Raman and x-ray absorption spectroscopy characterization of Zr-doped MOCVD YBa{sub 2}Cu{sub 3}O{sub 6+{delta}}.

Journal Article · Fri Jan 01 04:00:00 EST 2010 · Supercond. Sci. Technol.

DOI:https://doi.org/10.1088/0953-2048/23/1/014020· OSTI ID:973034

Maroni, V A; Kropf, A J; Aytung, T; Paranthaman, M; ORNL,

Metal-organic chemical vapor deposited YBa{sub 2}Cu{sub 3}O{sub 6+{delta}} (YBCO) films (about 0.9 {micro}m thick) containing varying amounts of added zirconium were examined by Raman microscopy and synchrotron x-ray absorption spectroscopy. The self-field and in-field (1 T, B {parallel} c)J{sub c} performance of the YBCO films at 77 K (reported by the group at Oak Ridge National Laboratory that fabricated the samples) exhibited an increase on going from 0 mol% (m/o) Zr-added to 2.5 m/o Zr-added but then decreased sharply with increasing Zr content. Raman measurements on these films showed that the added Zr had little effect on YBCO cation disorder up to about 7.5 m/o Zr-added. Cation disorder increased while Ba-Cu-O content remained relatively constant for Zr additions {ge} 7.5 m/o. In the region of sharpest descent of J{sub c} with increasing Zr content (2.5-7.5 m/o Zr-added) neither the cation disorder nor the Ba-Cu-O content showed a systematic variation with J{sub c}. Zirconium K edge x-ray absorption near-edge spectroscopy revealed that virtually all of the added Zr in each sample was present as a BaZrO{sub 3}-like phase (BZO). The J{sub c} performance of the Zr-added films showed a high correlation with the variations in the next-nearest-neighbor Zr-M (M = Zr, Y) scattering path amplitude from the extended x-ray absorption fine structure (EXAFS) and the critical temperature over the full range of Zr additions and with cation disorder at the higher Zr-added levels (>7.5 m/o). There was no obvious correlation with the amount of residual barium cuprate or CuO. Approximate ranges for the BZO particle dimensions estimated from the EXAFS data indicated that the mean particle size gets larger with increasing Zr addition.

• Research Organization: Argonne National Laboratory (ANL)
• Sponsoring Organization: SC
• DOE Contract Number: AC02-06CH11357
• OSTI ID: 973034
• Report Number(s): ANL/CSE/JA-65671
• Journal Information: Supercond. Sci. Technol., Journal Name: Supercond. Sci. Technol. Journal Issue: Jan. 2010 Vol. 23; ISSN SUSTEF; ISSN 0953-2048
• Country of Publication: United States
• Language: ENGLISH

Related Subjects

43 PARTICLE ACCELERATORS
ABSORPTION
ABSORPTION SPECTROSCOPY
AMPLITUDES
BARIUM
CATIONS
CRITICAL TEMPERATURE
CUPRATES
DIMENSIONS
FINE STRUCTURE
MICROSCOPY
PARTICLE SIZE
PERFORMANCE
SCATTERING
SPECTROSCOPY
SYNCHROTRONS
ZIRCONIUM