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Tuning reactivity layer-by-layer: formic acid activation on Ag/Pd(111)

Journal Article · · Chemical Science
DOI:https://doi.org/10.1039/D0SC01461C· OSTI ID:1616354
 [1];  [2];  [1];  [3];  [4];  [5];  [6]
  1. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, USA
  2. Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, USA
  3. Center for Functional Nanomaterials, Brookhaven National Laboratory, USA
  4. Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, USA, Department of Chemistry and Biochemistry
  5. John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, USA
  6. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, USA, John A. Paulson School of Engineering and Applied Sciences

Modified electronic structure of Ag monolayer on Pd(111) enhances reactivity of Ag towards formic acid.

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0012573
OSTI ID:
1616354
Alternate ID(s):
OSTI ID: 1843585
OSTI ID: 1677678
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 25 Vol. 11; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (42)

Quantization of electronic states on metal surfaces journal November 1994
The oxidation of methanol on a silver (110) catalyst journal September 1978
The chemisorption of carbon monoxide on palladium single crystal surfaces: IR spectroscopic evidence for localised site adsorption journal April 1978
Acid-base reactions on solid surfaces: The reactions of HCOOH, H2CO, and HCOOCH3 with oxygen on Ag(110) journal April 1980
A vibrational study of formic acid interaction with clean and oxygen-covered silver (110) surfaces journal April 1981
An iras study of formic acid and surface formate adsorbed on Cu(110) journal October 1983
Monolayer and multilayer growth of Cu on the Ru(0001) surface journal March 1986
Reactions of formic acid and formaldehyde on Rh(111) and Rh(111)-(2 × 2)O surfaces journal May 1991
Physisorption of CO on Ag(111): investigation of the monolayer and the multilayer through HREELS, ARUPS, and TDS journal August 1991
Reactions of carboxylic acids on the Pd(111)-(2 × 2)O surface: multiple roles of surface oxygen atoms journal October 1991
Thermal desorption of gases journal July 1962
The adsorption of H2 and CO on strained Ni overlayers on W(110) and W(100) journal September 1987
Analysis of CO-Cu bonding by observation of interface states on Cu/Ru bimetallic surfaces journal December 1987
High temperature partial oxidation reactions over silver catalysts journal November 1999
A density functional theory study of CO oxidation on Pd-Ni alloy with sandwich structure journal January 2013
Recent advances in direct formic acid fuel cells (DFAFC) journal July 2008
Monolayer bimetallic surfaces: Experimental and theoretical studies of trends in electronic and chemical properties journal May 2008
Growth of thin platinum films on Cu(100): CAICISS, XPS and LEED studies journal June 2005
Dynamics of Surface Alloys: Rearrangement of Pd/Ag(111) Induced by CO and O 2 journal October 2018
Enhancement of Formic Acid Dehydrogenation Selectivity of Pd(111) Single Crystal Model Catalyst Surface via Brønsted Bases journal November 2019
Chemisorption of ethylene and acetylene on ultrathin palladium films on molybdenum(100) journal May 1993
Dissociative adsorption and hydrogenolysis of ethane over clean and nickel-covered platinum (111) journal June 1990
The temperature and coverage dependences of adsorbed formic acid and its conversion to formate on platinum(111) journal February 1992
Importance of Ligand Effect in Selective Hydrogen Formation via Formic Acid Decomposition on the Bimetallic Pd/Ag Catalyst from First-Principles journal September 2014
Multiple Bonding Configurations of Adsorbed Formate on Ag{111} journal January 1996
Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst journal April 2011
The interaction of CO with PdAg/Pd(111) surface alloys—A case study of ensemble effects on a bimetallic surface journal January 2011
Formation, atomic distribution and mixing energy in two-dimensional PdxAg1−x surface alloys on Pd(111) journal January 2012
Designing bimetallic catalysts for a green and sustainable future journal January 2012
Modification of the surface electronic and chemical properties of Pt(111) by subsurface 3d transition metals journal June 2004
Ab initiomolecular dynamics for liquid metals journal January 1993
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium journal May 1994
Surface core-level shifts of some 4 d -metal single-crystal surfaces: Experiments and ab initio calculations journal December 1994
From ultrasoft pseudopotentials to the projector augmented-wave method journal January 1999
Experimental and ab initio study of the structural and electronic properties of subnanometer thick Ag films on Pd(111) journal December 2005
Mechanism for reversed photoemission core-level shifts of oxidized Ag journal March 2012
CO Chemisorption at Metal Surfaces and Overlayers journal March 1996
Generalized Gradient Approximation Made Simple journal October 1996
Structure of Ag ( 111 ) − p ( 4 × 4 ) − O : No Silver Oxide journal April 2006
Surface chemistry of monolayer metallic films on Re(0001) and Mo(110)
  • He, J. ‐W.; Shea, W. ‐L.; Jiang, X.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 8, Issue 3 https://doi.org/10.1116/1.576711
journal May 1990
Molecular Transformations on Single Crystal Metal Surfaces journal September 1986
The Nature of the Metal-Metal Bond in Bimetallic Surfaces journal August 1992

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