U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on VF5 by Materials Project
Abstract
VF5 crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of two VF5 ribbons oriented in the (1, 0, 0) direction. V5+ is bonded to six F1- atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 26°. There are a spread of V–F bond distances ranging from 1.73–2.03 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. In the third F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent V5+ atoms. In the fourth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom.
- Publication Date:
- Other Number(s):
- mp-764959
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; F-V; VF5; crystal structure
- OSTI Identifier:
- 1295486
- DOI:
- https://doi.org/10.17188/1295486
Citation Formats
Materials Data on VF5 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1295486.
Materials Data on VF5 by Materials Project. United States. doi:https://doi.org/10.17188/1295486
2020.
"Materials Data on VF5 by Materials Project". United States. doi:https://doi.org/10.17188/1295486. https://www.osti.gov/servlets/purl/1295486. Pub date:Wed Jul 15 04:00:00 UTC 2020
@article{osti_1295486,
title = {Materials Data on VF5 by Materials Project},
abstractNote = {VF5 crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of two VF5 ribbons oriented in the (1, 0, 0) direction. V5+ is bonded to six F1- atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 26°. There are a spread of V–F bond distances ranging from 1.73–2.03 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one V5+ atom. In the third F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent V5+ atoms. In the fourth F1- site, F1- is bonded in a single-bond geometry to one V5+ atom.},
doi = {10.17188/1295486},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Jul 15 04:00:00 UTC 2020},
month = {Wed Jul 15 04:00:00 UTC 2020}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.