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Lead zirconate titanate thin films on base-metal foils : an apporach for embedded high-permittivity passive components.

Journal Article · · J. Am. Ceram. Soc.

An approach for embedding high-permittivity dielectric thin films into glass epoxy laminate packages has been developed. Lead lanthanum zirconate titanate (Pb{sub 0.85}La{sub 0.15}-(Zr{sub 0.52}Ti{sub 0.48}){sub 0.96}O{sub 3}, PLZT) thin films were prepared using chemical solution deposition on nickel-coated copper foils that were 50 {mu}m thick. Sputter-deposited nickel top electrodes completed the all-base-metal capacitor stack. After high-temperature nitrogen-gas crystallization anneals, the PLZT composition showed no signs of reduction, whereas the base-metal foils remained flexible. The capacitance density was 300-400 nF/cm2, and the loss tangent was 0.01-0.02 over a frequency range of 1-1000 kHz. These properties represent a potential improvement of 2-3 orders of magnitude over currently available embedded capacitor technologies for polymeric packages.

Research Organization:
Argonne National Laboratory (ANL)
Sponsoring Organization:
DOD
DOE Contract Number:
AC02-06CH11357
OSTI ID:
949438
Report Number(s):
ANL/MSD/JA-40916
Journal Information:
J. Am. Ceram. Soc., Journal Name: J. Am. Ceram. Soc. Journal Issue: 10 ; Oct. 2001 Vol. 84
Country of Publication:
United States
Language:
ENGLISH

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