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Isothermal Martensitic and Pressure-Induced ? to ?? Phase Transformations in a Pu-Ga Alloy

Conference ·
OSTI ID:925680

A Pu-2 at.% Ga alloy specimen is slowly compressed to {approx}1 GPa in a large volume moissanite anvil cell to induce the face-centered cubic {delta} to simple monoclinic {alpha}{prime} phase transformation. Optical microscopy, x-ray diffraction, and transmission electron microscopy of the specimen recovered to ambient pressure reveal that the vast majority of the microstructure consists of the {alpha}{prime} phase with grain sizes ranging from 10 nm to several hundred nm, with the remainder being {delta} phase dispersed between the {alpha}{prime} grains. This morphology is in contrast to the transformation product of the low-temperature isothermal martensite in which the lath-shaped {alpha}{prime} particles are {approx}20 {micro}m by 2 {micro}m.

Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA
Sponsoring Organization:
USDOE
DOE Contract Number:
W-7405-ENG-48
OSTI ID:
925680
Report Number(s):
UCRL-CONF-234546
Country of Publication:
United States
Language:
English