U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Pb2O3 by Materials Project
Abstract
Pb2O3 crystallizes in the monoclinic P2_1/m space group. The structure is two-dimensional and consists of one Pb2O3 sheet oriented in the (0, 0, 1) direction. there are two inequivalent Pb3+ sites. In the first Pb3+ site, Pb3+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedra tilt angles range from 11–14°. There are a spread of Pb–O bond distances ranging from 2.03–2.46 Å. In the second Pb3+ site, Pb3+ is bonded in a distorted pentagonal planar geometry to five O2- atoms. There are a spread of Pb–O bond distances ranging from 2.48–2.55 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to three Pb3+ atoms. In the second O2- site, O2- is bonded to five Pb3+ atoms to form a mixture of corner and edge-sharing OPb5 square pyramids. In the third O2- site, O2- is bonded in a 3-coordinate geometry to three Pb3+ atoms.
- Authors:
- Publication Date:
- Other Number(s):
- mp-608439
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Pb2O3; O-Pb
- OSTI Identifier:
- 1277631
- DOI:
- https://doi.org/10.17188/1277631
Citation Formats
The Materials Project. Materials Data on Pb2O3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1277631.
The Materials Project. Materials Data on Pb2O3 by Materials Project. United States. doi:https://doi.org/10.17188/1277631
The Materials Project. 2020.
"Materials Data on Pb2O3 by Materials Project". United States. doi:https://doi.org/10.17188/1277631. https://www.osti.gov/servlets/purl/1277631. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1277631,
title = {Materials Data on Pb2O3 by Materials Project},
author = {The Materials Project},
abstractNote = {Pb2O3 crystallizes in the monoclinic P2_1/m space group. The structure is two-dimensional and consists of one Pb2O3 sheet oriented in the (0, 0, 1) direction. there are two inequivalent Pb3+ sites. In the first Pb3+ site, Pb3+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedra tilt angles range from 11–14°. There are a spread of Pb–O bond distances ranging from 2.03–2.46 Å. In the second Pb3+ site, Pb3+ is bonded in a distorted pentagonal planar geometry to five O2- atoms. There are a spread of Pb–O bond distances ranging from 2.48–2.55 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to three Pb3+ atoms. In the second O2- site, O2- is bonded to five Pb3+ atoms to form a mixture of corner and edge-sharing OPb5 square pyramids. In the third O2- site, O2- is bonded in a 3-coordinate geometry to three Pb3+ atoms.},
doi = {10.17188/1277631},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jul 16 00:00:00 EDT 2020},
month = {Thu Jul 16 00:00:00 EDT 2020}
}