Influence of Ceria on the NOx Storage/Reduction Behavior of Lean NOx Trap Catalysts

Journal Article · Tue Jan 01 04:00:00 EST 2008 · Catalysis Today

DOI:https://doi.org/10.1016/j.cattod.2007.11.059· OSTI ID:931187

Ji, Yaying ^[1]; Choi, Jae-Soon ^[2]; Toops, Todd J ^[2]; Crocker, Dr. Mark ^[3]; Naseri, Mojghan ^[4]

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1. CAER-UK
2. ORNL
3. University of Kentucky, Lexington
4. DCL International Inc.

The effect of La2O3-stabilized ceria incorporation on the functioning of fully formulated lean NOx trap catalysts was investigated. Monolithic catalysts were prepared, corresponding to loadings of 0, 50 and 100 g CeO2/L, together with a catalyst containing 100 g/L of ceria-zirconia (Ce0.7Zr0.3O2). Loadings of the other main components (Pt, Rh and BaO) were held constant. Catalyst evaluation was performed on a bench flow reactor under simulated diesel exhaust conditions, employing NOx storage/reduction cycles. NOx storage efficiency in the temperature range 150-350 C was observed to increase with ceria loading, resulting in higher NOx conversion levels. At 150 C, high rich phase NOx slip was observed for all of the catalysts, resulting from an imbalance in the rates of nitrate decomposition and NOx reduction. Optimal NOx conversion was obtained in the range 250-350 C for all the catalysts, while at 450 C high rich phase NOx slip from the most highly loaded ceria-containing catalyst resulted in lower NOx conversion than for the ceria-free formulation. N2O was the major NOx reduction product at 150 C over all of the catalysts, although low NOx conversion levels limited the N2O yield. At higher temperatures N2 was the main product of NOx reduction, although NH3 formation was also observed. Selectivity to NH3 decreased with increasing ceria loading, indicating that NH3 is consumed by reaction with stored oxygen in the rear of the catalyst.

• Research Organization: Oak Ridge National Laboratory (ORNL); Fuels, Engines and Emissions Research Center
• Sponsoring Organization: ME USDOE - Office of Management, Budget, and Evaluation; ORNL work for others
• DOE Contract Number: AC05-00OR22725
• OSTI ID: 931187
• Journal Information: Catalysis Today, Journal Name: Catalysis Today Journal Issue: 1-2 Vol. 136; ISSN 0920-5861; ISSN CATTEA
• Country of Publication: United States
• Language: English

Related Subjects

33 ADVANCED PROPULSION SYSTEMS
54 ENVIRONMENTAL SCIENCES
AIR POLLUTION ABATEMENT
BARIUM OXIDES
CATALYSTS
CATALYTIC EFFECTS
CERIUM OXIDES
DIESEL ENGINES
EXHAUST GASES
NITROGEN OXIDES
PLATINUM
REDUCTION
RHODIUM
ZIRCONIUM OXIDES