U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Pb2O3 by Materials Project
Abstract
Pb2O3 crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are eight inequivalent Pb3+ sites. In the first Pb3+ site, Pb3+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedra tilt angles range from 30–33°. There are a spread of Pb–O bond distances ranging from 2.18–2.30 Å. In the second Pb3+ site, Pb3+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedra tilt angles range from 30–33°. There are a spread of Pb–O bond distances ranging from 2.19–2.31 Å. In the third Pb3+ site, Pb3+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedra tilt angles range from 33–36°. There are a spread of Pb–O bond distances ranging from 2.20–2.30 Å. In the fourth Pb3+ site, Pb3+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedra tilt angles range from 33–36°. There are a spread of Pb–O bond distances ranging from 2.20–2.30 Å. In the fifth Pb3+ site, Pb3+ is bonded in a distorted hexagonal planar geometrymore »
- Authors:
- Publication Date:
- Other Number(s):
- mp-690722
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Pb2O3; O-Pb
- OSTI Identifier:
- 1284567
- DOI:
- https://doi.org/10.17188/1284567
Citation Formats
The Materials Project. Materials Data on Pb2O3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1284567.
The Materials Project. Materials Data on Pb2O3 by Materials Project. United States. doi:https://doi.org/10.17188/1284567
The Materials Project. 2020.
"Materials Data on Pb2O3 by Materials Project". United States. doi:https://doi.org/10.17188/1284567. https://www.osti.gov/servlets/purl/1284567. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1284567,
title = {Materials Data on Pb2O3 by Materials Project},
author = {The Materials Project},
abstractNote = {Pb2O3 crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are eight inequivalent Pb3+ sites. In the first Pb3+ site, Pb3+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedra tilt angles range from 30–33°. There are a spread of Pb–O bond distances ranging from 2.18–2.30 Å. In the second Pb3+ site, Pb3+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedra tilt angles range from 30–33°. There are a spread of Pb–O bond distances ranging from 2.19–2.31 Å. In the third Pb3+ site, Pb3+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedra tilt angles range from 33–36°. There are a spread of Pb–O bond distances ranging from 2.20–2.30 Å. In the fourth Pb3+ site, Pb3+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedra tilt angles range from 33–36°. There are a spread of Pb–O bond distances ranging from 2.20–2.30 Å. In the fifth Pb3+ site, Pb3+ is bonded in a distorted hexagonal planar geometry to six O2- atoms. There are a spread of Pb–O bond distances ranging from 2.52–2.88 Å. In the sixth Pb3+ site, Pb3+ is bonded in a distorted hexagonal planar geometry to six O2- atoms. There are a spread of Pb–O bond distances ranging from 2.48–2.77 Å. In the seventh Pb3+ site, Pb3+ is bonded in a distorted hexagonal planar geometry to six O2- atoms. There are a spread of Pb–O bond distances ranging from 2.53–2.95 Å. In the eighth Pb3+ site, Pb3+ is bonded in a distorted hexagonal planar geometry to six O2- atoms. There are a spread of Pb–O bond distances ranging from 2.50–2.84 Å. There are twelve inequivalent O2- sites. In the first O2- site, O2- is bonded in a 2-coordinate geometry to four Pb3+ atoms. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to four Pb3+ atoms. In the third O2- site, O2- is bonded in a 2-coordinate geometry to four Pb3+ atoms. In the fourth O2- site, O2- is bonded in a 2-coordinate geometry to four Pb3+ atoms. In the fifth O2- site, O2- is bonded to four Pb3+ atoms to form a mixture of corner and edge-sharing OPb4 tetrahedra. In the sixth O2- site, O2- is bonded to four Pb3+ atoms to form a mixture of distorted corner and edge-sharing OPb4 tetrahedra. In the seventh O2- site, O2- is bonded to four Pb3+ atoms to form a mixture of distorted corner and edge-sharing OPb4 tetrahedra. In the eighth O2- site, O2- is bonded to four Pb3+ atoms to form a mixture of distorted corner and edge-sharing OPb4 tetrahedra. In the ninth O2- site, O2- is bonded to four Pb3+ atoms to form a mixture of distorted corner and edge-sharing OPb4 tetrahedra. In the tenth O2- site, O2- is bonded to four Pb3+ atoms to form a mixture of distorted corner and edge-sharing OPb4 tetrahedra. In the eleventh O2- site, O2- is bonded to four Pb3+ atoms to form a mixture of distorted corner and edge-sharing OPb4 tetrahedra. In the twelfth O2- site, O2- is bonded to four Pb3+ atoms to form a mixture of corner and edge-sharing OPb4 tetrahedra.},
doi = {10.17188/1284567},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}