Spectroscopic Constants of the Known Electronic States of Lead Monofluoride
Journal Article
·
· Journal of Molecular Spectroscopy
Based on measurements made by mass-resolved 1 + 1{prime} + 1{double_prime} resonance-enhanced multiphoton ionization spectroscopy, we have determined new molecular constants describing the rotational and fine structure levels of the B, D, E, and F states of the most abundant isotopic variant {sup 208}Pb{sup 19}F, and we summarize the spectroscopic constants for all the know electronic states of the radical. Many spectroscopic constants for the isotopologues {sup 206}Pb{sup 19}F and {sup 207}Pb{sup 19}F have also been determined. The symmetry of the D-state is found to be {sup 2}{pi}{sub 1/2}, and the F-state is found to be an {Omega} = 3/2 state.
- Research Organization:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Organization:
- Doe - Office Of Science
- DOE Contract Number:
- DE-AC02-98CH10886
- OSTI ID:
- 989173
- Report Number(s):
- BNL-91316-2010-JA; R&D Project: CO-006; KC0301020; TRN: US201019%%383
- Journal Information:
- Journal of Molecular Spectroscopy, Vol. 262, Issue 2; ISSN 0022-2852
- Country of Publication:
- United States
- Language:
- English
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