Materials Data on Ni(RhO2)2 by Materials Project

doi:10.17188/1279587

Title: Materials Data on Ni(RhO2)2 by Materials Project

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Abstract

Ni(RhO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Rh3+ is bonded to six equivalent O2- atoms to form RhO6 octahedra that share corners with six equivalent NiO4 tetrahedra and edges with six equivalent RhO6 octahedra. There are two shorter (2.07 Å) and four longer (2.08 Å) Rh–O bond lengths. Ni2+ is bonded to four equivalent O2- atoms to form NiO4 tetrahedra that share corners with twelve equivalent RhO6 octahedra. The corner-sharing octahedra tilt angles range from 52–61°. All Ni–O bond lengths are 2.01 Å. O2- is bonded in a rectangular see-saw-like geometry to three equivalent Rh3+ and one Ni2+ atom.

Authors:: The Materials Project

Publication Date:: Sun May 03 00:00:00 EDT 2020

Other Number(s):: mp-636519

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; Ni(RhO2)2; Ni-O-Rh

OSTI Identifier:: 1279587

DOI:: https://doi.org/10.17188/1279587

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                    The Materials Project. Materials Data on Ni(RhO2)2 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1279587.

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                    The Materials Project. Materials Data on Ni(RhO2)2 by Materials Project.  United States.  doi:https://doi.org/10.17188/1279587

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                    The Materials Project. 2020.  
"Materials Data on Ni(RhO2)2 by Materials Project".  United States.  doi:https://doi.org/10.17188/1279587.  https://www.osti.gov/servlets/purl/1279587. Pub date:Sun May 03 00:00:00 EDT 2020

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@article{osti_1279587,

  title        = {Materials Data on Ni(RhO2)2 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {Ni(RhO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Rh3+ is bonded to six equivalent O2- atoms to form RhO6 octahedra that share corners with six equivalent NiO4 tetrahedra and edges with six equivalent RhO6 octahedra. There are two shorter (2.07 Å) and four longer (2.08 Å) Rh–O bond lengths. Ni2+ is bonded to four equivalent O2- atoms to form NiO4 tetrahedra that share corners with twelve equivalent RhO6 octahedra. The corner-sharing octahedra tilt angles range from 52–61°. All Ni–O bond lengths are 2.01 Å. O2- is bonded in a rectangular see-saw-like geometry to three equivalent Rh3+ and one Ni2+ atom.},

  doi          = {10.17188/1279587},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Sun May 03 00:00:00 EDT 2020},

  month        = {Sun May 03 00:00:00 EDT 2020}

}

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DOI: https://doi.org/10.17188/1279587

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