U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on CoH16C4(NCl2)2 by Materials Project
Abstract
(C2H5NH3)2CoCl4 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight dimethylazanium molecules and four CoCl4 clusters. In each CoCl4 cluster, Co2+ is bonded in a tetrahedral geometry to four Cl1- atoms. There are a spread of Co–Cl bond distances ranging from 2.25–2.29 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Co2+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Co2+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Co2+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Co2+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-568314
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; CoH16C4(NCl2)2; C-Cl-Co-H-N
- OSTI Identifier:
- 1274354
- DOI:
- https://doi.org/10.17188/1274354
Citation Formats
The Materials Project. Materials Data on CoH16C4(NCl2)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1274354.
The Materials Project. Materials Data on CoH16C4(NCl2)2 by Materials Project. United States. doi:https://doi.org/10.17188/1274354
The Materials Project. 2020.
"Materials Data on CoH16C4(NCl2)2 by Materials Project". United States. doi:https://doi.org/10.17188/1274354. https://www.osti.gov/servlets/purl/1274354. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1274354,
title = {Materials Data on CoH16C4(NCl2)2 by Materials Project},
author = {The Materials Project},
abstractNote = {(C2H5NH3)2CoCl4 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight dimethylazanium molecules and four CoCl4 clusters. In each CoCl4 cluster, Co2+ is bonded in a tetrahedral geometry to four Cl1- atoms. There are a spread of Co–Cl bond distances ranging from 2.25–2.29 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Co2+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Co2+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Co2+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Co2+ atom.},
doi = {10.17188/1274354},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}