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{gamma} Irradiation-induced degradation of organochlorinated pollutants in fatty esters and in Cod

Journal Article · · Journal of Agricultural and Food Chemistry
; ;  [1]
  1. Institut Armand-Frappier, Quebec (Canada); and others

The {gamma} irradiation-induced degradation of 2,2-bis(4-chlorophenyl)-1,1,1-trichloroethane (DDT), 2,2-bis(4-chlorophenyl)-1,1-dichloroethane (DDD), and 2,2-bis(4-chlorophenyl)-1,1-dichloroethylene (DDE) dissolved in methyl myristate and methyl oleate was studied. DDT and DDE produced DDD and 2,2-bis(4-chlorophenyl)chloroethylene (DDMU) respectively, in agreement with a previous study performed with aliphatic solvents. The degradation of these two former compounds was larger in methyl myristate than in methyl oleate and addition products between methyl myristate and the organochlorines were found. While DDD, DDE, and many PCB congeners in a cod sample were not measurably degraded at 15 KGy, DDT underwent 30% degradation. 9 refs., 1 fig., 2 tabs.

Sponsoring Organization:
USDOE
OSTI ID:
96380
Journal Information:
Journal of Agricultural and Food Chemistry, Journal Name: Journal of Agricultural and Food Chemistry Journal Issue: 2 Vol. 43; ISSN 0021-8561; ISSN JAFCAU
Country of Publication:
United States
Language:
English