heterogenous catalysis has driven interest in ultrathin metal films which may differ from their bulk form. Herein, a 1-atomic layer Ag film on Pd(111) (Ag/Pd(111)) is demonstrated to have dramatically different reactivity towards formic acid compared to bulk Ag. Formic acid decomposition is of interest as a source of H₂ for fuel cell applications and modification of Pd by Ag reduces poisoning by CO and increases the selectivity for H₂ formation. Formic acid reacts below room temperature on the 1-atomic layer Ag film, whereas nomore »« less
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The potential for tuning the electronic structure of materials to control reactivity and selectivity in heterogenous catalysis has driven interest in ultrathin metal films which may differ from their bulk form. Herein, a 1-atomic layer Ag film on Pd(111) (Ag/Pd(111)) is demonstrated to have dramatically different reactivity towards formic acid compared to bulk Ag. Formic acid decomposition is of interest as a source of H₂ for fuel cell applications and modification of Pd by Ag reduces poisoning by CO and increases the selectivity for H₂ formation. Formic acid reacts below room temperature on the 1-atomic layer Ag film, whereas nomore »« less
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The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.
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The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.

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