U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on U(SbO3)2 by Materials Project
Abstract
U(SbO3)2 crystallizes in the monoclinic C2/m space group. The structure is two-dimensional and consists of one U(SbO3)2 sheet oriented in the (0, 0, 1) direction. U6+ is bonded in a 2-coordinate geometry to six O2- atoms. There are two shorter (1.84 Å) and four longer (2.37 Å) U–O bond lengths. Sb3+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Sb–O bond distances ranging from 1.99–2.17 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one U6+ atom. In the second O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sb3+ atoms. In the third O2- site, O2- is bonded in a trigonal planar geometry to two equivalent U6+ and one Sb3+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-31256
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; U(SbO3)2; O-Sb-U
- OSTI Identifier:
- 1205539
- DOI:
- https://doi.org/10.17188/1205539
Citation Formats
The Materials Project. Materials Data on U(SbO3)2 by Materials Project. United States: N. p., 2017.
Web. doi:10.17188/1205539.
The Materials Project. Materials Data on U(SbO3)2 by Materials Project. United States. doi:https://doi.org/10.17188/1205539
The Materials Project. 2017.
"Materials Data on U(SbO3)2 by Materials Project". United States. doi:https://doi.org/10.17188/1205539. https://www.osti.gov/servlets/purl/1205539. Pub date:Wed May 10 00:00:00 EDT 2017
@article{osti_1205539,
title = {Materials Data on U(SbO3)2 by Materials Project},
author = {The Materials Project},
abstractNote = {U(SbO3)2 crystallizes in the monoclinic C2/m space group. The structure is two-dimensional and consists of one U(SbO3)2 sheet oriented in the (0, 0, 1) direction. U6+ is bonded in a 2-coordinate geometry to six O2- atoms. There are two shorter (1.84 Å) and four longer (2.37 Å) U–O bond lengths. Sb3+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Sb–O bond distances ranging from 1.99–2.17 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one U6+ atom. In the second O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sb3+ atoms. In the third O2- site, O2- is bonded in a trigonal planar geometry to two equivalent U6+ and one Sb3+ atom.},
doi = {10.17188/1205539},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed May 10 00:00:00 EDT 2017},
month = {Wed May 10 00:00:00 EDT 2017}
}