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Inclusion free cadmium zinc tellurium and cadmium tellurium crystals and associated growth method

Patent ·
OSTI ID:993079
The present disclosure provides systems and methods for crystal growth of cadmium zinc tellurium (CZT) and cadmium tellurium (CdTe) crystals with an inverted growth reactor chamber. The inverted growth reactor chamber enables growth of single, large, high purity CZT and CdTe crystals that can be used, for example, in X-ray and gamma detection, substrates for infrared detectors, or the like. The inverted growth reactor chamber enables reductions in the presence of Te inclusions, which are recognized as an important limiting factor in using CZT or CdTe as radiation detectors. The inverted growth reactor chamber can be utilized with existing crystal growth techniques such as the Bridgman crystal growth mechanism and the like. In an exemplary embodiment, the inverted growth reactor chamber is a U-shaped ampoule.
Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-98CH10886
Assignee:
U.S. Department of Energy (Washington, DC)
Patent Number(s):
7,758,843
Application Number:
12/416,224
OSTI ID:
993079
Country of Publication:
United States
Language:
English

References (9)

Improved growth of PbI2 single crystals journal March 2007
Thermophysical properties of liquid Te: Density, electrical conductivity, and viscosity journal April 2005
Purification of Cd0.9Zn0.1Te by physical vapor transport method journal December 2005
Buoyancy and rotation in small-scale vertical Bridgman growth of cadmium zinc telluride using accelerated crucible rotation journal December 2001
Vapor Growth of Cadmium Telluride Single Crystals journal March 1962
Effect of Te precipitates on the performance of CdZnTe detectors journal April 2006
Light-Induced Tellurium Enrichment on CdZnTe Crystal Surfaces Detected by Raman Spectroscopy journal April 2008
Crystal growth of large-diameter bulk CdTe on GaAs wafer seed plates journal April 2008
Analysis of CZT crystals and detectors grown in russia and the ukraine by high-pressure bridgman methods journal June 1999

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