Materials Data on Ag(NO)3 by Materials Project

doi:10.17188/1718196

Title: Materials Data on Ag(NO)3 by Materials Project

Dataset
Other Related Research

Abstract

NAgNAg(N2O3)2 crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two Ag(N2O3)2 clusters and two NAgN clusters. In each Ag(N2O3)2 cluster, Ag1+ is bonded in a 4-coordinate geometry to two equivalent N+1.67+ and two equivalent O2- atoms. Both Ag–N bond lengths are 2.11 Å. Both Ag–O bond lengths are 2.78 Å. There are two inequivalent N+1.67+ sites. In the first N+1.67+ site, N+1.67+ is bonded in a single-bond geometry to one Ag1+ atom. In the second N+1.67+ site, N+1.67+ is bonded in a trigonal planar geometry to three O2- atoms. There is two shorter (1.25 Å) and one longer (1.27 Å) N–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and one N+1.67+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one N+1.67+ atom. In each NAgN cluster, Ag1+ is bonded in a linear geometry to two equivalent N+1.67+ atoms. Both Ag–N bond lengths are 2.09 Å. N+1.67+ is bonded in a single-bond geometry to one Ag1+ atom.

Publication Date:: Sun May 03 04:00:00 UTC 2020

Other Number(s):: mp-1192809

DOE Contract Number:: AC02-05CH11231

Research Org.:: LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Collaborations:: The Materials Project; MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE; Ag(NO)3; Ag-N-O; crystal structure

OSTI Identifier:: 1718196

DOI:: https://doi.org/10.17188/1718196

Citation Formats


                    Materials Data on Ag(NO)3 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1718196.

Copy to clipboard


                    Materials Data on Ag(NO)3 by Materials Project.  United States.  doi:https://doi.org/10.17188/1718196

Copy to clipboard


                    2020.  
"Materials Data on Ag(NO)3 by Materials Project".  United States.  doi:https://doi.org/10.17188/1718196.  https://www.osti.gov/servlets/purl/1718196. Pub date:Sun May 03 04:00:00 UTC 2020

Copy to clipboard


                    
@article{osti_1718196,

  title        = {Materials Data on Ag(NO)3 by Materials Project},

  
  abstractNote = {NAgNAg(N2O3)2 crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two Ag(N2O3)2 clusters and two NAgN clusters. In each Ag(N2O3)2 cluster, Ag1+ is bonded in a 4-coordinate geometry to two equivalent N+1.67+ and two equivalent O2- atoms. Both Ag–N bond lengths are 2.11 Å. Both Ag–O bond lengths are 2.78 Å. There are two inequivalent N+1.67+ sites. In the first N+1.67+ site, N+1.67+ is bonded in a single-bond geometry to one Ag1+ atom. In the second N+1.67+ site, N+1.67+ is bonded in a trigonal planar geometry to three O2- atoms. There is two shorter (1.25 Å) and one longer (1.27 Å) N–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and one N+1.67+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one N+1.67+ atom. In each NAgN cluster, Ag1+ is bonded in a linear geometry to two equivalent N+1.67+ atoms. Both Ag–N bond lengths are 2.09 Å. N+1.67+ is bonded in a single-bond geometry to one Ag1+ atom.},

  doi          = {10.17188/1718196},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Sun May 03 04:00:00 UTC 2020},

  month        = {Sun May 03 04:00:00 UTC 2020}

}

Copy to clipboard

Dataset:

View Dataset

DOI: https://doi.org/10.17188/1718196

Save / Share:

Export Metadata

Save to My Library

Similar records in DOE Data Explorer and OSTI.GOV collections:

Materials Data on Ag(Bi2S3)3 by Materials Project

Dataset

Ag(Bi2S3)3 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Ag1+ is bonded to six S2- atoms to form AgS6 octahedra that share corners with two equivalent BiS6 octahedra, corners with four equivalent BiS5 square pyramids, edges with two equivalent AgS6 octahedra, and edges with six equivalent BiS5 square pyramids. The corner-sharing octahedral tilt angles are 55°. There are two shorter (2.51 Å) and four longer (2.98 Å) Ag–S bond lengths. There are three inequivalent Bi+2.83+ sites. In the first Bi+2.83+ site, Bi+2.83+ is bonded to six S2- atoms to form a mixture of edge and corner-sharing BiS6more »« less
Materials Data on Ag(AsSe2)3 by Materials Project

Dataset

Ag(AsSe2)2As(Se)2 crystallizes in the orthorhombic Cmmm space group. The structure is two-dimensional and consists of two arsenic molecules; four selenium molecules; and one Ag(AsSe2)2 sheet oriented in the (0, 0, 1) direction. In the Ag(AsSe2)2 sheet, Ag1+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent Se2- atoms. All Ag–Se bond lengths are 2.68 Å. As+3.67+ is bonded in a linear geometry to two equivalent Se2- atoms. Both As–Se bond lengths are 2.39 Å. Se2- is bonded in a distorted linear geometry to one Ag1+, one As+3.67+, and one Se2- atom. The Se–Se bond length is 2.60 Å.
Materials Data on Ag(BiTe2)3 by Materials Project

Dataset

Ag(BiTe2)2Bi(Te)2 crystallizes in the orthorhombic Cmmm space group. The structure is two-dimensional and consists of two bismuth molecules; four tellurium molecules; and one Ag(BiTe2)2 sheet oriented in the (0, 0, 1) direction. In the Ag(BiTe2)2 sheet, Ag1+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent Te2- atoms. All Ag–Te bond lengths are 2.82 Å. Bi+3.67+ is bonded in a linear geometry to two equivalent Te2- atoms. Both Bi–Te bond lengths are 2.88 Å. Te2- is bonded in a 3-coordinate geometry to one Ag1+, one Bi+3.67+, and one Te2- atom. The Te–Te bond length is 2.92 Å.
Materials Data on Ag(MoSe)3 by Materials Project

Dataset

Ag(MoSe)3 crystallizes in the hexagonal P6_3/m space group. The structure is three-dimensional. Mo is bonded in a distorted see-saw-like geometry to four equivalent Se atoms. There are a spread of Mo–Se bond distances ranging from 2.61–2.71 Å. Ag is bonded in a 12-coordinate geometry to six equivalent Se atoms. All Ag–Se bond lengths are 3.12 Å. Se is bonded in a 6-coordinate geometry to four equivalent Mo and two equivalent Ag atoms.
Materials Data on Ag(NO2)3 by Materials Project

Dataset

(Ag(NO3)2)2N2 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of four ammonia molecules and two Ag(NO3)2 sheets oriented in the (0, 0, 1) direction. In each Ag(NO3)2 sheet, Ag1+ is bonded in a 4-coordinate geometry to six O2- atoms. There are a spread of Ag–O bond distances ranging from 2.19–2.91 Å. There are two inequivalent N+3.67+ sites. In the first N+3.67+ site, N+3.67+ is bonded in a trigonal planar geometry to three O2- atoms. There is one shorter (1.22 Å) and two longer (1.29 Å) N–O bond length. In the second N+3.67+ site, N+3.67+ ismore »« less

Similar Records