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Title: Materials Data on VF5 by Materials Project

Abstract

VF5 crystallizes in the triclinic P1 space group. The structure is one-dimensional and consists of one VF5 ribbon oriented in the (0, 0, 1) direction. V5+ is bonded to six F1- atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 28°. There are a spread of V–F bond distances ranging from 1.77–1.95 Å. There are ten inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent V5+ atoms. In the second F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent V5+ atoms. In the third F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. The F–V bond length is 1.78 Å. In the fourth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. The F–V bond length is 1.77 Å. In the seventh F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. In the eighth F1- site, F1-more » is bonded in a single-bond geometry to one V5+ atom. The F–V bond length is 1.77 Å. In the ninth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. In the tenth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. The F–V bond length is 1.77 Å.« less

Publication Date:
Other Number(s):
mvc-14312
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; VF5; F-V
OSTI Identifier:
1319102
DOI:
https://doi.org/10.17188/1319102

Citation Formats

The Materials Project. Materials Data on VF5 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1319102.
The Materials Project. Materials Data on VF5 by Materials Project. United States. doi:https://doi.org/10.17188/1319102
The Materials Project. 2020. "Materials Data on VF5 by Materials Project". United States. doi:https://doi.org/10.17188/1319102. https://www.osti.gov/servlets/purl/1319102. Pub date:Mon Jul 20 00:00:00 EDT 2020
@article{osti_1319102,
title = {Materials Data on VF5 by Materials Project},
author = {The Materials Project},
abstractNote = {VF5 crystallizes in the triclinic P1 space group. The structure is one-dimensional and consists of one VF5 ribbon oriented in the (0, 0, 1) direction. V5+ is bonded to six F1- atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 28°. There are a spread of V–F bond distances ranging from 1.77–1.95 Å. There are ten inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent V5+ atoms. In the second F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent V5+ atoms. In the third F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. The F–V bond length is 1.78 Å. In the fourth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. The F–V bond length is 1.77 Å. In the seventh F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. In the eighth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. The F–V bond length is 1.77 Å. In the ninth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. In the tenth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. The F–V bond length is 1.77 Å.},
doi = {10.17188/1319102},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}