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Title: Materials Data on Ni(RhO2)2 by Materials Project

Abstract

Ni(RhO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Rh3+ is bonded to six equivalent O2- atoms to form RhO6 octahedra that share corners with six equivalent NiO4 tetrahedra and edges with six equivalent RhO6 octahedra. All Rh–O bond lengths are 2.07 Å. Ni2+ is bonded to four equivalent O2- atoms to form NiO4 tetrahedra that share corners with twelve equivalent RhO6 octahedra. The corner-sharing octahedra tilt angles range from 57–61°. All Ni–O bond lengths are 2.02 Å. O2- is bonded in a rectangular see-saw-like geometry to three equivalent Rh3+ and one Ni2+ atom.

Publication Date:
Other Number(s):
mp-19307
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ni(RhO2)2; Ni-O-Rh
OSTI Identifier:
1194195
DOI:
https://doi.org/10.17188/1194195

Citation Formats

The Materials Project. Materials Data on Ni(RhO2)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1194195.
The Materials Project. Materials Data on Ni(RhO2)2 by Materials Project. United States. doi:https://doi.org/10.17188/1194195
The Materials Project. 2020. "Materials Data on Ni(RhO2)2 by Materials Project". United States. doi:https://doi.org/10.17188/1194195. https://www.osti.gov/servlets/purl/1194195. Pub date:Fri Apr 24 00:00:00 EDT 2020
@article{osti_1194195,
title = {Materials Data on Ni(RhO2)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Ni(RhO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Rh3+ is bonded to six equivalent O2- atoms to form RhO6 octahedra that share corners with six equivalent NiO4 tetrahedra and edges with six equivalent RhO6 octahedra. All Rh–O bond lengths are 2.07 Å. Ni2+ is bonded to four equivalent O2- atoms to form NiO4 tetrahedra that share corners with twelve equivalent RhO6 octahedra. The corner-sharing octahedra tilt angles range from 57–61°. All Ni–O bond lengths are 2.02 Å. O2- is bonded in a rectangular see-saw-like geometry to three equivalent Rh3+ and one Ni2+ atom.},
doi = {10.17188/1194195},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}