U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on SnH22C6(NCl2)2 by Materials Project
Abstract
((CH3)2NH2)2SnH6(CCl2)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dimethylazanium molecules and one SnH6(CCl2)2 cluster. In the SnH6(CCl2)2 cluster, Sn4+ is bonded in an octahedral geometry to two equivalent C+2.67- and four Cl1- atoms. Both Sn–C bond lengths are 2.15 Å. There are two shorter (2.66 Å) and two longer (2.68 Å) Sn–Cl bond lengths. C+2.67- is bonded in a distorted trigonal non-coplanar geometry to one Sn4+ and three H1+ atoms. All C–H bond lengths are 1.09 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Sn4+ atom. In the second Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Sn4+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-983519
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; SnH22C6(NCl2)2; C-Cl-H-N-Sn
- OSTI Identifier:
- 1316515
- DOI:
- https://doi.org/10.17188/1316515
Citation Formats
The Materials Project. Materials Data on SnH22C6(NCl2)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1316515.
The Materials Project. Materials Data on SnH22C6(NCl2)2 by Materials Project. United States. doi:https://doi.org/10.17188/1316515
The Materials Project. 2020.
"Materials Data on SnH22C6(NCl2)2 by Materials Project". United States. doi:https://doi.org/10.17188/1316515. https://www.osti.gov/servlets/purl/1316515. Pub date:Thu Jul 23 00:00:00 EDT 2020
@article{osti_1316515,
title = {Materials Data on SnH22C6(NCl2)2 by Materials Project},
author = {The Materials Project},
abstractNote = {((CH3)2NH2)2SnH6(CCl2)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dimethylazanium molecules and one SnH6(CCl2)2 cluster. In the SnH6(CCl2)2 cluster, Sn4+ is bonded in an octahedral geometry to two equivalent C+2.67- and four Cl1- atoms. Both Sn–C bond lengths are 2.15 Å. There are two shorter (2.66 Å) and two longer (2.68 Å) Sn–Cl bond lengths. C+2.67- is bonded in a distorted trigonal non-coplanar geometry to one Sn4+ and three H1+ atoms. All C–H bond lengths are 1.09 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Sn4+ atom. In the second Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Sn4+ atom.},
doi = {10.17188/1316515},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jul 23 00:00:00 EDT 2020},
month = {Thu Jul 23 00:00:00 EDT 2020}
}