Seca Coal-Based Systems Program

Technical Report · Sat May 31 04:00:00 EDT 2008

DOI:https://doi.org/10.2172/950474· OSTI ID:950474

Alinger, Matthew ^[1]

---

1. General Electric Company

This report summarizes the progress made during the August 1, 2006 - May 31, 2008 award period under Cooperative Agreement DE-FC26-05NT42614 for the U. S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled 'SECA Coal Based Systems'. The initial overall objective of this program was to design, develop, and demonstrate multi-MW integrated gasification fuel cell (IGFC) power plants with >50% overall efficiency from coal (HHV) to AC power. The focus of the program was to develop low-cost, high performance, modular solid oxide fuel cell (SOFC) technology to support coal gas IGFC power systems. After a detailed GE internal review of the SOFC technology, the program was de-scoped at GE's request. The primary objective of this program was then focused on developing a performance degradation mitigation path for high performing, cost-effective solid oxide fuel cells (SOFCs). There were two initial major objectives in this program. These were: (1) Develop and optimize a design of a >100 MWe integrated gasification fuel cell (IGFC) power plant; (2) Resolve identified barrier issues concerning the long-term economic performance of SOFC. The program focused on designing and cost estimating the IGFC system and resolving technical and economic barrier issues relating to SOFC. In doing so, manufacturing options for SOFC cells were evaluated, options for constructing stacks based upon various cell configurations identified, and key performance characteristics were identified. Key factors affecting SOFC performance degradation for cells in contact with metallic interconnects were be studied and a fundamental understanding of associated mechanisms was developed using a fixed materials set. Experiments and modeling were carried out to identify key processes/steps affecting cell performance degradation under SOFC operating conditions. Interfacial microstructural and elemental changes were characterized, and their relationships to observed degradation identified. Mitigation strategies, including innovative coatings and bond layers, were developed, evaluated and down-selected to improve degradation rates. Focus was on microstructural stabilization and minimization of the ASR contribution from Cr{sub 2}O{sub 3} scale growth and other interactions at electrode/interconnect interfaces evaluated during electrochemical testing and advanced microstructural characterization. Novel long-term and accelerated testing techniques were developed and conducted under standard operating conditions to demonstrate capability to meet targeted degradation rates.

• Research Organization: General Electric Company
• Sponsoring Organization: USDOE
• DOE Contract Number: FC26-05NT42614
• OSTI ID: 950474
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES
24 POWER TRANSMISSION AND DISTRIBUTION
30 DIRECT ENERGY CONVERSION
COAL
COAL GAS
COATINGS
DESIGN
ECONOMICS
EFFICIENCY
FUEL CELLS
GASIFICATION
MANUFACTURING
MINIMIZATION
MITIGATION
POWER PLANTS
POWER SYSTEMS
SOLID OXIDE FUEL CELLS
STABILIZATION
TESTING