skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on Zn(SbO3)2 by Materials Project

Abstract

ZnSb2O6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Zn2+ is bonded to six O2- atoms to form ZnO6 octahedra that share corners with eight equivalent SbO6 octahedra and edges with two equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 51–52°. There are two shorter (2.09 Å) and four longer (2.11 Å) Zn–O bond lengths. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with four equivalent ZnO6 octahedra, corners with four equivalent SbO6 octahedra, an edgeedge with one ZnO6 octahedra, and an edgeedge with one SbO6 octahedra. The corner-sharing octahedra tilt angles range from 47–52°. There are two shorter (2.01 Å) and four longer (2.03 Å) Sb–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal planar geometry to one Zn2+ and two equivalent Sb5+ atoms. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to one Zn2+ and two equivalent Sb5+ atoms.

Publication Date:
Other Number(s):
mp-3188
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Zn(SbO3)2; O-Sb-Zn
OSTI Identifier:
1205955
DOI:
https://doi.org/10.17188/1205955

Citation Formats

The Materials Project. Materials Data on Zn(SbO3)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1205955.
The Materials Project. Materials Data on Zn(SbO3)2 by Materials Project. United States. doi:https://doi.org/10.17188/1205955
The Materials Project. 2020. "Materials Data on Zn(SbO3)2 by Materials Project". United States. doi:https://doi.org/10.17188/1205955. https://www.osti.gov/servlets/purl/1205955. Pub date:Tue Jul 14 00:00:00 EDT 2020
@article{osti_1205955,
title = {Materials Data on Zn(SbO3)2 by Materials Project},
author = {The Materials Project},
abstractNote = {ZnSb2O6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Zn2+ is bonded to six O2- atoms to form ZnO6 octahedra that share corners with eight equivalent SbO6 octahedra and edges with two equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 51–52°. There are two shorter (2.09 Å) and four longer (2.11 Å) Zn–O bond lengths. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with four equivalent ZnO6 octahedra, corners with four equivalent SbO6 octahedra, an edgeedge with one ZnO6 octahedra, and an edgeedge with one SbO6 octahedra. The corner-sharing octahedra tilt angles range from 47–52°. There are two shorter (2.01 Å) and four longer (2.03 Å) Sb–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal planar geometry to one Zn2+ and two equivalent Sb5+ atoms. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to one Zn2+ and two equivalent Sb5+ atoms.},
doi = {10.17188/1205955},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}