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Chemical Properties of the Cu(In,Ga)Se2/Mo/glass Interfaces in Thin Film Solar Cells

Journal Article · · Thin Solid Films

The Cu(In,Ga)Se{sub 2}/Mo and the Mo/glass interfaces in high efficiency thin film solar cells have been investigated by surface-sensitive photoelectron spectroscopy and bulk-sensitive X-ray emission spectroscopy. The interfaces were accessed by a suitable lift-off technique. Our experiments show a strong Se diffusion from the absorber into the Mo film, suggesting the formation of a MoSe{sub 2} layer in the surface-near region of the back contact. In addition, we find a Ga diffusion into the Mo back contact, while no diffusion of In and Cu occurs. Furthermore, we derive a detailed picture of the Na distribution near the back and front side of the Cu(In,Ga)Se{sub 2} absorber.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO.
Sponsoring Organization:
USDOE
DOE Contract Number:
AC36-99GO10337
OSTI ID:
915632
Journal Information:
Thin Solid Films, Journal Name: Thin Solid Films Journal Issue: 2007 Vol. 515; ISSN THSFAP; ISSN 0040-6090
Country of Publication:
United States
Language:
English

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