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Title: Materials Data on Ag(NO2)3 by Materials Project

Abstract

(Ag(NO3)2)2N2 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of four ammonia molecules and two Ag(NO3)2 sheets oriented in the (0, 0, 1) direction. In each Ag(NO3)2 sheet, Ag1+ is bonded in a 4-coordinate geometry to six O2- atoms. There are a spread of Ag–O bond distances ranging from 2.19–2.91 Å. There are two inequivalent N+3.67+ sites. In the first N+3.67+ site, N+3.67+ is bonded in a trigonal planar geometry to three O2- atoms. There is one shorter (1.22 Å) and two longer (1.29 Å) N–O bond length. In the second N+3.67+ site, N+3.67+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.23–1.29 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a 2-coordinate geometry to one Ag1+ and one N+3.67+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and one N+3.67+ atom. In the third O2- site, O2- is bonded in a 1-coordinate geometry to two equivalent Ag1+ and one N+3.67+ atom. In the fourth O2- site, O2- is bonded in a distorted L-shaped geometrymore » to one Ag1+ and one N+3.67+ atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to one N+3.67+ atom. In the sixth O2- site, O2- is bonded in a bent 120 degrees geometry to one Ag1+ and one N+3.67+ atom.« less

Publication Date:
Other Number(s):
mp-1182987
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ag(NO2)3; Ag-N-O
OSTI Identifier:
1743842
DOI:
https://doi.org/10.17188/1743842

Citation Formats

The Materials Project. Materials Data on Ag(NO2)3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1743842.
The Materials Project. Materials Data on Ag(NO2)3 by Materials Project. United States. doi:https://doi.org/10.17188/1743842
The Materials Project. 2020. "Materials Data on Ag(NO2)3 by Materials Project". United States. doi:https://doi.org/10.17188/1743842. https://www.osti.gov/servlets/purl/1743842. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1743842,
title = {Materials Data on Ag(NO2)3 by Materials Project},
author = {The Materials Project},
abstractNote = {(Ag(NO3)2)2N2 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of four ammonia molecules and two Ag(NO3)2 sheets oriented in the (0, 0, 1) direction. In each Ag(NO3)2 sheet, Ag1+ is bonded in a 4-coordinate geometry to six O2- atoms. There are a spread of Ag–O bond distances ranging from 2.19–2.91 Å. There are two inequivalent N+3.67+ sites. In the first N+3.67+ site, N+3.67+ is bonded in a trigonal planar geometry to three O2- atoms. There is one shorter (1.22 Å) and two longer (1.29 Å) N–O bond length. In the second N+3.67+ site, N+3.67+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.23–1.29 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a 2-coordinate geometry to one Ag1+ and one N+3.67+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and one N+3.67+ atom. In the third O2- site, O2- is bonded in a 1-coordinate geometry to two equivalent Ag1+ and one N+3.67+ atom. In the fourth O2- site, O2- is bonded in a distorted L-shaped geometry to one Ag1+ and one N+3.67+ atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to one N+3.67+ atom. In the sixth O2- site, O2- is bonded in a bent 120 degrees geometry to one Ag1+ and one N+3.67+ atom.},
doi = {10.17188/1743842},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}